Shengchun Qu

Surface plasmon enhanced ultraviolet emission from ZnO films deposited on Ag∕Si(001) by magnetron sputtering

The ZnO films were grown on Ag/Si(001) substrates by sputtering Ag and ZnO targets successively in a pure Ar ambient. A significant enhancement of ZnO ultraviolet emission and a reduction of its full width of half maximum have been observed while introducing a 100 nm Ag interlayer between ZnO film and Si substrate. Furthermore, a complete suppression of the defect related visible emission was also found for the ZnO/Ag/Si sample. This improved optical performance of ZnO is attributed to the resonant coupling between Ag surface plasmon and ultraviolet emission of ZnO. (c) 2007 American Institute of Physics.

Porous ZnAl2O4 spinel nanorods doped with Eu3+: synthesis and photoluminescence

Eu3+-doped zinc aluminate (ZnAl2O4) nanorods with a spinel structure were successfully synthesized via an annealing transformation of layered precursors obtained by a homogeneous coprecipitation method combined with surfactant assembly. These spinel nanorods, which consist of much finer nanofibres together with large quantities of irregular mesopores and which possess a large surface area of 93.2 m(2) g(-1) and a relatively narrow pore size distribution in the range of 6 - 20 nm, are an ideal optical host for Eu3+ luminescent centres. In this nanostructure, rather disordered surroundings induce the typical electric-dipole emission (D-5(0) --> F-7(2)) of Eu3+ to predominate and broaden.

Synthesis of shuttle-like ZnO nanostructures from precursor ZnS nanoparticles

Precursor ZnS nanoparticles, synthesized from the precipitation reaction of zinc acetate and sodium sulfide, were annealed at 700??C for the fabrication of shuttle-like ZnO nanoparticles. The structural characteristics, morphology, and chemical compositions of the as-prepared ZnO nanoparticles were investigated by x-ray powder diffraction (XRD), transmission electron microscopy (TEM), and x-ray photoelectron spectroscopy (XPS). It was revealed that the shuttle-like ZnO nanoparticles are pure and single crystalline, with lengths of up to 500?nm, stem diameters of 30?80?nm, and tip diameters of only a few nanometres. In addition, a possible growth mechanism for the obtained shuttle-like nanostructures is also discussed.

Magnetic Properties of FePt Nanoparticles Prepared by a Micellar Method

FePt nanoparticles with average size of 9 nm were synthesized using a diblock polymer micellar method combined with plasma treatment. To prevent from oxidation under ambient conditions, immediately after plasma treatment, the FePt nanoparticle arrays were in situ transferred into the film-growth chamber where they were covered by an SiO2 overlayer. A nearly complete transformation of L 10 FePt was achieved for samples annealed at temperatures above 700 °C. The well control on the FePt stoichiometry and avoidance from surface oxidation largely enhanced the coercivity, and a value as high as 10 kOe was obtained in this study. An evaluation of magnetic interactions was made using the so-called isothermal remanence (IRM) and dc-demagnetization (DCD) remanence curves and Kelly–Henkel plots (ΔM measurement). The ΔM measurement reveals that the resultant FePt nanoparticles exhibit a rather weak interparticle dipolar coupling, and the absence of interparticle exchange interaction suggests no significant particle agglomeration occurred during the post-annealing. Additionally, a slight parallel magnetic anisotropy was also observed. The results indicate the micellar method has a high potential in preparing FePt nanoparticle arrays used for ultrahigh density recording media.

Composition deviation of arrays of FePt nanoparticles starting from poly(styrene)-poly(4-vinylpyridine) micelles

Ordered arrays of FePt nanoparticles were prepared using a diblock polymer micellar method combined with plasma treatment. Rutherford backscattering spectroscopy analyses reveal that the molar ratios of Fe to Pt in metal-salt-loaded micelles deviate from those when metal precursors are added, and that the plasma treatment processes have little influence upon the compositions of the resulting FePt nanoparticles. The results from Fourier transform infrared spectroscopy show that the maximum loadings of FeCl(3) and H(2)PtCl(6) inside poly(styrene)-poly(4-vinylpyridine) micelles are different. The composition deviation of FePt nanoparticles is attributed to the fact that one FeCl(3) molecule coordinates with a single 4-vinylpyridine (4VP) unit, while two neighboring and uncomplexed 4VP units are required for one H(2)PtCl(6) molecule. Additionally, we demonstrate that the center-to-center distances of the neighboring FePt nanoparticles can also be tuned by varying the drawing velocity.

Ordered FePt nanoparticle arrays prepared by a micellar method

We prepared L10 phase FePt nanoparticle arrays on Si by a micellar method combined with plasma treatment, in-situ deposition of a Si02 overlayer, and a post-annealing. The FePt nanoparticle arrays exhibit a quasi-hexagonal order with tailored inter-particle spacing and partiele size. Transformation of L10 FePt was achieved for the annealed samples. In addition, the ordering temperature of FePt nanoparticles was reduced by 50∼100 °C by Au or Ag doping. The micellar method has a high potential in preparing FePt nanoparticle arrays used for ultrahigh density recording media.