Shiming Wan

Extreme weathering/erosion during the Miocene Climatic Optimum: Evidence from sediment record in the South China Sea

Investigating the interplay between continental weathering and erosion, climate, and atmospheric CO(2) concentrations is significant in understanding the mechanisms that force the Cenozoic global cooling and predicting the future climatic and environmental response to increasing temperature and CO(2) levels. The Miocene represents an ideal test case as it encompasses two distinct extreme climate periods, the Miocene Climatic Optimum (MCO) with the warmest time since 35 Ma in Earths history and the transition to the Late Cenozoic icehouse mode with the establishment of the east Antarctic ice sheet. However the precise role of continental weathering during this period of major climate change is poorly understood. Here we show changes in the rates of Miocene continental chemical weathering and physical erosion, which we tracked using the chemical index of alteration ( CIA) and mass accumulation rate ( MAR) respectively from Ocean Drilling Program (ODP) Site 1146 and 1148 in the South China Sea. We found significantly increased CIA values and terrigenous MARs during the MCO (ca. 17-15 Ma) compared to earlier and later periods suggests extreme continental weathering and erosion at that time. Similar high rates were revealed in the early-middle Miocene of Asia, the European Alps, and offshore Angola. This suggests that rapid sedimentation during the MCO was a global erosion event triggered by climate rather than regional tectonic activity. The close coherence of our records with high temperature, strong precipitation, increased burial of organic carbon and elevated atmospheric CO(2) concentration during the MCO argues for long-term, close coupling between continental silicate weathering, erosion, climate and atmospheric CO(2) during the Miocene. Citation: Wan, S., W. M. Kurschner, P. D. Clift, A. Li, and T. Li (2009), Extreme weathering/ erosion during the Miocene Climatic Optimum: Evidence from sediment record in the South China Sea, Geophys. Res. Lett., 36, L19706, doi: 10.1029/2009GL040279.

Human impact overwhelms long-term climate control of weathering and erosion in southwest China

During the Holocene there has been a gradual increase in the influence of humans on Earth systems. High-resolution sedimentary records can help us to assess how erosion and weathering have evolved in response to recent climatic and anthropogenic disturbances. Here we present data from a high-resolution (similar to 75 cm/k.y.) sedimentary archive from the South China Sea. Provenance data indicate that the sediment was derived from the Red River, and can be used to reconstruct the erosion and/or weathering history in this river basin. Accelerator mass spectrometry C-14 dating provides direct age control and reveals coherent variations in clay mineralogy, geochemistry, and terrigenous flux, indicative of strong chemical weathering and physical erosion during the mid-Holocene warm period (6400-4000 cal [calibrated] yr B.P.), followed by weakening from ca. 4000-1800 cal yr B.P., and renewed intensification since 1800 cal yr B.P.. Comparison with climatic records from China indicates that precipitation and temperature controlled both physical erosion and chemical weathering intensity before 1800 cal yr B.P.. However, weathering proxies in the offshore sediment indicate recent increased soil erosion. We suggest that enhanced human activity (deforestation, cultivation, and mining) since the end of the Chinese Han Dynasty (220 CE) has overwhelmed the natural climatic controls on erosion in the Red River.

Geochemical records in the South China Sea: implications for East Asian summer monsoon evolution over the last 20 Ma

Abstract We reconstruct past changes in the East Asian summer monsoon over the last 20 Ma using samples from Ocean Drilling Program (ODP) Site 1146 of Leg 184 in the northern South China Sea based on the major (Al, Ca, Na, K, Ti, etc.) and trace element (Rb, Sr, and Ba) geochemistry of terrigenous sediments. This study and combined review suggests that the long-term evolution of the East Asian summer monsoon is similar to that of the Indian summer monsoon, but distinct from the East Asian winter monsoon. Generally, the Asian summer monsoon intensity has decreased gradually from its maximum in the Early Miocene. In contrast, the Asian winter monsoon shows a phased enhancement since 20 Ma bp. Moreover, our study shows that the long-term intensities of the Asian summer and winter monsoons may have different forcing factors. Specifically, the winter monsoon is strongly linked to phased uplift of Tibetan plateau and to Northern Hemispheric Glaciation. In contrast, global cooling since 20 Ma bp may have largely reduced the amount of water vapour held in the atmosphere and thus weakened the Asian summer monsoon.

