Simona Silvia Merola

Time-resolved spectral and spatial description of laser-induced breakdown in air as a pulsed, bright, and broadband ultraviolet–visible light source

The optical breakdown induced in air at atmospheric pressure by Nd:YAG Q-switched laser pulses is studied in terms of the spectral features of the emitted radiation in the wavelength range 180-850 nm during the first 200 ns after the laser pulse onset. During the plasma build up, radiation emission features intense, broadband, and structureless ultraviolet-visible spectra before the appearence of atomic lines on the microsecond scale. Also, the emitting plasma kernel, imaged during the buildup and decay stages in the early tens of nanoseconds, turns out to have a size of ~0.3 mm and a volume of ~0.02 mm(3). The coupling of direct emission data and broadband absorption measurements allowed us to retrieve peak values of electron temperature above 100,000 K and of an optical depth of the order of unity, under the assumptions of local thermodynamic equilibrium and a homogeneous kernel. The simultaneous occurrence of such temporal, spatial, and spectral features of the plasma kernel suggests its exploitation as a pulsed, bright, and broadband ultraviolet-visible light source.

Validation of a Fractal Combustion Model through Flame Imaging

The paper is focused on the development of a fractal combustion model, included within a whole-engine one-dimensional model (1 Dime code). An extensive validation is carried out through the comparison with experimental data. The experimental activity was carried out in the combustion chamber of an optically accessible one-cylinder engine, equipped with a commercial head. Experimental data basically consisted on optical measurements which were also correlated to the instantaneous pressure inside the cylinder. Optical measurements were based on 2D digital imaging and UV chemiluminescence of radical species. The rate of chemical energy release and related parameters were evaluated from the in-cylinder pressure data using interpretation models for heat release analysis. Moreover a post-processing of the optical measurements allowed to define the mean flame radius, and propagation speeds as well, as a function of the crank angle. Theoretical and experimental analyses allowed to fully characterize flame structure and propagation speed as well. In order to estimate prediction levels and limitations of the numerical procedure, different engine speeds and spark timings were experimentally analyzed. A good agreement has been found in the whole tested range.

Study of the multi-injection combustion process in a transparent direct injection common rail diesel engine by means of optical techniques

Abstract A combination of ultraviolet—visible optical diagnostics has been applied in the combustion chamber of a diesel engine in order to study the fuel injection, autoignition, and soot formation processes. Measurements were made in an optically accessible diesel engine equipped with a multivalve cylinder head and a common rail (CR) high-pressure injection system. Several multi-injection strategies, characteristic of new generation CR diesel engines, were tested. They consisted of two (pre + main) and three (pre + main + post) injections per cycle. Fuel injection and visible combustion were studied by imaging the natural flame luminosity, and soot formation and evolution were evaluated by means of the two-colour pyrometry method. The reactions that occur during autoignition and soot formation were investigated by chemiluminescence imaging, while the broadband ultraviolet—visible extinction and scattering spectroscopy (BUVESS) technique was used in order to measure the soot particle size and number concentration. For all the injection strategies investigated, pre injection has contributed to the reduction of the ignition delay of the main injection. Moreover, the present study showed that autoignition can be characterized to some degree by the presence of the OH radical. The effect of post injection on combustion development and soot particle diameter has also been observed and discussed.

The Diesel Exhaust Aftertreatment (DEXA) Cluster: A Systematic Approach to Diesel Particulate Emission Control in Europe

The DEXA Cluster consisted of three closely interlinked projects. In 2003 the DEXA Cluster concluded by demonstrating the successful development of critical technologies for Diesel exhaust particulate after-treatment, without adverse effects on NO x emissions and maintaining the fuel economy advantages of the Diesel engine well beyond the EURO IV (2000) emission standards horizon. In the present paper the most important results of the DEXA Cluster projects in the demonstration of advanced particulate control technologies, the development of a simulation toolkit for the design of diesel exhaust after-treatment systems and the development of novel particulate characterization methodologies, are presented. The motivation for the DEXA Cluster research was to increase the market competitiveness of diesel engine powertrains for passenger cars worldwide, and to accelerate the adoption of particulate control technology.

Experimental investigations of butanol-gasoline blends effects on the combustion process in a SI engine

Fuel blend of alcohol and conventional hydrocarbon fuels for a spark-ignition engine can increase the fuel octane rating and the power for a given engine displacement and compression ratio. In this work, the influence of butanol addition to gasoline in a port fuel injection, spark-ignition engine was investigated. The experiments were realized in a single-cylinder ported fuel injection spark-ignition (SI) engine with an external boosting device. The optically accessible engine was equipped with the head of a commercial SI turbocharged engine with the same geometrical specifications (bore, stroke and compression ratio) as the research engine. The effect on the spark ignition combustion process of 20% and 40% of n-butanol blended in volume with pure gasoline was investigated through cycle-resolved visualization. The engine worked at low speed, medium boosting and wide-open throttle. Fuel injections both in closed-valve and open-valve conditions were considered. Comparisons between the parameters related to the flame luminosity and the pressure signals were performed. Butanol blends allowed working in more advanced spark timing without knocking occurrence. The duration of injection for butanol blends was increased to obtain a stoichiometric mixture. In open-valve injection condition, the fuel deposits on intake manifold and piston surfaces decreased, allowing a reduction in fuel consumption. BU40 granted the performance levels of gasoline and, in open-valve injection, allowed to minimize the abnormal combustion effects including the emission of ultrafine carbonaceous particles at the exhaust. In-cylinder investigations were correlated to engine out emissions.

