Shi Xue-fa

Major element, trace element, and Sr, Nd and Pb isotope studies of Cenozoic basalts from the South China Sea

The whole rock K-Ar ages of basalts from the South China Sea basin vary from 3.8 to 7.9 Ma, which suggest that intra-plate volcanism after the cessation of spreading of the South China Sea (SCS) is comparable to that in adjacent regions around the SCS, i.e., Leiqiong Peninsula, northern margin of the SCS, Indochina block, and so on. Based on detailed petrographic studies, we selected many fresh basaltic rocks and measured their major element, trace element, and Sr-Nd-Pb isotope compositions. Geochemical characteristics of major element and trace element show that these basaltic rocks belong to alkali basalt magma series, and are similar to OIB-type basalt. The extent of partial melting of mantle rock in source region is very low, and magma may experience crystallization differentiation and cumulation during the ascent to or storing in the high-level magma chamber. Sr-Nd-Pb isotopic data of these basaltic rocks imply an inhomogeneous mantle below the South China Sea. The nature of magma origin has a two end-member mixing model, one is EM2 (Enriched Mantle 2) which may be originated from mantle plume, the other is DMM (Depleted MORB Mantle). Pb isotopic characteristics show the Dupal anomaly in the South China Sea, and combined with newly found Dupal anomaly at Gakkel ridge in Arctic Ocean, this implies that Dupal anomaly is not only limited to South Hemisphere. In variation diagrams among Sr, Nd and Pb, the origin nature of mantle below the SCS is similar to those below Leiqiong peninsula, northern margin of the SCS and Indochina peninsula, and is different from those below north and northeast China. This study provides geochemical constraints on Hainan mantle plume.

Geochemical source, deposition, and environmental risk assessment of cadmium in surface and core sediments from the Bohai Sea, China

Geochemical sources, spatio-temporal distribution, and associated environmental risk of Cd in the Bohai Sea were investigated using data from 405 surface sediment samples and two sediment cores. Local point Cd sources, TOC content, and currents are the main controlling factors of Cd distribution. The contribution of Cd from river discharge surpasses that from atmospheric deposition. Sediment-quality guidelines, enrichment factors, and chemical fraction analysis were used to assess metal toxicity in the collected sediments. Results show that Bohai Sea sediments have a moderate Cd enrichment level. This enrichment poses a high risk due to the relatively high mobility and bioavailability of Cd despite measured levels below sediment-quality guidelines at most stations. Vertical profiles of Cd concentrations, Al-normalized enrichment factors, and excess burial fluxes combined with 210Pb dating reveal the history of Cd pollution in the Bohai Sea over the last century. Data show Cd unvaried before the 1800s, a slight increase from the 1800s to the late 1950s, a decrease from the late 1960s to the 1970s, and an increase from the 1980s to 2001, including a relatively high value in 1998. Historic variation in Cd is closely associated with both natural and anthropogenic activities.

Distribution of thallium in the Bohai Sea: implications for hydrodynamic forces and anthropogenic impact

The distribution, sources, and fate of sedimentary thallium (Tl) in the Bohai Sea (BS) were studied on the basis of datasets of total Tl and chemical speciation of Tl in surface sediment samples. The Tl concentration exhibits a certain trend of accumulation in the fine-grained sediment, suggesting that the mud deposits are sinks for land-originated Tl and that the regional currents and tide systems play a key role in the sorting of sediment and accumulation of Tl in the BS. The low Tl enrichment factor and high proportion of Tl in the residual fraction indicated that Tl is mainly derived from a natural source, although the BS is under intense environmental pressure because of excess wastewater discharge. Local Tl contamination was observed at the Liuguhe River mouth, and this contamination does not extend to beyond the inner shelves of the BS because of the regional currents. The level of Tl in the nonresidual fraction is very low and is dominated by the level of Tl in the Fe–Mn oxide fraction, indicating that Tl exhibits low mobility and bioavailability in the BS. The correlations between Tl concentration and MnO and Fe2O3 and the relatively high level of Tl in Fe–Mn oxide fraction suggested that MnO and Fe2O3 influence the geochemical behavior of Tl in the BS. The oxidizable fraction of Tl is negligible, suggesting that total organic carbon (TOC) might not be a major factor influencing the accumulation of Tl in the BS, although there is a positive correlation between Tl and TOC in the samples.

