Sören Fröjdö

1.8 Ga Svecofennian post-collisional shoshonitic magmatism in the Fennoscandian shield

Abstract At least 14 small (1–11 km across) 1.8 Ga Svecofennian post-collisional bimodal intrusions occur in southern Finland and Russian Karelia in a 600-km-long belt from the Aland Islands to the NW Lake Ladoga region. The rocks range from ultramafic, calc-alkaline, apatite-rich potassium lamprophyres to peraluminous HiBaSr granites, and form a shoshonitic series with K 2 O+Na 2 O>5%, K 2 O/Na 2 O>0.5, Al 2 O 3 >9% over a wide spectrum of SiO 2 (32–78%). Although strongly enriched in all rocks, the LILE Ba and Sr and the LREE generally define a decreasing trend with increasing SiO 2 . Depletion is noted for HFSE Ti, Nb and Ta. Available isotopic data show overlapping values for lamprophyres and granites within separate intrusions and a cogenetic origin is thus not precluded. Initial magmas (Mg#>65) in this shoshonitic association are considered to be generated in an enriched lithospheric mantle during post-collisional uplift some 30 Ma after the regional Svecofennian metamorphic peak. However, prior to the melting episode, the lithospheric mantle was affected by carbonatite metasomatism; more extensively in the east than in the west. The melts generated in the more carbonate-rich mantle are extremely enriched in P 2 O 5 ∼4%, F∼12,000 ppm, LILE: Ba∼9000 ppm, Sr∼7000 ppm, LREE: La∼600 ppm and Ce∼1000 ppm. The parental magma underwent 55–60% fractionation of biotite+clinopyroxene+apatite+magnetite+sphene whereupon intermediate varieties were produced. After further fractionation, 60–80%, of K-feldspar+amphibole+plagioclase±(minor magnetite, sphene and apatite), leucosyenites and quartz-monzonites were formed. In the west, where the source was less affected by carbonatite metasomatism, calc-alkaline lamprophyres (vogesites, minettes and spessartites) and equivalent plutonic rocks (monzonites) were formed. Removal of about 50% of biotite, amphibole, plagioclase, magnetite, apatite and sphene produced peraluminous HiBaSr granites. The impact of crustal assimilation is considered to be low. At about 1.8 Ga, the post-collisional shoshonitic magmatism brought juvenile material, particularly enriched in alkalis, LILE, LREE and F, into the crust. Although areally restricted, the regional distribution of the post-collisional intrusions may indicate that larger volumes of 1.8 Ga juvenile material resides in unexposed parts of the crust.

1.8 Ga magmatism in southern Finland: strongly enriched mantle and juvenile crustal sources in a post-collisional setting

Whole-rock and isotope geochemistry of six ∼1.8 Ga post-kinematic intrusions, emplaced along the ∼1.9 Ga Southern Svecofennian Arc Complex (SSAC) and in the SW part of the Karelian Domain in Finland, was studied. The intrusive age [U–Pb secondary ion mass spectrometer (SIMS)] of one of these, the Petravaara Pluton, was determined as 1811 ± 6 Ma. Basic-intermediate rocks are alkali-rich (K2O + Na2O > 4 wt.%) and typically shoshonitic, strongly enriched in large ion lithophile elements and light rare earth elements, but relatively depleted in high field strength elements and heavy rare earth elements. The enrichment is much higher than can be accounted for by crustal contamination and requires previously melt-depleted mantle sources, subjected to variable metasomatism by carbonate-rich fluids and sediment-derived melts. These sources are inferred to consist of phlogopite ± amphibole-bearing peridotites from depths below the spinel–garnet transition, as shown by the high Ce/Yb ratios. 87Sr/86Sr(1.8 Ga) ratios in the range 0.7027–0.7031 and ‘mildly depleted’ ϵNd(1.8 Ga) values (+0.1 to +1.4), with T DM values <2.1 Ga, suggest that mantle enrichment was associated with the previous Svecofennian subduction–accretion process, when enriched sub-Svecofennian mantle sections developed, dominantly characterized by 147Sm/144Nd ratios of 0.14–0.17. The associated granitoids are diversified. One group is marginally peraluminous, transitional between I (volcanic-arc) and S (syn-collisional) types, and was derived from mixed igneous and sedimentary, but juvenile Svecofennian source rocks, as supported by near-chondritic ϵNd(1.8 Ga) and somewhat elevated 87Sr/86Sr(1.8 Ga). The other group is transitional between I and A (within-plate) types in character and had dominantly igneous protoliths. The whole-rock geochemistry and isotopes suggest that the compositional variation between ∼50 and 70 wt.% SiO2 may be explained by hybridization between strongly enriched mantle-derived magmas and anatectic granitic magmas from the juvenile Svecofennian crust. One intrusion in the east contains a significant portion of Archaean, mostly igneous protolithic material (ϵNd(1.8 Ga) = –2.8 and ϵHf(t) for zircons between +2.8 and −11.9, with an average of −4.9). The ∼1.8 Ga post-kinematic intrusions were emplaced within the SSAC subsequent to the continental collision with the Volgo-Sarmatia craton from the SE, during a shift from contraction to extension, that is, in a post-collisional setting.

