Shunjiro Misumi
Hokkaido University
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Tetrahedron Letters | 1980
Haruhisa Shirahama; Kiyoharu Hayano; Yoshiro Kanemoto; Shunjiro Misumi; Toshikazu Ohtsuka; Nobuhiro Hashiba; Akio Furusaki; Shizuaki Murata; Ryoji Noyori; Takeshi Matsumoto
Two cyclohumulanoids, dl-bicyclohumulenone (4) and dl-africanol (7 were synthesized through newly developed conformationally selective transannular cyclization of humulene 9,10-epoxide (2). The epoxide 2 was converted to a bicyclohumulenediol diacetate 3a in 70% yield by treatment with BF3·OEt2-Ac2O, while treatment of 2 with trimethylsilyl trifluoromethansulfonate gave an africen-10-ol (5a and 5b) in 80% yield. The two intermediates 3a and 5a furnished the natural products 4 and 7 in 30 and 8 % yield from 2 respectively.
Tetrahedron Letters | 1979
Shunjiro Misumi; Toshikazu Ohtsuka; Yasufumi Ohfune; Kazumi Sugita; Haruhisa Shirahama; Takeshi Matsumoto
Tetrahedron Letters | 1979
Shunjiro Misumi; Toshikazu Ohtsuka; Hisanobu Hashimoto; Yasufumi Ohfune; Haruhisa Shirahama; Takeshi Matsumoto
Chemistry Letters | 1981
Kazuya Sakai; Toshikazu Ohtsuka; Shunjiro Misumi; Haruhisa Shirahama; Takeshi Matsumoto
Tetrahedron Letters | 1977
Yasufumi Ohfune; Shunjiro Misumi; Akio Furusaki; Haruhisa Shirahama; Takeshi Matsumoto
Bulletin of the Chemical Society of Japan | 1974
Akio Furusaki; Shunjiro Misumi; Takeshi Matsumoto
ChemInform | 1979
Shunjiro Misumi; T. Ohtsuka; Hisanobu Hashimoto; Yasufumi Ohfune; Haruhisa Shirahama; Takeshi Matsumoto
ChemInform | 1977
Yasufumi Ohfune; Shunjiro Misumi; Akio Furusaki; Haruhisa Shirahama; Takeshi Matsumoto
ChemInform | 1976
Shunjiro Misumi; Yasufumi Ohfune; Akio Furusaki; Haruhisa Shirahama; Takeshi Matsumoto
ChemInform | 1975
Akio Furusaki; Shunjiro Misumi; Takeshi Matsumoto