Shuting Zhang

Influence of NaOH and thermal pretreatment on dewatered activated sludge solubilisation and subsequent anaerobic digestion: Focused on high-solid state

In this study, the influence of NaOH and thermal pretreatment of dewatered activated sludge (DAS) on the high-solid solubilisation and anaerobic digestion was separately investigated by monitoring common parameters. The results indicated that COD, proteins and carbohydrates were efficiently solubilised in both NaOH and thermal pretreated DAS samples. For NaOH pretreatment, the concentrations of volatile fatty acids (VFAs) and total ammonium nitrogen (TAN) firstly increased followed by decreasing with NaOH dose increasing. However, they decreased with the severity of thermal pretreatment. During the batch digestion experiments (at 37°C), for 80mg NaOHg(-1) total solid (TS) DAS pretreatment it resulted in a 6.99% decrease in cumulative methane yield (CMY) compared to untreated DAS. While for 80, 100, 120°C and 20mg NaOH pretreatment, CMY increased by 15%, 42%, 71% and 35%, respectively, in comparison to untreated DAS.

Study on the waste liquid crystal display treatment: focus on the resource recovery.

A process combined pyrolysis and acid immersion was proposed in this study to dispose the hazardous liquid crystal display (LCD) waste for recovering valuable resources. The thermogravimetric (TG) analysis and fixed bed pyrolysis were investigated for the polarizing film that was separated from LCD. The results suggested the liquid product mainly contained acids, esters and aromatics should be upgraded such as hydrotreating process before used as industrial feedstock or fuel source. The gaseous product mainly consisted of H(2), CO, CO(2) and CH(4) can be used as a valuable fuel. The sulfuric acid immersion experiments were studied for recovering indium from the LCD glass after stripping the polarizing film. Central composite design (CCD) under response surface methodology (RSM) was used to optimize the acid immersion process and the results indicated the indium recovery can be fitted based on the actual value to a polynomial quadratic equation and the temperature was more essential factor than time and acid concentration in the studied ranges. The optimum processing condition was obtained with time 42.2 min, temperature 65.6 °C and acid concentration 0.6 mol/L. Under the optimal conditions, the indium recovery was close to 100%.

A new method for evaluating the sewage sludge pyrolysis kinetics

A new method to simplify calculation the kinetics model is applied to sewage sludge pyrolysis based on the assumption that volatile run out as soon as it formed and during temperature arising process in this study. Difference method widely used to solve math problems is conducted to calculate kinetics parameters. Pyrolysis experiments are carried out at heating rates of 10, 15, 20, and 50 degrees C/min. All the TG curves are divided into three parts which are beginning decomposition temperature range, main decomposition temperature range, and final decomposition temperature range. The second one is employed to determine the parameters for more than 70% of the total mass loss occurs in this range. According to the developed method, the react order, reaction energy and pre-exponential factor are obtained, which are in the range of 3.9-4.1, 82.3-109.2 kJ/mol and 7.7 x 10(6)-2.8 x 10(9)/min, respectively, which are in the range of that reported previously. As a comparison experimental data with calculated data, the well fitting results indicate that this method is appropriate for simulating sludge pyrolysis kinetics.

Pretreatment of corn stover with diluted acetic acid for enhancement of acidogenic fermentation

A Box-Behnken design of response surface method was used to optimize acetic acid-catalyzed hydrothermal pretreatment of corn stover, in respect to acid concentration (0.05-0.25%), treatment time (5-15 min) and reaction temperature (180-210°C). Acidogenic fermentations with different initial pH and hydrolyzates were also measured to evaluate the optimal pretreatment conditions for maximizing acid production. The results showed that pretreatment with 0.25% acetic acid at 191°C for 7.74 min was found to be the most optimal condition for pretreatment of corn stover under which the production of acids can reach the highest level. Acidogenic fermentation with the hydrolyzate of pretreatment at the optimal condition at the initial pH=5 was shown to be butyric acid type fermentation, producing 21.84 g acetic acid, 7.246 g propionic acid, 9.170 butyric acid and 1.035 g isovaleric acid from 100g of corn stover in 900 g of water containing 2.25 g acetic acid.

Two-step pretreatment of corn stalk silage for increasing sugars production and decreasing the amount of catalyst.

The study investigated the effects of two-step pretreatment on fermentable sugar production from corn stalk silage. In the first step, the corn stalk silage was extracted by tepid water and then the solid was pretreated using Fe(NO(3))(3) as catalyst. The results showed that 45.8 g/100g DM total sugars was obtained and the surface of remaining solid was seriously damaged after two-step pretreatment. Compared with one-step pretreatment, the production of total sugars increased by 23.8% and the amount of the catalyst of Fe(NO(3))(3) decreased by 28.8%. This research provides a new effective, suitable and economical pretreatment method for biogas production from corn stalk.

Pressurized electro-dewatering of activated sludge: Analysis of electrode configurations (anode)

An electric field and mechanical pressure combined are considered an effective electro-dewatering (PED) technology for activated sludge. Here, the curved surface anodes were used for electro-dewatering to improve the effective anode area, and the PED characteristics were investigated for three anode types (flat plate, sawtooth plate and wave plate). First, evaluation methodology of the modified energy consumption ( [Formula: see text] ) and the modified processing capacity ( [Formula: see text] ) were established, with electro-dewatering factor (ξED), to evaluate the PED efficiency of different anode configurations under three raw sludge processing capacity modes. Second, the solid content distribution was analyzed by the layered method, and the electric field and current density distribution were analyzed by the finite element method. Finally, the gas emission mechanism of the curved surface anodes was discussed. When the raw sludge processing capacity and dewatering time (10 min) were the same, nearly the same extent of dewatering was achieved for the wave plate anode as for the flat plate anode. The total filtrate amount was 69.5 g and 59.0 g for the wave plate and flat plate anodes, respectively, and [Formula: see text] increased by 17.8% for the former. Under the same raw sludge thickness, the dewatering percentages in area A of the sawtooth plate and wave plate anodes were 10% and 11%, respectively, higher than that of the flat plate anode. However, according to numeric simulation results, the current density at the tips of the sawtooth plate anode can reach 740-770 A/m2, which can reduce its service life as compared to flat plate anode. In area D, gas was more easily emitted from the wave plate anode than from the flat plate anode, reducing the influence of the gas barrier layer on the electrical contact between the sludge cake and the anode.

Removing Silicon from Feed Water by Electrocoagulation for Power Plant Boiler

Power plant boilers are suffering from fouling, which causes not only economic loss but also serious security risks. Of different deposits, silicate scale has the smallest thermal conductivity and can interact with other scales to form more hard scales, especially in the high silicon content regions. Therefore, the removal of silicon was studied in the experiment by electrocoagulation process. The reverse-electrode method and no-reverse-electrode method were applied to study the silicon removal efficiency and electrical energy consumption in the flocculation process. The results showed that the reverse-electrode method could lead to a higher removal efficiency and lower power consumption. In addition, the better time interval was 10min for reversing electrodes. Then the overpotentials determined in reverse-electrode method and no-reverse-electrode method was 0.74 and 1.31V respectively which essentially explains why the former method had a better effect.