Sertan Sukas

Superstructures of chiral nematic microspheres as all-optical switchable distributors of light

Light technology is based on generating, detecting and controlling the wavelength, polarization and direction of light. Emerging applications range from electronics and telecommunication to health, defence and security. In particular, data transmission and communication technologies are currently asking for increasingly complex and fast devices, and therefore there is a growing interest in materials that can be used to transmit light and also to control the distribution of light in space and time. Here, we design chiral nematic microspheres whose shape enables them to reflect light of different wavelengths and handedness in all directions. Assembled in organized hexagonal superstructures, these microspheres of well-defined sizes communicate optically with high selectivity for the colour and chirality of light. Importantly, when the microspheres are doped with photo-responsive molecular switches, their chiroptical communication can be tuned, both gradually in wavelength and reversibly in polarization. Since the kinetics of the “on” and “off” switching can be adjusted by molecular engineering of the dopants and because the photonic cross-communication is selective with respect to the chirality of the incoming light, these photo-responsive microspheres show potential for chiroptical all-optical distributors and switches, in which wavelength, chirality and direction of the reflected light can be controlled independently and reversibly.

A novel side electrode configuration integrated in fused silica microsystems for synchronous optical and electrical spectroscopy

We present a novel electrode configuration consisting of coplanar side electrode pairs integrated at the half height of the microchannels for the creation of a homogeneous electric field distribution as well as for synchronous optical and electrical measurements. For the integration of such electrodes in fused silica microsystems, a dedicated microfabrication method was utilized, whereby an intermediate bonding layer was applied to lower the temperature for fusion bonding to avoid thereby metal degradation and subsequently to preserve the electrode structures. Finally, we demonstrate the applicability of our devices with integrated electrodes for single cell electrical lysis and simultaneous fluorescence and impedance measurements for both cell counting and characterization.

Performance Evaluation of Different Design Alternatives for Microfabricated Nonporous Fused Silica Pillar Columns for Capillary Electrochromatography

An experimental study comparing the performance of different designs for microfabricated column structures for microchip capillary electrochromatography is presented. The work is a follow-up to our previously published modeling and simulation study on the same topic. Experiments were performed using fused silica microchips with and without octadecyltrimethoxysilane coating for nonretained and retained modes of operation, respectively. Showing the same trends as the modeling results, the foil shape produces a significant decrease in plate height with an increase of around 15% in mobile phase velocity in nonretained measurements of Coumarin 480 (C480). Measured plate heights at 1 kV/cm applied electric field were 0.77, 1.33, and 1.42 μm for foil, diamond, and hexagon, respectively. Chromatographic runs of C480 yielded minimal plate height values of 1.85 and 3.28 μm for foil and diamond, respectively. The optimization of the shape and placement of the structures appeared to have a considerable impact on the achievable performance.

Novel shape and placement definitions with retention modeling for solid microfabricated pillar columns for CEC and HPLC

A novel design approach for optimizing the shape of microfabricated pillar columns for LC is presented. 2‐D flow simulations are performed with a focus on electrokinetically driven flow, in order to evaluate the performance of the new method. The proposed foil shape is compared with geometrical shapes known from the literature, for various arrangements. It yields a much more uniform velocity field distribution and a decrease in plate height values up to 25%. In addition to shape optimization, a new method for spatial arrangement of structures is presented. With the aim of conserving the hydrodynamic balance, the axial spacing of the pillars is adjusted according to the proposed equivalent width approach. When compared with a fixed interpillar spacing in all directions, it increases the flow uniformity and results in an 18% lower plate height. A new direct simulation approach is implemented to model both flow field and retention for solid microfabricated pillar structures in the 2‐D domain. This model, which defines retention as inward/outward fluxes through the wall surfaces as first order reactions, enables monitoring of the time‐dependent process and an evaluation of the parameters affecting performance. The meaning of the obtained results in a practical setting, with limitations in photolithography and microfabrication, will be highlighted.

Design and implementation of injector/distributor structures for microfabricated non-porous pillar columns for capillary electrochromatography

A previously proposed foil definition is applied in the design of injector/distributor structures for solid microfabricated column structures for capillary electrochromatography. In addition to a typical bifurcated distributor, an optimized design alternative with two different configurations is experimentally evaluated. Optimized designs yielded a flat profile for the injected sample with a maximum of 3% variation from the mean width, while it went up to 18% for the typical bifurcated distributor. The implemented electrokinetic injection approach enabled controlling the volume of the injected sample accurately without sacrificing the compactness of the device design. The width of the injected sample was directly proportional to the injection time, namely 165 and 218 μm base widths were obtained for 0.6 and 0.8s of feeding, respectively. Reducing the external porosity of the distributor by 85% compared to the typical design, optimized distributors caused a decrease in the mean flow velocity of up to 70%. However, having a flat initial plug shape enabled the separation of a mixture of Coumarin 440, 460, 480 and 540 at 1 mm downstream of the injection point in 80s, while it was even not possible to detect the C440 signal for a typical bifurcated design.

Foil Definition for Optimizing the Shape of Microfabricated Columns for Capillary Electrochromatography

A novel design approach for optimizing the shape of the microfabricated pillar columns [1] for capillary electrochromatography (CEC) is presented. Applying this optimization approach, a new foil shape definition was introduced. Several design alternatives were evaluated starting from typical NACA 4-digit series symmetric airfoil definition. In order to avoid stagnant regions over the leading edge for NACA airfoil, the maximum thickness point was defined at the center of the chord. Then this shape was defined as the intersection of two parent circles to create the same geometry with simpler definition. As a final step of the optimization, a custom foil shape was obtained by fitting the 4th order polynomial, which was obtained from typical NACA 4-digit series, according to the defined boundary conditions. Microfluidic flow simulations were performed for electroosmotic flow (EOF) case for evaluating the performance of the foil definitions over other popular geometries (diamond and hexagon) from literature [2]. For electric field of 100 V/cm and same length and width, the custom foil shape yielded a plate height value of 2.76 μm, while 2.85 μm was obtained with hexagon as being the lowest value among other alternatives from the literature.Copyright