Spectroscopic analysis and modeling of particulate formation in a diesel engine

Abstract Combined measurements of scattering and extinction coefficients in the UV–visible range have been used to characterize the particulate formed in an optically accessible divided-chamber diesel engine. Multi-wavelength spectroscopic analysis has shown the presence of two classes of particles: soot and organic aerosol. The latter structures absorb light radiation in the UV region and have sizes of 2– 3 nm . They are present just after fuel ignition and their concentration suddenly increases as the combustion proceeds, reaching a maximum value well before the formation of soot particles. Soot particles are characterized by light absorption extending in the visible range and show sizes of about 10 nm in the first stages of the inception process. A detailed kinetic mechanism has been used to model the formation of both classes of particles in high-pressure conditions. The kinetic scheme, coupled to a simplified model of diesel combustion, has been able to correctly predict the total concentration and the size of the particulates.

Analysis of exhausts emitted by i.c. engines and stationary burners, by means of u.v. extinction and fluorescence spectroscopy.

Optical investigations of the exhausts emitted by internal combustion (i.c.) engines and a stationary burner were performed, in order to assess their relative role as sources of organic matter to the atmosphere. Extinction spectra of air-diluted exhausts in the 200-400 nm u.v. band reveal the expected existence of gaseous trace-species (NO, NO2 and SO2) and carbonaceous particulate matter (soot). In addition, after subtracting the absorption contribution from known species, a strong residual absorption band remains below 250 nm, which is attributed to organic aromatic matter, involving no more than two aromatic rings. A set of ex situ extinction and laser induced fluorescence (LIF) experiments were carried out on condensed combustion-water samples. Extinction measurements from the water samples show absorption spectra similar to those observed from air-diluted samples, which are attributed to low volatility organic compounds, as they are trapped in the condensed phase. Combining the indications of extinction data for both air-diluted and condensed samples, it is suggested that the absorbing species might be molecular clusters of one/two aromatic rings. LIF spectra from condensed samples evidence two fluorescence bands, centered above 300 and 400 nm, respectively, whose intensities correlate with the combustion regimes. Analogous optical analysis on rain samples, collected in an urban area, showed that rain absorption and fluorescence spectra are similar to those found in condensed exhaust samples, which is consistent with the prevailing contribution of i.c. engines to the urban air pollution. The combined experimental data suggest that the absorbing and fluorescent species trapped in the condensed samples are organic (aromatic) compounds, involving mostly one two aromatic rings structural units, since they do not absorb above 250 nm. The overall molecular weight of the trapped material is likely heavy as they show low volatility.

Multiwavelength ultraviolet absorption spectroscopy of NO and OH radical concentration applied to a high-swirl diesel-like system

Ultraviolet absorption measurements were carried out in an optical research engine by exploiting the emitted plasma kernel of laser-induced breakdown. Temporal evolution and spatial distribution of OH radical and NO absolute concentrations were evaluated by a numerical procedure for retrieving optical data. Spectral measurements were made in an optically accessible external combustion chamber obtained by modifying a single cylinder, four-stroke diesel engine. The experiments were performed using a commercial diesel fuel at two engine speeds varying the ignition delay and fixing the injected fuel amount. In-chamber NO concentrations for each engine operating condition were correlated with those measured at the exhaust by a conventional method.

Knocking diagnostics in the combustion chamber of boosted port fuel injection spark ignition optical engine

High spatial resolution optical techniques have been used to get information about the timing and the location of knocking and about the chemical species involved in this phenomenon. The experiments were realised in the combustion chamber of a boosted single-cylinder spark ignition port-fuel injection optical engine fuelled with commercial gasoline. Engine conditions with different levels of knock were considered from the borderline case onto standard knocking and heavy knocking. Cycle-resolved digital imaging was used to follow the combustion and the flame propagation in normal combustion and knocking conditions. Moreover, the effects of an abnormal combustion due to the firing of fuel deposition near the intake valves and on the piston surface were investigated. The knocking influence on the flame front propagation and combustion speed was investigated following the time evolution of the mean flame radius in the different engine conditions. The appearance of the auto-ignition centres in the end gas during the knock was evaluated in terms of timing, location and frequency of occurrence. Finally, UV-visible natural emission spectroscopy was applied to detect radical species that marked the knock. HCO and OH were identified as markers of the knocking onset and OH of its intensity.

Effect of the Fuel-Injection Strategy on Flame-Front Evolution in an Optical Wall-Guided DISI Engine with Gasoline and Butanol Fueling

AbstractThis work investigates the effect of n-butanol on combustion processes in a direct injection spark ignition (DISI) engine through the analysis of flame front propagation. Specific attention is given to the sensitivity of n-butanol when changing injection mode in terms of timing and number of injections. Tests were carried out on an optically accessible single-cylinder DISI engine fueled with n-butanol and gasoline, alternatively. The engine is equipped with the head of a commercial turbocharged engine with similar geometrical specifications (bore, stroke, compression ratio). The head has four valves and a centrally located spark device. A conventional elongated hollow piston is used and an optical crown, accommodating a fused-silica window, is screwed onto it. The injector is side mounted and features six holes oriented so that the spray is directed toward the piston crown. During the experimental activity, injection pressure was maintained at 100 bar for all conditions; homogeneous charge conditi...