Shuh-Ji Kao

A review of nitrogen isotopic alteration in marine sediments

Key Points: Use of sedimentary nitrogen isotopes is examined; On average, sediment 15N/14N increases approx. 2 per mil during early burial; Isotopic alteration scales with water depth Abstract: Nitrogen isotopes are an important tool for evaluating past biogeochemical cycling from the paleoceanographic record. However, bulk sedimentary nitrogen isotope ratios, which can be determined routinely and at minimal cost, may be altered during burial and early sedimentary diagenesis, particularly outside of continental margin settings. The causes and detailed mechanisms of isotopic alteration are still under investigation. Case studies of the Mediterranean and South China Seas underscore the complexities of investigating isotopic alteration. In an effort to evaluate the evidence for alteration of the sedimentary N isotopic signal and try to quantify the net effect, we have compiled and compared data demonstrating alteration from the published literature. A >100 point comparison of sediment trap and surface sedimentary nitrogen isotope values demonstrates that, at sites located off of the continental margins, an increase in sediment 15N/14N occurs during early burial, likely at the seafloor. The extent of isotopic alteration appears to be a function of water depth. Depth-related differences in oxygen exposure time at the seafloor are likely the dominant control on the extent of N isotopic alteration. Moreover, the compiled data suggest that the degree of alteration is likely to be uniform through time at most sites so that bulk sedimentary isotope records likely provide a good means for evaluating relative changes in the global N cycle.

Hyperpycnal Discharge of Fluvial Sediment to the Ocean: Impact of Super‐Typhoon Herb (1996) on Taiwanese Rivers

Hyperpycnal events (when suspended sediment concentrations exceed 40 g/L) occur in smalland medium-sized rivers throughout the world but are particularly common in Taiwan; they are often related to landslides or debris flows initiated and transported by typhoon floods. Super-Typhoon Herb, which swept across Taiwan on July 31–August 2, 1996, triggered floods and landslides throughout the southern part of the island. Sediment concentrations in at least seven rivers (Taan, Choshui, Pachang, Erhjen, Tsengwen, Kaoping, and Peinan) approached or exceeded 40 g/L. Calculated sediment discharged from nine rivers (these seven as well as the Wu and Houlung, neither of which apparently reached hyperpycnal concentrations) during these 3 d was 217 million tons (MT)—most of it on August 1—of which ∼80% was discharged at hyperpycnal concentrations. Presumably, most of the sediments discharged by the Peinan River (to the southeast) and the Kaoping, Erhjen, Tsengwen, and Pachang rivers (to the southwest) were transported directly to the Huatong Basin and the South China Sea (via the Penghu Canyon system), respectively. The bulk of the typhoon-derived sediment (142 MT), however, was discharged to the northwest (primarily by the Choshui River), and its fate remains unknown. It may have ultimately reached the Penghu Canyon system and thereby the South China Sea, but more probably it was transported northward (via the Taiwan Warm Current) toward China, the East China Sea, or (perhaps) the Okinawa Trough.

Extreme storm events, landscape denudation, and carbon sequestration: Typhoon Mindulle, Choshui River, Taiwan

We have performed the first known semicontinuous monitoring of particulate organic carbon (POC) fluxes and dissolved Si concentrations delivered to the ocean during a typhoon. Sampling of the Choshui River in Taiwan during Typhoon Mindulle in 2004 revealed a POC flux of 5.00 × 105 t associated with a sediment flux of 61 Mt during a 96 h period. The linkage of high amounts of POC with sediment concentrations capable of generating a hyperpycnal plume upon reaching the ocean provides the first known evidence for the rapid delivery and burial of POC from the terrestrial system. These fluxes, when combined with storm-derived CO2 consumption of 1.65 × 108 mol from silicate weathering, elucidate the important role of these tropical cyclone events on small mountainous rivers as a global sink of CO2.

Gravity Flows Associated with Flood Events and Carbon Burial: Taiwan as Instructional Source Area

Taiwans unique setting allows it to release disproportionately large quantities of fluvial sediment into diverse dispersal systems around the island. Earthquakes, lithology, topography, cyclone-induced rainfall, and human disturbance play major roles in the catchment dynamics. Deep landslides dominate the sediment-removal process on land, giving fluvial sediment distinct geochemical signals. Extreme conditions in river runoff, sediment load, nearshore waves and currents, and the formation of gravity flows during typhoon events can be observed within short distances. Segregation of fresh biomass and clastic sediment occurs during the marine transport process, yet turbidity currents in the Gaoping Submarine Canyon carry woody debris. Strong currents in the slope and back-arc basin of the Okinawa Trough disperse fine-grained sediments rapidly and widely. Temporal deposition and remobilization may occur when the shallow Taiwan Strait acts as a receptacle. Taiwan can therefore serve as a demonstration of the episodic aspect of the source-to-sink pathway to both the coastal and deep-ocean environments.

Predicting the Flux of Sediment to the Coastal Zone: Application to the Lanyang Watershed, Northern Taiwan

Abstract A global scale approach involving data assimilation schemes (e.g. Distributed Oceanographic Data System) is designed to simulate the discharge of sediment to the coastal ocean at the dynamic level (daily). The result is either a real-time, hindcast or forecast picture of coastal hydrology optimized to estimate sediment loads of rivers. The approach links a compendium of global and regional web-based databases into a GIS system. Relational and spatial methods (i.e. RiverToolst, HYDRO1k, ArcInfot) facilitate the process of data acquisition useful to sediment discharge models (i.e. HydroTrend). As a climate-driven hydrological model, HydroTrend incorporates drainage basin properties (river networks, hypsometry, relief, lakes or reservoirs, distributary channels) through high-resolution digital elevation models, along with other biophysical parameters (basin-average temperature, precipitation, evapo-transpiration, canopy, soil depth, hydraulic conductivity, ice fields). The schema is designed to provide important boundary conditions for marine sediment-dispersal models, concomitant with ocean data (wind, wave, currents). Considering that <4% of world-rivers are monitored for their sediment loads, the approach provides a unique means to predict the sediment flux across an entire coastline at a high-resolution temporal scale. Model comparison to long-term (1950–1994) observations from the Lanyang River (Hsi), Taiwan is shown to capture average conditions and inter- and intra-annual variability of water discharge, sediment concentration and loads.

