Siti Masrinda Tasirin

CFD Evaluation of Droplet Drying Models in a Spray Dryer Fitted with a Rotary Atomizer

Computational fluid dynamics (CFD) modeling of spray dryers requires a simple but sufficiently realistic drying model. This work evaluates two such models that are currently in discussion; reaction engineering approach (REA) and characteristic drying curve (CDC). Two versions of the CDC, linear and convex, drop in drying rate were included. Simulation results were compared to the overall outlet conditions obtained from our pilot-scale experiments. The REA and CDC with a linear drop in drying rate predicted the outlet conditions reasonably well. This is contrary to the kinetics determined previously. Analysis shows that the models exhibit different responses to changes in the initial feed moisture content. Utilizing different models did not result in significantly different particle trajectories. This is due to the low relaxation time of the particles. Despite the slight differences in the drying curves, both models predicted similar particle rigidity depositing the wall. For the first time in a CFD simulation, the REA model was extended to calculate the particle surface moisture, which showed promising results for wet particles. Room for improvement was identified when applying this concept for relatively dry particles.

Entrainment of FCC from fluidized beds — A new correlation for the elutriation rate constants Ki∞*

Batch and continuous experiments of fluidization have been carried out in columns of diameter 76 and 152 mm. Gas velocities of 0.1–0.8 m/s were used with mixtures of coarse and fine FCC as the feed materials. The total entrainment flux EZ and the elutriation rate constants Ki∞* are found to depend on the gas velocity in the form of EZ ∝ Un and Ki∞* ∝ Um, respectively. The values of n and m depend on the bed compositions and particle size; they become smaller at higher gas velocities. For FCC, n has an average value of 4.0 in the velocity range 0.2–0.4 m/s and tends to a value of 2 at higher gas velocities. The effect of column diameter depends on the gas velocity profiles and is reduced for column diameters above 0.1 m. Empirical correlations to predict Ki∞* and EZ have been developed from the results.

Effect of Wall Surface Properties at Different Drying Kinetics on the Deposition Problem in Spray Drying

Current methods in alleviating the wall deposition problem in spray drying emphasize mainly controlling the stickiness of the drying particles and less attention is placed on the properties of the dryer wall. In this experimental study, the effect of wall surface properties on the deposition mechanism has been investigated. Properties considered in classifying different wall materials were surface energy, roughness, and dielectric properties. The model solution contained sucrose, representing low-molecular-weight sugars commonly encountered in spray drying of fruit and vegetable juices. The effect of wall properties on deposition was explored at different drying rates producing particles of different surface rigidity. Larger surface roughness produced higher deposition fluxes for particles with high impact velocity and moisture. Surface energy and surface roughness were found to have no significant effect for dry rigid particles at the middle and bottom elevation of the drying chamber. However, material with lower surface energy (Teflon) exhibited less deposition for rubbery particles at such elevations. Analysis shows that dielectric wall material (Teflon) tends to enhance deposition of dry particles because of attrition at the surface. Higher wall temperature was found to produce slightly more deposition. The results of this work give a general indication of the effect of wall material on the deposition problem and provide the fundamental understanding for further studies along this line. Proper selection of dryer wall material will provide potential alternatives for reducing the deposition problem.

Experimental investigation on fluidized bed jet grinding

Abstract The industrial uses of fluidized bed jet grinding are increasing but the basic mechanism of comminution within such a mill is not well-understood and their design and prediction of performance is therefore largely very empirical. The effects of free jet velocity, separation distance and the geometry of the set-up on the initial rate of grinding of coarse cracking catalyst have been studied using 2 mm i.d. nozzles.

Optimization of the Spray Drying Operating Parameters—A Quick Trial-and-Error Method

This short communication reports an optimization approach to effectively determine suitable spray drying operating parameters for a pilot-scale dryer. The proposed optimization approach is essential, as pilot-scale investigations and medium-scale contract productions often involve usage of standard spray dryer units which is not specifically designed for the feed material used. This optimization approach was developed based on past studies on the effect and relationship of the many spray drying operating parameters and highlights two factors which has to be solved (or considered) chronologically: dripping problem, followed by product caking problem. Based on this proposed approach, an algorithm was developed in a case study to optimize an available spray dryer for our future experimental study on wall deposition. In this case, the operating parameters were determined under minimal experimental runs. This proposed optimization approach will be a useful tool for operators and experimenters utilizing spray dryers of similar type, particularly in exploring new feed materials. Depending on the optimization objectives and experimental limitations, different algorithms can be developed. Apart from that, interesting deposition pattern was also observed in the case study. This short communication also reported on the design of an internal rig for further studies on wall deposition.

