Seunghee Kim

Biosurfactant as an Enhancer of Geologic Carbon Storage: Microbial Modification of Interfacial Tension and Contact Angle in Carbon dioxide/Water/Quartz Systems

Injecting and storing of carbon dioxide (CO2) in deep geologic formations is considered as one of the promising approaches for geologic carbon storage. Microbial wettability alteration of injected CO2 is expected to occur naturally by microorganisms indigenous to the geologic formation or microorganisms intentionally introduced to increase CO2 storage capacity in the target reservoirs. The question as to the extent of microbial CO2 wettability alteration under reservoir conditions still warrants further investigation. This study investigated the effect of a lipopeptide biosurfactant—surfactin, on interfacial tension (IFT) reduction and contact angle alteration in CO2/water/quartz systems under a laboratory setup simulating in situ reservoir conditions. The temporal shifts in the IFT and the contact angle among CO2, brine, and quartz were monitored for different CO2 phases (3 MPa, 30°C for gaseous CO2; 10 MPa, 28°C for liquid CO2; 10 MPa, 37°C for supercritical CO2) upon cultivation of Bacillus subtilis strain ATCC6633 with induced surfactin secretion activity. Due to the secreted surfactin, the IFT between CO2 and brine decreased: from 49.5 to 30 mN/m, by ∼39% for gaseous CO2; from 28.5 to 13 mN/m, by 54% for liquid CO2; and from 32.5 to 18.5 mN/m, by ∼43% for supercritical CO2, respectively. The contact angle of a CO2 droplet on a quartz disk in brine increased: from 20.5° to 23.2°, by 1.16 times for gaseous CO2; from 18.4° to 61.8°, by 3.36 times for liquid CO2; and from 35.5° to 47.7°, by 1.34 times for supercritical CO2, respectively. With the microbially altered CO2 wettability, improvement in sweep efficiency of injected and displaced CO2 was evaluated using 2-D pore network model simulations; again the increment in sweep efficiency was the greatest in liquid CO2 phase due to the largest reduction in capillary factor. This result provides novel insights as to the role of naturally occurring biosurfactants in CO2 storage and suggests that biostimulation of biosurfactant production may be a feasible technique for enhancement of CO2 storage capacity.

Carbon Geological Storage: Coupled Processes, Engineering and Monitoring

Abstract Today’s energy concerns reflect the large anticipated increase in demand within the next generation, the current dependency on fossil fuels and climate implications, the geographic mismatch between resources and demand, and the disparity in associated time scales. The long-term geological storage of vast quantities of CO2 is a relatively new scientific and technological challenge, plagued with underlying coupled hydro-chemo-mechanical processes and potential emergent phenomena. Processes include: capillarity, density and viscous effects on flow; acidification, mineral dissolution, and ensuing changes in permeability; phase transformations (and CO2-CH4 exchange in hydrates); and stress changes. These processes are involved in the analysis of CO2 storage in saline aquifers, coal seams, depleted reservoirs, and in clathrates. Furthermore, the understanding of underlying processes guides monitoring (active: seismic and electromagnetic; passive: seismic, deformation, thermal) and may lead to improved efficiency and leakage-sealing strategies. Dimensionless ratios help identify the domain for the various dominant processes that govern CO2 geo-storage.

Rock Crushing Using Microwave Pre-Treatment

Crushing and grinding are primary contributors to a high energy demand in the mining industry, yet, both are surprisingly inefficient processes, often with efficiencies as low as 1%. We analyze size reductions during crushing and grinding operations and explore the potential of multiplying internal weaknesses in rock materials by non-mechanical means. In particular, when rock blocks (wet or even dry if polycrystalline) are exposed to microwaves, internal cracks can develop along grain boundaries via differential thermal expansion between grains and volumetric thermal expansion of water in pores. Brazilian tests conducted on granite and cement mortar specimens show that the tensile strength decreases proportional to the duration of microwave treatment. Thermal changes, excessive fluid pressure buildup and induced stresses are analyzed in the context of hydro-thermomechanically coupled processes. Results confirm that both differential thermal expansion of mineral grains and volumetric thermal expansion of water can generate cracks upon microwave exposure. Optimal conditions are suggested to lower the combined consumption of electric and mechanical energy.