Cyclone-driven deep sea injection of freshwater and heat by hyperpycnal flow in the subtropics

China (973 Program) [2009CB421200]; Program of Introducing Talents of Discipline to Universities [B07034]; Academia Sinica Thematic Program AFOBi, Taiwan [NSC 98-2116-M-001-005]

Eutrophication-Driven Hypoxia in the East China Sea off the Changjiang Estuary.

Coastal hypoxia is an increasingly recognized environmental issue of global concern to both the scientific community and the general public. We assessed the relative contributions from marine and terrestrially sourced organic matter that were responsible for oxygen consumption in a well-studied seasonal coastal hypoxic zone, the East China Sea off the Changjiang Estuary. Our fieldwork was conducted in August 2011 during reinstatement of a subsurface hypoxia, when we observed a continuous decline of dissolved oxygen along with production of dissolved inorganic carbon resulting from organic carbon remineralization. On the basis of a three end-member mixing model and determinations of the stable isotopic compositions of dissolved inorganic carbon (δ(13)CDIC), the end product of particulate organic carbon (POC) degradation, we quantified the δ(13)C value of the remineralized organic carbon (δ(13)COCx), which was -18.5 ± 1.0‰. This isotopic composition was very similar to the δ(13)C of marine sourced POC produced in situ (-18.5 ± 0.3‰) rather than that of the terrestrially sourced POC (-24.4 ± 0.2‰). We concluded that marine-sourced organic matter, formed by eutrophication-induced marine primary production, was the dominant oxygen consumer in the subsurface hypoxic zone in the East China Sea off the Changjiang Estuary.

Effects of acidic processing, transport history, and dust and sea salt loadings on the dissolution of iron from Asian dust

[1] Aerosol particles collected over the East China Sea (ECS) were analyzed for water-soluble Fe (Fe s ), total Fe (Fe T ), and other chemical species. Eight samples were classified as high Asian dust (HAD) on the basis of total Al concentrations >1500 ng/m 3 . Comparisons with low Asian dust (LAD) samples showed that unlike Fe T or most other substances, the percentage of Fe T soluble in deionized water (%Fe s ) was lower in the HAD samples. The %Fe s in the HAD samples varied with transport pattern and air mass history. As the difference in Fe s concentrations between HAD and LAD is relatively small and HAD occurs several days each year, the supply of Fe s through dry deposition to the surface ocean may be less sporadic than previously thought. Soluble Fe correlated with non-sea-salt sulfate, water-soluble organic carbon, and nitrate, possibly because of an anthropogenic, relatively soluble, form of Fe or enhanced dissolution caused by reactions with anthropogenic acids. Sea salt loadings evidently have a negative effect on %Fe s , presumably due to buffering effects of the salts. Dust concentrations and %Fe s followed an inverse power law relationship with a moderate correlation, suggesting that the %Fe s may be increased by acid processing during transport as dust loadings gradually decrease.

Widespread dispersal and aging of organic carbon in shallow marginal seas

The occurrence of pre-aged organic carbon (OC) in continental margin surface sediments is a commonly observed phenomenon, yet the nature, sources, and causes of this aged OC remain largely undetermined for many continental shelf settings. Here we present the results of an extensive survey of the abundance and radiocarbon content of OC in surface sediments from the northern Chinese marginal seas. Pre-aged OC is associated with both coarser (>63 µm) and finer (<63 µm) sedimentary components; measurements on specific grain-size fractions reveal that it is especially prevalent within the 20–63 µm fraction of inner shelf sediments. We suggest that organic matter associated with this sortable silt fraction is subject to protracted entrainment in resuspension-deposition loops during which it ages, is modified, and is laterally dispersed, most likely via entrainment within benthic nepheloid layers. This finding highlights the complex dynamics and predepositional history of organic matter accumulating in continental shelf sediments, with implications for our understanding of carbon cycling on continental shelves, development of regional carbon budgets, and interpretation of sedimentary records.

Linking typhoon tracks and spatial rainfall patterns for improving flood lead time predictions over a mesoscale mountainous watershed

area of 620 km 2 ) located in eastern Taiwan were analyzed to fill the gaps in our knowledge concerning the linkage between typhoon track, rainfall patterns, and flood peak time. This study used spatially high-resolution radar-derived rainfall estimates from 38 storm events (� 2800 h) to investigate this linkage. The effect of spatial rainfall patterns on the timing of flood peak for the selected events was examined with the aid of a diffusive wave model. The results show that the typhoon rainfall was spatially aggregated and that the relative variations in the rainfall became smaller at higher rainfall rates. The maximum hourly rainfall was approximately twice the areal mean rainfall. Three major rainfall types were identified statistically, and different typhoon tracks appeared to have preferable rainfall types. This finding is presumably due to the interaction of the typhoon circulation and precipitation with the mountainous landscape. Flood lead times were derived for the different rainfall types, and it was found that differences in their lead times could be as large as � 3 h over the studied mesoscale watershed. It is recommended that this empirical approach be incorporated into flood forecasting and warning systems.