Sedimentary characteristics of silty clay facies in the South Yellow Sea shelf

Grain size analysis, X-ray diffraction analysis and biostratigraphy analysis of the structure, composition and formation conditions of the neritic silty clay facies sediments extensively distributed in the central part of the South Yellow Sea showed that the sediments were composed of more than 70% clay, less than 30% silt, had very little or no sand, and were characterized by homogenous texture, soapy feeling, high plasticity, light green gray color and elliptical distribution being about 3 m thick in the center, being thinner towards the margin and finally thinning out. These shelf cyclonic eddy environment sediments formed a sedimentary facies different from that of the sediments in the neighbouring area and revealed the particular sediment dynamic pattern in the environment.

Evolution of westerly jet during the last 60 ka: Evidence from core deposits in the central Japan (East) Sea

Aeolian dust has a significant environmental impact on the ocean biogeochemical cycles in different timescales. However, spatial and temporal variations of dust transported on long distances in the upper troposphere by the westerly jet, in particular over orbital-millennial timescales, have not been resolved yet. In this study, we present the evidence for changes in the main axis and path of westerly jet over East Asia at millennial-orbital scale during the last glacial period (~60 ka). We examine the grain size characteristics of sediment core LV53-23 collected from the central Japan (East) Sea, which lies the downwind of westerly jet to discuss the evolution of westerly jet since the last glacial period. Our results show that core sediments are composed mainly of silt characterized of eolian dust, which is consistent with those sediment cores discussed in previous studies from the Japan Sea. The median grain-size of silt fraction has similar pattern with environmentally sensitive grain size extracted by standard deviation/grain-size method. The median grain size in silt fraction increased in stadial periods and decreased in interstadial periods, which might be related to changes in the path of westerly jet. During the stadial, the westerly jet mostly located in the the south of the Tibetan Plateau. It can influence the northern part of the Tibetan Plateau extending to 50°N with high speed, which is prerequisite of dust raised to westerlies in northern China and thus carried the coarser dust from nearby Mongolian Gobi and northeastern China to the Japan Sea. During the interstadial, the provenance of the finer aeolian dust was from Taklimakan Desert when westerly jet migrated northward and concentrated within a narrow band at northern Tibetan Plateau with a longer duration. We found the multi-millennial time scales variations during DOI 8, 12, 14, 16 in cores LV53-23 and MD01-2407 located in the southwestern Japan Sea based on the results of NGRIP and GISP 2 Greenland ice cores. Contrasting with grain size variations of the loess-paleosol records (e.g., Gulang Loess sequence), the lowest grain size during the Last Glacial Maximum confirm that the silt fraction of Japan Sea sediment was mostly transported by westerlies instead of East Asian Winter Monsoon. The mechanism driving the orbital scale variability in grain size of aeolian dust in the Japan Sea is mainly forced by variations of ice volume due to summer insolation in the Northern Hemisphere. A southward migration in the main axis of westerly jet and its influential area was affected by a decrease of summer insolation and increase of ice volume in Northern Hemisphere. During the Last Glacial Maximum, although the cold surges and dust storms were intensive, the southward path of westerly jet may decreased the dust entrainment ability transported by westerlies so that downwind received finer grain size eolian dust. This argument is consistent with findings showing that the location of subarctic front in North Pacific during the Last Glacial Maximum was caused by a southward shift of the path of Kuroshio Current which is controlled by westerly jet. During the glacial period, the decreasing grain size of dust in northern site is explained by weaker westerlies in higher latitudes (40°–50°N) caused by the southward shift of westerly jet main axis, while the increase grain size in the southern site is controlled by the increasing of dust transport path because of westerlies speed in lower latitudes.