Sergio G. Rodrigo

Efficient unidirectional nanoslit couplers for surface plasmons

The emerging field of plasmonics is based on exploiting the coupling between light and collective electronic excitations within conducting materials known as surface plasmons. Because the so-called surface plasmon polariton (SPP) modes that arise from this coupling are not constrained by the optical diffraction limit, it is hoped that they could enable the construction of ultracompact optical components1,2. But in order that such potential can be realized, it is vital that the relatively poor light–SPP coupling be improved. This is made worse by the fact that the incident light that is conventionally used to launch SPPs in a metal film 3,4,5,6 is a significant source of noise, unless directed away from a region of interest, which then decreases the signal and increases the system’s size. Back-side illumination of subwavelength apertures in optically thick metal films7,8,9,10,11,12,13 eliminates this problem but does not ensure a unique propagation direction for the SPP. We propose a novel back-side slit-illumination method that incorporates a periodic array of grooves carved into the front side of a thick metal film. Bragg reflection enhances the propagation of SPPs away from the array, enabling them to be unidirectionally launched from, and focused to, a localized point.

Triangular metal wedges for subwavelength plasmon-polariton guiding at telecom wavelengths

We report on subwavelength plasmon-polariton guiding by triangular metal wedges at telecom wavelengths. A high-quality fabrication procedure for making gold wedge waveguides, which is also mass-production compatible offering large-scale parallel fabrication of plasmonic components, is developed. Using scanning near-field optical imaging at the wavelengths in the range of 1.43-1.52 microm, we demonstrate low-loss (propagation length approximately 120 microm) and well-confined (mode width congruent with 1.3 microm) wedge plasmon-polariton guiding along triangular 6-microm-high and 70.5 degree-angle gold wedges. Experimental observations are consistent with numerical simulations performed with the multiple multipole and finite difference time domain methods.

Nanofocusing with channel plasmon polaritons.

We investigate radiation nanofocusing with channel plasmon polaritons (CPPs) propagating along subwavelength metal grooves that are tapered synchronously in depth and in width. Efficient CPP nanofocusing at telecom wavelengths with the estimated field intensity enhancement of up to approximately 90 is directly demonstrated using near-field microscopy. Experimental observations are concurred with electromagnetic simulations, predicting the possibility of reaching the intensity enhancements of approximately 1200 and opening thereby exciting perspectives for practical applications of CPP nanofocusing.

Highly Reproducible Near-Field Optical Imaging with Sub-20-nm Resolution Based on Template-Stripped Gold Pyramids

With a template-stripping fabrication technique, we demonstrate the mass fabrication of high-quality, uniform, ultrasharp (10 nm) metallic probes suitable for single-molecule fluorescence imaging, tip-enhanced Raman spectroscopy (TERS), and other near-field imaging techniques. We achieve reproducible single-molecule imaging with sub-20-nm spatial resolution and an enhancement in the detected fluorescence signal of up to 200. Similar results are obtained for TERS imaging of carbon nanotubes. We show that the large apex angle (70.5°) of our pyramidal tip is well suited to scatter the near-field optical signal into the far-field, leading to larger emission enhancement and hence to a larger quantum yield. Each gold or silver pyramidal probe is used on-demand, one at a time, and the unused tips can be stored for extended times without degradation or contamination. The high yield (>95%), reproducibility, durability, and massively parallel fabrication (1.5 million identical probes over a wafer) of the probes hold promise for reliable optical sensing and detection and for cementing near-field optical imaging and spectroscopy as a routine characterization technique.

Theory of Negative-Refractive-Index Response of Double-Fishnet Structures

A theory is presented of the negative refractive index observed in the so-called double-fishnet structures. We find that the electrical response of these structures is dominated by the cutoff frequency of the hole waveguide whereas the resonant magnetic response is due to the excitation of gap surface plasmon polaritons propagating along the dielectric slab. Associated with this origin, we show how the negative refractive index in these metamaterials presents strong dispersion with the parallel momentum of the incident light.

Optimization of bull's eye structures for transmission enhancement.

We present an exhaustive exploration of the parameter space defining the optical properties of a bulls eye structure, both experimentally and theoretically. By studying the resonance intensity variations associated with the different geometrical features, several parameters are seen to be interlinked and scale laws emerge. From the results it is possible to give a simple recipe to design a bulls eye structure with optimal transmission properties.

Mechanisms for extraordinary optical transmission through bull’s eye structures

We analyze both experimentally and theoretically the physical mechanisms that determine the optical transmission through deep sub-wavelength bulls eye structures (concentric annular grooves surrounding a circular hole). Our analysis focus on the transmission resonance as a function of the distance between the central hole and its nearest groove. We find that, for that resonance, each groove behaves almost independently, acting as an optical cavity that couples to incident radiation, and reflecting the surface plasmons radiated by the other side of the same cavity. It is the constructive contribution at the central hole of these standing waves emitted by independent grooves which ends up enhancing transmission. Also for each groove the coupling and reflection coefficients for surface plasmons are incorporated into a phenomenological Huygens-Fresnel model that gathers the main mechanisms to enhance transmission. Additionally, it is shown that the system presents a collective resonance in the electric field that does not lead to resonant transmission, because the fields radiated by the grooves do not interfere constructively at the central hole.

Extraordinary transmission through metal-coated monolayers of microspheres.

The spectral dependence of the extraordinary transmission through monolayers of close-packed silica or polystyrene microspheres on a quartz support, covered with different thin metal films (Ag, Au and Ni) was investigated. The measured spectra were compared with modeled transmission spectra using finite difference time domain (FDTD) calculations. Measured and modeled spectra show good overall agreement. The supported modes in the sphere array were found to be of utmost importance for the transmission mechanism and the results also suggest that the presence of guided modes in the photonic crystal may further enhance the extraordinary transmission through the metal film.

Extraordinary optical transmission through hole arrays in optically thin metal films

A theoretical study is presented on the optical transmission through square hole arrays drilled in optically thin films, where transmission may occur through both the holes and the metal layer. It is shown that, as the thickness of the metal film decreases, the coupling of light with short-range surface plasmons redshifts the extraordinary optical transmission peak to longer wavelengths. At the same time, the maximum-to-minimum transmittance ratio is kept high even for metal thicknesses as small as one skin depth.

In the diffraction shadow: Norton waves versus surface plasmon polaritons in the optical region

Surface electromagnetic modes supported by metal surfaces have a great potential for use in miniaturized detectors and optical circuits. For many applications, these modes are excited locally. In the optical regime, surface plasmon polaritons (SPPs) have been thought to dominate the fields at the surface, beyond a transition region comprising 3-4 wavelengths from the source. In this work, we demonstrate that at sufficiently long distances SPPs are not the main contribution to the field. Instead, for all metals, a different type of wave prevails, which we term Norton waves (NWs) for their resemblance to those found in the radio-wave regime at the surface of the Earth. Our results show that NWs are stronger at the surface than SPPs at distances larger than 6-9 SPP absorption lengths, the precise value depending on wavelength and metal. Moreover, NWs decay more slowly than SPPs in the direction normal to the surface.