An analytical procedure for determination of sulphur species and isotopes in boreal acid sulphate soils and sediments

An analytical scheme suitable for boreal acid sulphate (AS) soils and sediments was developed on the basis of existing methods. The presented procedure can be used to quantify and discriminate among acid volatile sulphide, cold chromium reducible sulphur, hot chromium reducible sulphur, elemental sulphur, sulphate sulphur, organic sulphur, total reducible sulphur and total sulphur. The sulphur fractions are recovered as either Ag2S or BaSO4 precipitates and can further be used for isotope analysis. Overlaps between sulphur species are common during speciation, and must be minimized. Some of these overlaps are caused by poor sampling and storage, inappropriate conditions during the distillation, or natural variations in the sample (e.g. Fe 3+ interference and grain size). The procedural impact was determined by conducting tests on both artificial and natural samples containing one or several sulphur species. The method is applied on reduced sediment from an AS soil locality (Overpurmo) and a brackish lake (Larsmo Lake) in western Finland and the results, including S-isotopes, are discussed.

Palaeomagnetism and U–Pb geochronology of c. 1570 Ma intrusives from Åland archipelago, SW Finland – implications for Nuna

Abstract We report new palaeomagnetic and isotope age data of Early Mesoproterozoic (i.e. Subjotnian) intrusions from the Åland archipelago, SW Finland. The palaeomagnetic results reveal dual-polarity magnetizations with a pronounced reversal asymmetry occurring in dykes. We explain the asymmetry by an unremoved secondary component, which is affecting more N-polarity dykes. Other explanations, such as the age difference of magnetization between normal and reversed polarity dykes, are discussed. The primary nature of magnetization in dykes for both normal (N) and reversed (R) groups is verified by positive baked contact tests. A dyke showing reversed polarity from Korsö is dated 1575.9±3.0 Ma (U–Pb) in this study. This and previous U–Pb data tighten the magmatic activity in Åland to 1580–1570 Ma. We combined new palaeomagnetic data with those from earlier studies to provide a new key-palaeomagnetic pole for Baltica. Our data positions Baltica on equatorial latitudes, supporting the NENA (North Europe–North America) connection between Baltica and Laurentia at 1.59–1.58 Ga. Palaeomagnetic data support that NENA was valid at 1.75, 1.58, 1.46, and 1.26 Ga, forming the core of Mesoproterozoic Nuna (a.k.a. Columbia) supercontinent.

Intra-orogenic Svecofennian magmatism in SW Finland constrained by LA-MC-ICP-MS zircon dating and geochemistry

We have studied plutonic rocks from the Korpo and Rauma areas of south-western Finland which can be categorized as intra-orogenic, i.e. they were intruded during a proposed extensional period between the two main Svecofennian orogenic cycles: the Fennian and Svecobaltic orogenies. The diorite from Rauma yielded an age of 1865 ± 9 Ma and the diorite from Korpo an age of 1852 ± 4 Ma. The adjacent garnet-bearing Korpo granite was 1849 ± 8 Ma in age. Zircons from the granite also included inherited Archaean and older Palaeoproterozic zircons, as well as metamorphic c. 1820 Ma rims. The diorites are high-K to shoshonitic, mantle-derived magmas, rich in Fe, P, F and light rare earth elements. The Korpo granites show typical features of crustal-derived melts and form hybrids with the diorites in contact zones. Both the mantle-derived and crustal-derived intra-orogenic magmatism are considered to have had a causal effect on the subsequent late Svecofennian (Svecobaltic) thermal evolution in southern Finland which culminated in granulite facies metamorphism and large-scale crustal melting.