Sigurdur T. Thoroddsen

Stabilization of Leidenfrost vapour layer by textured superhydrophobic surfaces

In 1756, Leidenfrost observed that water drops skittered on a sufficiently hot skillet, owing to levitation by an evaporative vapour film. Such films are stable only when the hot surface is above a critical temperature, and are a central phenomenon in boiling. In this so-called Leidenfrost regime, the low thermal conductivity of the vapour layer inhibits heat transfer between the hot surface and the liquid. When the temperature of the cooling surface drops below the critical temperature, the vapour film collapses and the system enters a nucleate-boiling regime, which can result in vapour explosions that are particularly detrimental in certain contexts, such as in nuclear power plants. The presence of these vapour films can also reduce liquid–solid drag. Here we show how vapour film collapse can be completely suppressed at textured superhydrophobic surfaces. At a smooth hydrophobic surface, the vapour film still collapses on cooling, albeit at a reduced critical temperature, and the system switches explosively to nucleate boiling. In contrast, at textured, superhydrophobic surfaces, the vapour layer gradually relaxes until the surface is completely cooled, without exhibiting a nucleate-boiling phase. This result demonstrates that topological texture on superhydrophobic materials is critical in stabilizing the vapour layer and thus in controlling—by heat transfer—the liquid–gas phase transition at hot surfaces. This concept can potentially be applied to control other phase transitions, such as ice or frost formation, and to the design of low-drag surfaces at which the vapour phase is stabilized in the grooves of textures without heating.

Spin-cast bulk heterojunction solar cells: a dynamical investigation.

Spin-coating is extensively used in the lab-based manufacture of organic solar cells, including most of the record-setting solution-processed cells. We report the first direct observation of photoactive layer formation as it occurs during spin-coating. The study provides new insight into mechanisms and kinetics of bulk heterojunction formation, which may be crucial for its successful transfer to scalable printing processes.

Air entrapment under an impacting drop

When a drop impacts on a liquid surface it entraps a small amount of air under its centre as the two liquid surfaces meet. The contact occurs along a ring enclosing a thin disk of air. We use the next-generation ultra-high-speed video camera, capable of 1 million f.p.s. (Etoh et al. ), to study the dynamics of this air sheet as it contracts due to surface tension, to form a bubble or, more frequently, splits into two bubbles. During the contraction of the air disk an azimuthal undulation, resembling a pearl necklace, develops along its edge. The contraction speed of the sheet is accurately described by a balance between inertia and surface tension. The average initial thickness of the air sheet decreases with higher impact Reynolds numbers, becoming less than one micron. The total volume of air entrapped depends strongly on the bottom curvature of the drop at impact. A sheet of micro-bubbles is often observed along the original interface. Oguz-Prosperetti bubble rings are also observed. For low Weber numbers (We < 20) a variety of other entrapment phenomena appear

The ejecta sheet generated by the impact of a drop

When a drop impacts on a liquid layer it ejects a thin horizontal sheet of liquid, emanating from the neck region connecting the two liquid masses. Dual-frame imaging and pulsed lasers are used to study the origin, speed and evolution of this ejecta sheet for a range of viscosities. The initial ejecta speed can be more than 10 times the impact velocity of the drop. Visualizations using fluorescent dye show the sheet originating from the underlying liquid layer, not the drop liquid. The sheet undergoes a characteristic instability, bending out of its plane and hitting the bottom layer. For some impact conditions the sheet folds in on itself.

The air bubble entrapped under a drop impacting on a solid surface

We present experimental observations of the disk of air caught under a drop impacting onto a solid surface. By imaging the impact through an acrylic plate with an ultra-high-speed video camera, we can follow the evolution of the air disk as it contracts into a bubble under the centre of the drop. The initial size and contraction speed of the disk were measured for a range of impact Weber and Reynolds numbers. The size of the initial disk is related to the bottom curvature of the drop at the initial contact, as measured in free-fall. The initial contact often leaves behind a ring of micro-bubbles, marking its location. The air disk contracts at a speed comparable to the corresponding air disks caught under a drop impacting onto a liquid surface. This speed also seems independent of the wettability of the liquid, which only affects the azimuthal shape of the contact line. For some impact conditions, the dynamics of the contraction leaves a small droplet at the centre of the bubble. This arises from a capillary wave propagating from the edges of the contracting disk towards the centre. As the wave converges its amplitude grows until it touches the solid substrate, thereby pinching off the micro-droplet at the plate, in the centre of the bubble. The effect of increasing liquid viscosity is to slow down the contraction speed and to produce a more irregular contact line leaving more micro-bubbles along the initial ring.

The coalescence speed of a pendent and a sessile drop

When two liquid drops come into contact, they coalesce rapidly, owing to the large curvature and unbalanced surface-tension forces in the neck region. We use an ultra-high-speed video camera to study the coalescence of a pendent and a sessile drop, over a range of drop sizes and liquid viscosities. For low viscosity, the outward motion of the liquid contact region is successfully described by a dynamic capillary-inertial model based on the local vertical spacing between the two drop surfaces. This model applies even when the drops are of different sizes. Increasing viscosity slows down the coalescence when the Reynolds number

Solution-Printed Organic Semiconductor Blends Exhibiting Transport Properties on Par with Single Crystals

\hbox{\it Re}_v \,{=}\,\rho R_{\hbox{\scriptsize\it ave}}\sigma/\mu^2\,{ , where

One-dimensional self-confinement promotes polymorph selection in large-area organic semiconductor thin films

R_{\hbox{\scriptsize\it ave}}

Experiments on bubble pinch-off

is the average of the tip radii of the two similar size drops,

von Kármán vortex street within an impacting drop.

\rho