Serena Righi

Comparative cradle-to-gate life cycle assessments of cellulose dissolution with 1-butyl-3-methylimidazolium chloride and N-methyl-morpholine-N-oxide

In this paper the expected environmental impacts of the industrial cellulose dissolution with the ionic liquid 1-butyl-3-methylimidazolium chloride (Bmim Cl) were analyzed through a “cradle to gate” Life Cycle Assessment (LCA). In order to weigh up the “greenness” of the process, the analysis was performed through a comparison with the well established environmental friendly N-methyl-morpholine-N-oxide (NMMO)/H2O process. Although dissolution of cellulose in Bmim Cl has not been used for industrial production of cellulose fibers to date, results from LCA suggest that it could be interesting from an environmental point of view since its impacts are similar to those of the NMMO/H2O process. Specifically, the process with Bmim Cl generates a higher environmental load on abiotic resource depletion, emissions of volatile organic compounds and ecotoxicity than the NMMO/H2O process. Conversely it has some environmental advantages with regards to human toxicity. In both cellulose dissolution processes, the major contributions to the environmental impacts come from precursor syntheses. In addition to the comparative analysis of the two cellulose dissolution processes, the paper reports the complete life cycle inventory (LCI) of the two solvents, Bmim Cl and NMMO, and their life cycle impact assessment (LCIA).

Freshwater ecotoxicity characterisation factor for metal oxide nanoparticles: A case study on titanium dioxide nanoparticle

The Life Cycle Assessment (LCA) methodology is widely applied in several industrial sectors to evaluate the environmental performance of processes, products and services. Recently, several reports and studies have emphasized the importance of LCA in the field of engineered nanomaterials. However, to date only a few LCA studies on nanotechnology have been carried out, and fewer still have assessed aspects relating to ecotoxicity. This is mainly due to the lack of knowledge in relation on human and environmental exposure and effect of engineered nanoparticles (ENPs). This bottleneck is continued when performing Life Cycle Impact Assessment, where characterization models and consequently characterization factors (CFs) for ENPs are missing. This paper aims to provide the freshwater ecotoxicity CF for titanium dioxide nanoparticles (nano-TiO₂). The USEtox model has been selected as a characterisation model. An adjusted multimedia fate model has been developed which accounts for nano-specific fate process descriptors (i.e. sedimentation, aggregation with suspended particle matter, etc.) to estimate the fate of nano-TiO₂ in freshwater. A literature survey of toxicity tests performed on freshwater organism representative of multiple trophic levels was conducted, including algae, crustaceans and fish in order to collect relevant EC₅₀ values. Then, the toxic effect of nano-TiO₂ was computed on the basis of the HC₅₀ value. Thus, following the principle of USEtox model and accounting for nano-specific descriptors a CF for the toxic impact of freshwater ecotoxicity of 0.28 PAFdaym(3)kg(-1) is proposed.

Monitoring of natural radioactivity in working places

Abstract Radioactive materials are treated and transformed mainly in nuclear industries. However, non-nuclear industries use raw materials containing significant levels of natural radionuclides; the processing of these materials can expose workers and people living near such sites to radiation levels well above the natural background. This radioactivity is due to nuclides belonging to the 238 U and 232 Th decay chains and to 40 K. Inductively coupled plasma mass spectrometry (ICP-MS) and gamma-ray spectrometry have been used together to determine uranium and thorium concentration and the conditions of secular equilibrium in their decay chains for samples from ceramic and phosphate-fertiliser plants. In fact, the knowledge of the secular equilibrium conditions is necessary in order to make correct assumptions for the dose assessment. The results indicate that the secular equilibrium is verified for the samples from ceramic plants, whereas a situation of disequilibrium between parents and daughters of the natural chains is detected in phosphate fertilisers.

Life Cycle Assessment of high ligno-cellulosic biomass pyrolysis coupled with anaerobic digestion.

A Life Cycle Assessment is conducted on pyrolysis coupled to anaerobic digestion to treat corn stovers and to obtain bioenergy and biochar. The analysis takes into account the feedstock treatment process, the fate of products and the indirect effects due to crop residue removal. The biochar is considered to be used as solid fuel for coal power plants or as soil conditioner. All results are compared with a corresponding fossil-fuel-based scenario. It is shown that the proposed system always enables relevant primary energy savings of non-renewable sources and a strong reduction of greenhouse gases emissions without worsening the abiotic resources depletion. Conversely, the study points out that the use of corn stovers for mulch is critical when considering acidification and eutrophication impacts. Therefore, removal of corn stovers from the fields must be planned carefully.

Natural radioactivity in refractory manufacturing plants and exposure of workers to ionising radiation.

This paper shows the results of a survey carried out at some refractory manufacturing plants. During the first part of the survey, the concentration of natural radioactivity in raw materials and end-products, coming from four plants, was assessed. Several raw materials and, as a consequence, some end-products as well have shown activity concentrations exceeding a few hundreds of Bq kg(-1) of (238)U and (232)Th. In some important raw materials, such as bauxite and corundums, a remarkable radioactive disequilibrium was observed; this is probably due to the high temperature processes undergone by these materials. The second part of the survey focussed on the measurements of ambient equivalent dose rates, airborne dust concentrations and radon indoor. On the basis of results obtained, the effective dose for the standard worker was estimated. Two different types of refractory plants were investigated. Effective doses for both plants were lower than 1 mSv y(-1).

Modern accumulation rates and sources of organic carbon in the NE Gulf of Cádiz (SW Iberian Peninsula)

Abstract Organic carbon (OC) content, elemental (C/N) and isotopic (δ13C) composition of organic matter (OM) constrain relative contributions from both marine and terrestrial sources to modern sediments in the NE Gulf of Cádiz (GoC) shelf. C/N and (δ13C) indicate a transition from a dominantly marine to a terrestrial input of OM deposited in Bay of Cádiz and the Guadalquivir prodelta. OC and mass accumulation rates (MARs, based on bulk density and 210Pb-derived sediment MAR) suggest that labile OM from primary productivity accounts for the low OC content and burial rates in sediments in the NE GoC shelf.