Sophie Cazottes

M23C6 carbides and Cr2N nitrides in aged duplex stainless steel: A SEM, TEM and FIB tomography investigation

The precipitation evolution during ageing of a 2101 lean duplex stainless steel was investigated, revealing that the precipitate type and morphology depends on the nature of the grain boundary. Triangular M23C6 carbides precipitate only at γ/δ interfaces and rod-like Cr2N nitrides precipitate at both γ/δ and δ/δ interfaces. After 15min of ageing, the M23C6 size no longer evolves, whereas that of the Cr2N continues to evolve. For Cr2N, the morphology is maintained at γ/δ interfaces, whereas percolation occurs to form a continuous layer at δ/δ interfaces. By combining 2D and 3D characterisation at the nanoscale using transmission electron microscopy (TEM) and focused ion beam (FIB) tomography, a complete description of the precipitation evolution was obtained, including the composition, crystallographic structure, orientation relationship with the matrix phases, location, morphology, size and volume fraction.

Influence of microstructure on the fretting resistance of Al-Cu-Li alloys

The resistance of two Al-Cu-Li alloys (2050 and 2196) to fretting has been investigated. For each material two heat treatments have been studied (T8 and low temperature ageing). Fretting tests with a cylinder-plane configuration have been performed in the partial slip regime. The results obtained show that the low temperature temper gives a better resistance to fretting crack initiation and propagation than the T8 temper for both alloys. The 3D shape of the fretting cracks has been observed by high resolution synchrotron X-ray tomography. Multiple initiation sites were observed below the contact. In their early stages of development, the fretting cracks grow approximately radially within the material leading to thumb nail cracks which eventually merge laterally. The difference in fretting resistance is analysed with respect to the 3D fracture surface of the fretting cracks in relation with the alloys precipitation state.