Seiji Matsuo

FeNbVB ALLOY PARTICLES SUSPENDED IN LIQUID GALLIUM: INVESTIGATING THE MAGNETIC PROPERTIES OF THE MR SUSPENSION

A MR suspension was prepared by dispersing silica-coated iron alloy particles into a liquid gallium. In other words, the iron alloy particles of 30 to 50 nm in diameter were first prepared and then coated with silica. Next, the particles were then suspended in a liquid Ga (assay: 99.9999%). In addition, the magnetic properties of the synthesized particles and suspension under the influence of the magnetic field were investigated. One of the main findings of this study is that the prepared powder showed a temperature sensitive of magnetization within the testing temperature range of 293–353 K. The saturation magnetization of silica-coated FeNbVB particles was about 0.55 T, whereas the saturation magnetization (297 K) of the synthesized MR suspension was 0.019 T.

CO2 processing and hydration of fruit and vegetable tissues by clathrate hydrate formation

CO2 hydrate can be used to preserve fresh fruits and vegetables, and its application could contribute to the processing of carbonated frozen food. We investigated water transformation in the frozen tissue of fresh grape samples upon CO2 treatment at 2-3 MPa and 3°C for up to 46 h. Frozen fresh bean, radish, eggplant and cucumber samples were also investigated for comparison. X-ray diffraction indicated that after undergoing CO2 treatment for several hours, structure I CO2 hydrate formed within the grape tissue. Phase-contrast X-ray imaging using the diffraction-enhanced imaging technique revealed the presence of CO2 hydrate within the intercellular spaces of these tissues. The carbonated produce became effervescent because of the dissociation of CO2 hydrate through the intercellular space, especially above the melting point of ice. In addition, suppressed metabolic activity resulting from CO2 hydrate formation, which inhibits water and nutrient transport through intercellular space, can be expected.

Concept of Seafloor Mineral Processing for Development of Seafloor Massive Sulfides

Seafloor Massive Sulfides (SMS), which were formed by deposition of precipitates from hydrothermal fluids vented from seafloor, is one of unconventional mineral resources beneath deep seafloors in the world. The authors have proposed the concept of seafloor mineral processing for development of SMS, where useful minerals included in SMS ores are separated on seafloor to be lifted while the remaining gangue is disposed on seafloor in appropriate ways. To apply column flotation, one of conventional methods in mineral processing, to seafloor mineral processing, the authors carried out simulating experiments of column flotation on deep seafloor using ores including copper, iron, lead and zinc as metallic elements. Prior to the experiments at high pressures, preparatory experiments at the atmospheric pressure were carried out to find out the optimum condition of the properties of pulp, a mixture of feed ore, water and chemical reagents. In flotation experiments at high pressures, formation and overflow of froth layer by bubbling were observed at 1MPa in both of pulps with pure water and artificial seawater. The analytical data showed that the concentration of metallic elements such as copper and zinc in the concentrates recovered from the experiments was higher than that in the feed ores while the concentration of silicon and calcium, which are assigned to gangue, in the concentrates was lower than that in the feed ores. These results suggest that column flotation can be applied to operation on seafloor.Copyright

Study on Grinding Technology for Seafloor Mineral Processing

Seafloor Massive Sulfides (SMSs), which are formed by precipitates from hydrothermal fluids vented from seafloor, have been expected as one of mineral resources to be developed. The authors have proposed the concept of seafloor mineral processing for SMS mining, where valuable minerals contained in SMS ores are separated on seafloor. To apply a ball mill to the grinding unit for seafloor mineral processing, grinding experiments were carried out using a small-scale ball mill applicable to high-pressure condition. In the experiments, wet grinding and water-filled grinding of size-classified silica sands were carried out at three rotation rates to compare the grinding performance in both cases. In both cases, the silica sands were finely ground. The measurement of particle size of samples from the experiments showed that water-filled grinding had comparable grinding performance to wet grinding while the suitable rotation rate for water-filled grinding shifted to higher than that for wet grinding. This result suggests the possibility of water-filled grinding for seafloor mineral processing. If water-filled grinding can be employed for the grinding unit, the structure of the grinding unit would be simplified in comparison with wet grinding that leads to the saving of grinding costs.Copyright

Study on Seafloor Mineral Processing for Mining of Seafloor Massive Sulfides

Seafloor Massive Sulfides (SMSs), which were formed by deposition of precipitates from hydrothermal fluids vented from seafloor, has been expected as one of unconventional mineral resources on deep seafloors in the oceans. The authors have proposed the concept of seafloor mineral processing for SMS mining, where valuable minerals contained in SMS ores are separated on seafloor while gangue minerals are disposed on seafloor in appropriate ways. To confirm the applicability of column flotation, which is one of conventional mineral processing methods, to seafloor mineral processing, the authors carried out experiments simulating column flotation under the pressure conditions corresponding to the water depths down to 1000m in maximum using ore samples containing copper, iron, zinc and lead. In the experiments, formation of fine bubbles suitable to flotation and overflow of froth layer were observed at high pressures. The contents of copper and zinc in the concentrates recovered in the experiments at 1MPa were higher than those in the feed ores while the contents of silicon and calcium in the concentrates were lower than those in the feed ores. These results suggest that column flotation would be applicable to seafloor mineral processing.Copyright