ITCZ and ENSO pacing on East Asian winter monsoon variation during the Holocene: Sedimentological evidence from the Okinawa Trough

Deep-sea fan sediments provide an excellent geological archive for paleoenvironment reconstruction. Grain size, clay mineral and elemental (Ti, Fe, Ca) compositions were measured for a core retrieved from a submarine fan in the Okinawa Trough. Varimax-rotated Principal Component Analysis (V-PCA) on time-evolution of grain size spectrum reveals that, since the Holocene, sediment was transported mainly by the benthic nepheloid layer (33%) and upper layers (33%) which is driven by the East Asian winter monsoon (EAWM). The intensification of the Kuroshio Current during the Holocene, masks the fluvial signal of the summer monsoon and obstructs clay minerals derived from the Yellow River, a major contributor prior to 12 ka BP. A new grain size index (GSI), which represents the EAWM well, exhibits a negative correlation with the delta O-18 record in Dongge Cave, China during the Holocene when sea level was relatively steady. This anti-correlation suggests the southward migration of the Intertropical Convergence Zone (ITCZ). The consistency among our records and rainfall records in Peru, Ti counts in the Cariaco Basin, monsoon records in Oman and the averaged summer insolation pattern at 30 degrees N further support the ITCZs impact on monsoon systems globally. Cross-Correlation Analyses for GSI and log(Ti/Ca) against delta O-18 record in Dongge Cave reveal a decoupling between the East Asian winter and summer monsoon during 5500-2500 cal yr BP, with greater complexity in the last 2500 years. This can be attributed to exacerbated ENSO mode fluctuations and possibly anthropogenic interference superimposed on insolation and ITCZ forcing.

Tectonic and climatic controls on long-term silicate weathering in Asia since 5 Ma

Determining the interplay between tectonic deformation, climate, atmospheric CO2 concentrations and continental weathering and erosion is key to understanding the mechanisms that forced Cenozoic global cooling. In contrast with studies of paleo-climate and pCO(2), the history of long-term silicate weathering in the Himalaya and Tibetan Plateau (HTP) during the late Cenozoic remains unclear. We reconstruct 5 m.y. of silicate sedimentary records at Ocean Drilling Program (ODP) Site 1143 in the South China Sea to explore the weathering history of the Mekong River basin that supplied the sediment. Coherent variation of weathering proxies from the South China Sea, Bay of Bengal, Loess Plateau, as well as the Yangtze and Yellow Rivers, indicates weakening chemical weathering intensity since the late Pliocene, as the climate cooled. This cooling, coupled with tectonic activity, shifted the dominant weathering regime from more transport-limited to more weathering-limited, causing less chemical depletion of silicate minerals. While silicate weathering rates became strongly correlated to erosion rates, they were decoupled from chemical weathering intensity. Physical denudation and associated silicate weathering rates in the HTP area increased in the Pliocene, driven by both rock uplift and stronger monsoon precipitation, decreasing atmospheric CO2 concentrations, and so contributing to Northern Hemisphere Glaciation (NHG). Citation: Wan, S., P. D. Clift, A. Li, Z. Yu, T. Li, and D. Hu (2012), Tectonic and climatic controls on long-term silicate weathering in Asia since 5 Ma, Geophys. Res. Lett., 39, L15611, doi:10.1029/2012GL052377.

Quantitative estimates of Asian dust input to the western Philippine Sea in the mid-late Quaternary and its potential significance for paleoenvironment

We present a new high-resolution multiproxy data set of Sr-Nd isotopes, rare earth element, soluble iron, and total organic carbon data from International Marine Global Change Study Core MD06-3047 located in the western Philippine Sea. We integrate our new data with published clay mineralogy, rare earth element chemistry, thermocline depth, and delta C-13 differences between benthic and planktonic foraminifera, in order to quantitatively constrain Asian dust input to the basin. We explore the relationship between Philippine Sea and high-latitude Pacific eolian fluxes, as well as its significance for marine productivity and atmospheric CO2 during the mid-late Quaternary. Three different indices indicate that Asian dust contributes between similar to 15% and similar to 50% to the detrital fraction of the sediments. Eolian dust flux in Core MD06-3047 is similar to that in the polar southern Pacific sediment. Coherent changes for most dust flux maximum/minimum indicate that dust generation in interhemispheric source areas might have a common response to climatic variation over the mid-late Quaternary. Furthermore, we note relatively good coherence between Asian dust input, soluble iron concentration, local marine productivity, and even global atmospheric CO2 concentration over the entire study interval. This suggests that dust-borne iron fertilization of marine phytoplankton might have been a periodic process operating at glacial/interglacial time scales over the past 700 ka. We suggest that strengthening of the biological pump in the Philippine Sea, and elsewhere in the tropical western Pacific during the mid-late Quaternary glacial periods may contribute to the lowering of atmospheric CO2 concentrations during ice ages.

