Sina Seipel

Characterization and optimization of an inkjet-printed smart textile UV-sensor cured with UV-LED light

For the development of niche products like smart textiles and other functional high-end products, resource-saving production processes are needed. Niche products only require small batches, which m ...

Inkjet printing and UV-LED curing of photochromic dyes for functional and smart textile applications

Health concerns as a result of harmful UV-rays drive the development of UV-sensors of different kinds. In this research, a UV-responsive smart textile is produced by inkjet printing and UV-LED curing of a specifically designed photochromic ink on PET fabric. This paper focuses on tuning and characterizing the colour performance of a photochromic dye embedded in a UV-curable ink resin. The influence of industrial fabrication parameters on the crosslinking density of the UV-resin and hence on the colour kinetics is investigated. A lower crosslinking density of the UV-resin increases the kinetic switching speed of the photochromic dye molecules upon isomerization. By introducing an extended kinetic model, which defines rate constants kcolouration, kdecay and kdecolouration, the colour performance of photochromic textiles can be predicted. Fabrication parameters present a flexible and fast alternative to polymer conjugation to control kinetics of photochromic dyes in a resin. In particular, industrial fabrication parameters during printing and curing of the photochromic ink are used to set the colour yield, colouration/decolouration rates and the durability, which are important characteristics towards the development of a UV-sensor for smart textile applications.

Resource-Efficient Production of a Smart Textile UV Sensor Using Photochromic Dyes: Characterization and Optimization

Niche products like smart textiles and other technical high-end products require resource-efficient processes and small batches contrary to conventional textile processes that require larger batches and are water-, chemical- and energy-intensive. This study focuses on digital inkjet printing and UV light curing as a flexible and resource-efficient and therewith economic production process of a smart textile UV sensor. The UV sensor is based on a UV-curable inkjet ink and a commercial photochromic dye. The inkjet ink is cured via free radical polymerization initiated by a UV–LED lamp. This system contains two photoactive compounds for which UV light both cures and activates the prints. An important challenge is therefore polymer crosslinking of the resin and UV-sensing performance of the photochromic dye. In this paper, we present performance as a function of belt speed and lamp intensity during curing. Via wash tests, we investigate the durability of the photochromic prints. The UV-sensing textile is characterized by colour measurements, differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA).