Shaoyun Chen

Highly sensitive and well reproducible Surface-enhanced Raman spectroscopy from silver triangular platelets

Recently, considerable efforts have been made to prepare Surface-enhanced Raman scattering (SERS) nanostructures with high sensitivity and good reproducibility, which are always difficult and costly. In this article, we provide a simple route on the synthesis of silver particles with a novel single {111} plane and triangular morphology by reducing silver nitrate with poly(vinyl pyrrolidone) (PVP) in N,N-dimethylformamide (DMF) solutions. The results show that the Raman intensities of rhodamine 6G (R6G) decrease with decreasing the loading concentration and that R6G loading follows the first-order adsorption kinetics. Even at a low concentration of 10-12M, the signatures of R6G in Raman spectrum are still clearly observed. It indicates that the silver triangular platelets (i.e. AgTP) can offer sufficient active sites to efficiently capture the R6G molecules from the loading solution, and exhibit high SERS sensitivity. In addition, the relative standard deviation (RSD) of band at 1650cm-1 is calculated to be 13.7%, 12.7%, 15.7%, 15.1%, 13.3%, and 13.1%, respectively, corresponding with the concentration of R6G from 10-6M to 10-12M, which reveals the nanometer-scale AgTP can provide abundant hot spots and exhibit excellent reproducibility. This method offers an easy and low-cost way to prepare AgTP substrates and makes SERS detection more practicable.

Photoresponse properties based on CdS nanoparticles deposited on multi-walled carbon nanotubes

The influence of multi-walled carbon nanotube (i.e. MWCNT) architectures for facilitating charge transport in CdS semiconductor films was investigated. The power conversion efficiency (PCE) of the CdS nanoparticle-deposited multi-walled carbon nanotube nanohybrids (i.e. CdS@MWCNT) could be enhanced when the MWCNT was employed as the conducting scaffold in the CdS nanoparticle based photoelectrochemical cell. The CdS nanoparticles were deposited onto the MWCNT surface to improve photoinduced charge separation and transport of carriers (electrons and holes). The PCE of the CdS@MWCNT nanohybrids solar cell was found to be as high as 4.54%, contrasting sharply with the value (1.67%) for pure CdS nanoparticles. The outcome of the present work might provide a new avenue for designing optoelectronic and light-energy conversion devices.