The history of the Yangtze River entering sea since the last glacial maximum: a review and look forward

Abstract This review paper provides a brief review on the development of ideas in the fields of the sea level change of the ECS (East China Sea), the history of the Yangtze River entering the sea and paleochannels in the shelf of the ECS since the Last Glacial Maximum (LGM). The paper summarizes two opposite theories about the Yangtze River entering the sea during the LGM. One theory is that the Yangtze River input a lacustrine in the north of Jiangsu province which was defunct in middle Holocene, and the river was once dry. The other was that the Yangtze River still existed and entered into the Okinawa Trough during the LGM, but scholars share different opinions on which course the river ran across and which place the river input the trough. This paper concludes future work is to study the evolution of the Yangtze River and the paleoclimate and the corresponding events as a whole from the view of regional and even global change, and more attention should be paid to the study on mud sediment, the Yangtze Rivers response to the changes in climate and sea-level, and the channel metamorphosis.

The silicon isotope composition of Ethmodiscus rex laminated diatom mats from the tropical West Pacific: Implications for silicate cycling during the Last Glacial Maximum

The cause of massive blooms of Ethmodiscus rex laminated diatom mats (LDMs) in the eastern Philippine Sea (EPS) during the Last Glacial Maximum (LGM) remains uncertain. In order to better understand the mechanism of formation of E. rex LDMs from the perspective of dissolved silicon (DSi) utilization, we determined the silicon isotopic composition of single E. rex diatom frustules (δ30SiE. rex) from two sediment cores in the Parece Vela Basin of the EPS. In the study cores, δ30SiE. rex varies from −1.23‰ to −0.83‰ (average −1.04‰), a range that is atypical of marine diatom δ30Si and that corresponds to the lower limit of reported diatom δ30Si values of any age. A binary mixing model (upwelled silicon versus eolian silicon) accounting for silicon isotopic fractionation during DSi uptake by diatoms was constructed. The binary mixing model demonstrates that E. rex dominantly utilized DSi from eolian sources (i.e., Asian dust) with only minor contributions from upwelled seawater sources (i.e., advected from Subantarctic Mode Water, Antarctic Intermediate Water, or North Pacific Intermediate Water). E. rex utilized only ~24% of available DSi, indicating that surface waters of the EPS were eutrophic with respect to silicon during the LGM. Our results suggest that giant diatoms did not always use a buoyancy strategy to obtain nutrients from the deep nutrient pool, thus revising previously proposed models for the formation of E. rex LDMs.

Deepwater circulation variation in the South China Sea since the Last Glacial Maximum

Deepwater circulation plays a central role in global climate. Compared with the Atlantic, the Pacific deepwater circulation’s history remains unclear. The Luzon overflow, a branch of the North Pacific deep water, determines the ventilation rate of the South China Sea (SCS) basin. Sedimentary magnetic properties in the SCS reflect millennial-scale fluctuations in deep current intensity and orientation. The data suggest a slightly stronger current at the Last Glacial Maximum compared to the Holocene. But, the most striking increase in deep current occurred during Heinrich stadial 1 (H1) and to a lesser extent during the Younger Dryas (YD). Results of a transient deglacial experiment suggest that the northeastern current strengthening at the entrance of the SCS during H1 and the YD, times of weak North Atlantic Deep Water formation, could be linked to enhanced formation of North Pacific Deep Water.Deepwater circulation plays a central role in global climate. Compared with the Atlantic, the Pacific deepwater circulations history remains unclear. The Luzon overflow, a branch of the North Pacific deep water, determines the ventilation rate of the South China Sea (SCS) basin. Sedimentary magnetic properties in the SCS reflect millennial-scale fluctuations in deep current intensity and orientation. The data suggests a slightly stronger current at the Last Glacial Maximum compared to the Holocene. But, the most striking increase in deep current occurred during Heinrich stadial 1 (H1) and, to a lesser extent during the Younger Dryas (YD). Results of a transient deglacial experiment suggest that the Northeastern current strengthening at the entrance of the SCS during H1 and the YD, times of weak North Atlantic Deep Water formation, could be linked to enhanced formation of North Pacific Deep Water.

Assemblage characteristics of clay minerals and its implications to evolution of eolian dust input to the Parece Vela Basin since 1.95 Ma

To understand the provenance and evolution of eolian input in the last 1.95 Ma in the Parece Vela Basin in the eastern Philippine Sea, the clay mineral assemblage of a gravity core PV090510 from the basin was investigated using paleogeomagnetic dating and X-ray diffraction. The assemblage of the core mainly consisted of smectite (∼46%) and illite (∼40%), with some chlorite (∼10%) and kaolinite (∼4%). Analysis of the provenance of these minerals suggested that smectite was mainly derived from volcanic rocks of the Mariana Arc, while illite, chlorite, and kaolinite were mainly transported as eolian dust by the East Asian monsoon from central Asia. We used the ratio of (illite+chlorite+kaolinite)/smectite as a proxy for Asian eolian input to the Parece Vela Basin since 1.95 Ma. This ratio followed glacial and interglacial cycles and was consistent with the intensity of the East Asian monsoon and aridity of central Asia since 1.95 Ma. The changes of the ratio reflected three different stages of the East Asian monsoon and provenance climate.