Shuguang Liu

Adsorption of Clofibric Acid from Aqueous Solution by Graphene Oxide and the Effect of Environmental Factors

Graphene oxide (GO) nanosheets were used as adsorbent material for the removal of clofibric acid (CA) which was difficult to be removed from wastewater by traditional wastewater treatment technique. Adsorption kinetics, adsorption equilibrium, and effect of pH, ionic strength, and humic acid (HA) of the adsorption of CA onto the GO nanosheets in aqueous solution were investigated in detail. Adsorption isotherm studies indicated that the Langmuir isotherm equation fitted the sorption isotherm data better than Freundlich model and the maximum adsorption capacity of GO nanosheets for CA was 994xa0mgxa0g−1. In addition, adsorption kinetics data showed that the sorption of CA on GO nanosheets reached equilibration within a few minutes and were well fitted by pseudo second-order model. The results of the effects of environment factors indicated that CA sorption on GO nanosheets was weakly affected by ionic strength and strongly depended on pH and HA because of the structure of CA and the large number of oxygen-containing function groups presented on the surface of GO nanosheets. Besides, the removal efficiency of GO nanosheets for CA was reduced at pH >4 and enhanced at pH <4 in the presence of HA.

A new DDA model for kinematic analyses of rockslides on complex 3-D terrain

Landslides are common phenomena in mountainous regions worldwide. Over the past two decades, catastrophic rockslides in mountainous regions have caused serious damage and fatalities. To develop effective preventive countermeasures, it is important to estimate the kinematic behavior of displaced masses after slope failures, such as the velocity, run-out distance, and extent. Discontinuous deformation analysis (DDA) is an appropriate tool to analyze the dynamics, kinematics, and deformability of a block assembly. Many studies have reported applications of DDA to kinematic analyses of rockslides on two-dimensional (2-D) terrain. However, because of the restrictions of numerical techniques, few kinematic analyses of rockslides on three-dimensional (3-D) terrain have been performed using DDA. This study developed a new DDA model for the analysis of rockslides on 3-D terrain. First, contact treatment techniques for the 3-D model were developed to create an accurate and efficient computational scheme. The new model was then verified by the benchmark tests on the four basic types of block motion on 3-D terrain. Finally, the new model was applied to a designed rockslide with complex terrain to demonstrate its practical applicability. The results indicate that the new 3-D DDA model is an effective tool to analyze 3-D rockslides and could potentially be used to optimize protection designs for rockslides.

Experimental Study of Tidal Effects on Coastal Groundwater and Pollutant Migration

The problem of current urban groundwater pollution is very serious, which has influenced social development and people’s daily life. Around the land-sea interface, tide obviously changes nearshore the groundwater flow regime and makes the pollutant migration process become more complex. In the present study, the effect of tide-induced groundwater table fluctuations and on the pollutants migration in beach aquifers is investigated by constructing a two-dimensional sand trough physical experimental model. The model considered brackish-water density differences and the tide by controlling experimental medium properties and boundary conditions. The results showed that the groundwater table fluctuation cycle is the same as the tidal cycle and the fluctuation lag time increases linearly with the increase of the offshore distance. Tidal fluctuation flattens brackish-freshwater interface, widens the dispersion zone, and generates the upper saline and the freshwater belt. Time lag corresponding relationships between saline water and tidal fluctuation was observed. With the pollutant approaching the saline water area, the profile of the pollutant migration is gradually developed into a spindle shape until the strip shape, and the pollutant enters the saline water body along the curved edge of the upper part of the saline water. The transverse dispersion of pollutants is larger than the longitudinal dispersion in a tidal cycle and its outline presents a strip shape development. No mixing or exchange between the pollutants and the saline water body happened during the whole process. This study can provide scientific references for nearshore groundwater pollution prevention and control in the future.

Environmental and human impacts on sediment transport of the largest Asian rivers of Russia and China

The paper deals with comparative summary of sediment loads and particulate trace metals (V, Cr, Co, Cu, Zn, Cd, Pb) transport in the largest Asian rivers of Russia and China. Environmental conditions and human interventions in the selected catchments (Lena, Ob, Enisey, Selenga, Kolyma, Amur, Yellow, Yangtze, Pearl) are analyzed with respect to the rate and composition of suspended sediment loads. The paper presents calculations of sediment load changes at the downstream sections of the rivers and new database of the chemical composition of suspended matter which involves all recent studies of the last decade for the sediment geochemistry. The results indicate that fluvial system and its human modifications are the most significant drivers of sediment load. Fluvial erosion in the unconfined channels exerts a significant control on the sediment load changes due to observed permafrost melting. We concluded that construction of reservoirs has the most important influence on land–ocean sediment fluxes in the largest rivers of Asia but plays relatively weak role in heavy metal composition in suspended particulate matter (SPM) due to lowest sedimentation rates of the fine clay particles, which are mostly enriched with heavy metals. The paper also presents novel mapping approaches related to cartographic recognition of the fluvial system and its human modification and sediment transfer processes in the largest Asian rivers of Russia and China, linked with a specific legend. Finally, analysis of uncertainties associated with estimating the SPM composition in the rivers was done with respect to spatial and temporal variability. It was shown that the main error occurs due to incorporation of data only from particular hydrological seasons which usually ignore high flood conditions.