Shunmian Lu

Functions of Self-assembled Ultrafine TiO2 Nanocrystals for High Efficient Dye-Sensitized Solar Cells

In this paper, we demonstrate a simple approach of self-assembled process to form a very smooth and compacted TiO2 underlayer film from ultrafine titanium oxide (TiO2) nanocrystals with dimension of 4 nm for improving the electrical properties and device performances of dye-sensitized solar cells (DSSCs). Because the TiO2 film self-assembles by simply casting the TiO2 on fluorine-doped tin oxide (FTO) substrate, it can save a lot of materials in the process. As compared with control DSSC without the self-assembled TiO2 (SA-TiO2) layer, short-circuit current density (Jsc) improves from 14.9 mA/cm(2) for control DSSC to 17.3 mA/cm(2) for masked DSSC with the SA-TiO2 layer. With the very smooth SA-TiO2 layer, the power conversion efficiency is enhanced from 8.22% (control) to 9.35% for the DSSCs with mask and from 9.79% (control) to 11.87% for the DSSCs without mask. To explain the improvement, we have studied the optical properties, morphology, and workfunction of the SA-TiO2 layer on FTO substrate as well as the impedance spectrum of DSSCs. Importantly, we find that the SA-TiO2 layers have better morphology, uniformity, and contact with FTO electrode, increased workfunction and optical transmission, as well as reduced charge recombination at the contact of FTO substrate contributing to the improved device performances. Consequently, our results show that the simple self-assembly of TiO2 ultrafine nanocrystals forms a very good electron extraction layer with both improved optical and electrical properties for enhancing performances of DSSCs.

Recent progress of interconnecting layer for tandem organic solar cells

This paper has reviewed: (1) the two unique advantages of tandem organic solar cells (OSCs) compared to single OSCs; (2) the challengings as well as strategies to develop qualified interconnecting layer (ICL) for tandem OSCs. More specifically, firstly, the two key advantages unique to tandem OSCs as compared to single OSCs, namely minimizing sub-bandgap transmission and thermalization loss as well as realizing optical thick and electrical thin structures, have been discussed. Secondly, the ICL, as one of the most challenging issue in tandem OSCs that needs to fulfill the optical, electrical and mechanical requirements simultaneously to realize a qualified ICL has been reviewed. As one of the most challenging requirement among the three, the electrical requirement and its corresponding three different solving strategies have been discussed in detail, revealing a bright future for developing a general strategy to realizing qualified ICL composed of different hole transporting layer (HTL) and electron transporting layer (ETL).