Drying Kinetics of Oil Palm Frond Particles in an Agitated Fluidized Bed Dryer

The drying kinetics of oil palm frond particles in a laboratory-scale agitated fluidized bed dryer were investigated under various operating conditions: inlet air temperature (50–80°C), superficial air velocity (0.6–1.0 m/s), bed load (200–300 g), and agitation speed (300–500 rpm). To study the effects of these variables on the drying time and drying rate, an experimental design using Taguchi orthogonal array was employed. Based on analysis of variance (ANOVA), the results indicated that inlet air temperature greatly affected the drying rate, followed by superficial air velocity and bed load. The effect of agitation speed on the drying rate was found to be small. The experimental drying kinetics data were compared with the values obtained from three different models, namely, the Page model, modified quasi-stationary method (MQSM), and a new composite model. It was found that the proposed new model could satisfactorily predict the complete drying rate curve for the drying of oil palm fronds.

A New Variable Diffusion Drying Model for the Second Falling Rate Period of Paddy Dried in a Rapid Bin Dryer

Abstract The objectives of this article is to propose a new drying model for the second falling rate period known as the variable diffusion controlled period that follows after the first falling rate period and to propose a new method to determine the second critical moisture content that separates these two periods. Experimental work on paddy drying at minimum fluidization velocity was carried out in a rapid bin dryer. The effects of operating temperatures (60–120°C) and bed depths (2–6 cm) on the paddy drying characteristics were investigated. It was found that the normalized drying rate of paddy was proportional to the normalized moisture content in the first falling rate period but in the second falling rate period, the normalized drying rate of the material varies exponentially with the normalized moisture content. The different relationship between the normalized drying rate and the normalized moisture content in the first and second falling rate periods indicate that two different mechanism of moisture transport are at work. The new exponential model of the second falling rate period and the linear model of the first falling rate period were found to fit the experimental data very well. Derivation from variable diffusion equation shows that the linear model is the result of constant diffusion coefficient whereas the new exponential model is the result of linear diffusion coefficient. This also implies that the first falling rate period is a constant diffusion controlled period and the second falling rate period is a variable diffusion controlled period. In addition, drying kinetics data of a drying process that fits the exponential model over a very slow drying period will show that the drying process is under the effect of a linear diffusion coefficient. It was also found that the proposed new method to determine the second critical moisture content that distinguishes between the first and second falling rate periods by using a sudden change in the value of the drying rate gradient to a much lower value at that point is more rigorous and yet simpler than the method of determining the specific location of the receding drying boundary since it is based on the behavior of the actual drying kinetic data.

Review of hydrogen production via glycerol reforming

Owing to the high energy content of hydrogen and the possibility of converting this energy in fuel cell devices into electric power without any pollutant emissions, hydrogen has grown to be one of the most useful sources of energy, especially if it is produced from renewable sources. In recent years, the development of an efficient process for hydrogen production has become an important goal for energy researchers. Numerous studies have evaluated the catalytic reforming of glycerol for hydrogen production both experimentally and thermodynamically. To enhance hydrogen production and make the production process efficient, researchers have investigated different reforming processes under a wide range of operating conditions. Moreover, the main focus of these studies was the development of a high-performance reforming catalyst that can increase the hydrogen yield and decrease carbon formation and processing costs. Several reforming processes can be used to produce hydrogen from glycerol. This article reviews these reforming processes with emphasis on the common catalysts and the operating conditions used in thermodynamic analyses and experimental work. Although most of these studies have been conducted on steam and aqueous-phase reforming processes, more work on other reforming processes, such as autothermal reforming, partial oxidation, supercritical water, and photo-catalytic reforming, has yet to be completed.

Au/TiO2 Reusable Photocatalysts for Dye Degradation

Nanogold doped TiO2 catalysts are synthesized, and their application in the photodegradation of dye pollutants is studied. The materials are characterized using different analytical techniques such as X-ray diffraction, transmission electron microscopy, UV-visible diffuse reflectance spectroscopy, and X-ray photoelectron spectroscopy. The results revealed the strong interaction between the metallic gold nanoparticles and the anatase TiO2 support. Au doped systems showed very good photoactivity in the degradation of dye pollutants under UV irradiation as well as in sunlight. A simple mechanism is proposed for explaining the excellent photoactivity of the systems. The reusability studies of the photocatalysts exhibited more than 98% degradation of the dye even after 10 repeated cycles.

Drying of Citrus sinensis Peels in an Inert Fluidized Bed: Kinetics, Microbiological Activity, Vitamin C, and Limonene Determination

Citrus sinensis peel drying kinetics in a fluidized bed with inert material were investigated. Drying impact on microbiological activity as well as limonene and vitamin C content was also studied. Drying parameters studied were as follows: temperatures of 40°C, 50°C, and 60°C; air velocities of 0.73 m/s and 0.85 m/s; and orange peel:sand weight ratios of 1:0, 1:1, and 1:2. High temperatures, high air velocity, and the presence of inert material increased the drying rate. Nine thin-layer drying models were fitted to the experimental data of Citrus sinensis peels. The Midilli et al. model was found to be the most suitable model for describing the drying kinetics of Citrus sinensis peels. Vitamin C and limonene content were higher in the product dried using a fluidized bed than in the sun-dried product. Drying of Citrus sinensis peel in a fluidized bed also may reduce microorganism growth, increasing storage life.