Stefan Yoshi Buhmann

Dispersion forces in macroscopic quantum electrodynamics

The description of dispersion forces within the framework of macroscopic quantum electrodynamics in linear, dispersing and absorbing media combines the benefits of approaches based on normal-mode techniques of standard quantum electrodynamics and methods based on linear-response theory in a natural way. It renders generally valid expressions for both the forces between bodies and the forces on atoms in the presence of bodies while showing very clearly the intimate relation between the different types of dispersion forces. By considering examples, the influence of various factors like form, size, electric and magnetic properties, or intervening media on the forces is addressed. Since the approach based on macroscopic quantum electrodynamics does not only apply to equilibrium systems, it can be used to investigate dynamical effects such as the temporal evolution of forces on arbitrarily excited atoms.

Electromagnetic-field quantization and spontaneous decay in left-handed media

We present a quantization scheme for the electromagnetic field interacting with atomic systems in the presence of dispersing and absorbing magnetodielectric media, including left-handed material having negative real part of the refractive index. The theory is applied to the spontaneous decay of a two-level atom at the center of a spherical free-space cavity surrounded by magnetodielectric matter of overlapping band-gap zones. Results for both big and small cavities are presented, and the problem of local-field corrections within the real-cavity model is addressed.

Casimir-polder forces: A nonperturbative approach

Within the frame of macroscopic QED in linear, causal media, we study the radiation force of Casimir-Polder type acting on an atom which is positioned near dispersing and absorbing magnetodielectric bodies and initially prepared in an arbitrary electronic state. It is shown that minimal and multipolar coupling lead to essentially the same lowest-order perturbative result for the force acting on an atom in an energy eigenstate. To go beyond perturbation theory, the calculations are based on the exact center-of-mass equation of motion. For a nondriven atom in the weak-coupling regime, the force as a function of time is a superposition of force components that are related to the electronic density matrix elements at a chosen time. Even the force component associated with the ground state is not derivable from a potential in the ususal way, because of the position dependence of the atomic polarizability. Further, when the atom is initially prepared in a coherent superposition of energy eigenstates, then temporally oscillating force components are observed, which are due to the interaction of the atom with both electric and magnetic fields.

Thermal Casimir versus Casimir-Polder forces: equilibrium and nonequilibrium forces.

We critically discuss whether and under what conditions Lifshitz theory may be used to describe thermal Casimir-Polder forces on atoms or molecules. An exact treatment of the atom-field coupling reveals that for a ground-state atom (molecule), terms associated with virtual-photon absorption lead to a deviation from the traditional Lifshitz result; they are identified as a signature of nonequilibrium dynamics. