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Dive into the research topics where Shunjiro Misumi is active.

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Featured researches published by Shunjiro Misumi.


Tetrahedron Letters | 1980

Conformationally selective transannular cyclizations of humulene 9,10-epoxide. Synthesis of the two skeletally different cyclohumulanoids: dl-bicyclohumulenone and dl-africanol

Haruhisa Shirahama; Kiyoharu Hayano; Yoshiro Kanemoto; Shunjiro Misumi; Toshikazu Ohtsuka; Nobuhiro Hashiba; Akio Furusaki; Shizuaki Murata; Ryoji Noyori; Takeshi Matsumoto

Two cyclohumulanoids, dl-bicyclohumulenone (4) and dl-africanol (7 were synthesized through newly developed conformationally selective transannular cyclization of humulene 9,10-epoxide (2). The epoxide 2 was converted to a bicyclohumulenediol diacetate 3a in 70% yield by treatment with BF3·OEt2-Ac2O, while treatment of 2 with trimethylsilyl trifluoromethansulfonate gave an africen-10-ol (5a and 5b) in 80% yield. The two intermediates 3a and 5a furnished the natural products 4 and 7 in 30 and 8 % yield from 2 respectively.


Tetrahedron Letters | 1979

Biogenetic like synthesis of illudoid skeleton. In vitro conversion of humulene into 7-protoilludyl cation

Shunjiro Misumi; Toshikazu Ohtsuka; Yasufumi Ohfune; Kazumi Sugita; Haruhisa Shirahama; Takeshi Matsumoto


Tetrahedron Letters | 1979

Cyclization of humulene by means of mercury(II) salts. Transannular 1,6-hydride shift in the course of the reaction

Shunjiro Misumi; Toshikazu Ohtsuka; Hisanobu Hashimoto; Yasufumi Ohfune; Haruhisa Shirahama; Takeshi Matsumoto


Chemistry Letters | 1981

SYNTHESIS OF PENTALENIC ACID THROUGH BIOGENETIC LIKE CYCLIZATION OF HUMULENE

Kazuya Sakai; Toshikazu Ohtsuka; Shunjiro Misumi; Haruhisa Shirahama; Takeshi Matsumoto


Tetrahedron Letters | 1977

New ring contraction of cyclobutyl ketones to cyclopropyl ketones syntheses of Δ2(3),7(13)-illudadiene and Δ2(3) -7β-illudenol

Yasufumi Ohfune; Shunjiro Misumi; Akio Furusaki; Haruhisa Shirahama; Takeshi Matsumoto


Bulletin of the Chemical Society of Japan | 1974

The Crystal Structure of dl-Bi-1,4-dioxanyl

Akio Furusaki; Shunjiro Misumi; Takeshi Matsumoto


ChemInform | 1979

CYCLIZATION OF HUMULENE BY MEANS OF MERCURY(II) SALTS. TRANSANNULAR 1,6-HYDRIDE SHIFT IN THE COURSE OF THE REACTION

Shunjiro Misumi; T. Ohtsuka; Hisanobu Hashimoto; Yasufumi Ohfune; Haruhisa Shirahama; Takeshi Matsumoto


ChemInform | 1977

NEW RING CONTRACTION OF CYCLOBUTYL KETONES TO CYCLOPROPYL KETONES. SYNTHESES OF Δ2(3),7(13)-ILLUDADIENE AND Δ2(3)-7β-ILLUDENOL

Yasufumi Ohfune; Shunjiro Misumi; Akio Furusaki; Haruhisa Shirahama; Takeshi Matsumoto


ChemInform | 1976

A NEW MODE OF IN VITRO CYCLIZATION OF HUMULENE. FORMATION OF 3,6-SECOPROTOILLUDANE SKELETON

Shunjiro Misumi; Yasufumi Ohfune; Akio Furusaki; Haruhisa Shirahama; Takeshi Matsumoto


ChemInform | 1975

THE CRYSTAL STRUCTURE OF DL-BI-1,4-DIOXANYL

Akio Furusaki; Shunjiro Misumi; Takeshi Matsumoto

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Akio Furusaki

Kwansei Gakuin University

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