Sidney Lin

Applications of CCTO supercapacitor in energy storage and electronics

Since the discovery of colossal dielectric constant in CCTO supercapacitor in 2000, development of its practical application to energy storage has been of great interest. In spite of intensive efforts, there has been thus far, no report of proven application. The object of this research is to understand the reason for this lack of success and to find ways to overcome this limitation. Reported herein is the synthesis of our research in ceramic processing of this material and its characterization, particularly with the objective of identifying potential applications. Experimental results have shown that CCTOs permittivity and loss tangent, the two most essential dielectric parameters of fundamental importance for the efficiency of a capacitor device, are intrinsically coupled. They increase or decrease in tandem. Therefore, efforts to simultaneously retain the high permittivity while minimizing the loss tangent of CCTO might not succeed unless an entirely non-typical approach is taken for processing this m...

Properties and Applications of Varistor–Transistor Hybrid Devices

The nonlinear current–voltage characteristics of a varistor device are modified with the help of external agents, resulting in tuned varistor–transistor hybrid devices with multiple applications. The substrate used to produce these hybrid devices belongs to the modified iron titanate family with chemical formula 0.55FeTiO3·0.45Fe2O3 (IHC45), which is a prominent member of the ilmenite–hematite solid-solution series. It is a wide-bandgap magnetic oxide semiconductor. Electrical resistivity and Seebeck coefficient measurements from room temperature to about 700°C confirm that it retains its p-type nature for the entire temperature range. The direct-current (DC) and alternating-current (AC) properties of these hybrid devices are discussed and their applications identified. It is shown here that such varistor embedded ceramic transistors with many interesting properties and applications can be mass produced using incredibly simple structures. The tuned varistors by themselves can be used for current amplification and band-pass filters. The transistors on the other hand could be used to produce sensors, voltage-controlled current sources, current-controlled voltage sources, signal amplifiers, and low-band-pass filters. We believe that these devices could be suitable for a number of applications in consumer and defense electronics, high-temperature and space electronics, bioelectronics, and possibly also for electronics specific to handheld devices.

Novel Combustion Route for SrTiO3 Powders

This paper describes the combustion synthesis (CS) of SrTiO3 using Ti, TiO2, and SrO2. The kinetics of the CS reaction and the effect of the Ti/(Ti+TiO2) ratio on the CS reaction were examined. The thermal behavior of each reactant and the mixture of reactant powders were investigated to study the reaction mechanism. As a result, the oxidation of Ti was found to trigger the CS reaction. The apparent activation energy of the CS reaction was calculated as 287.6 kJ/mol. The obtained results suggest a new route to produce commercially available highly dense ceramics.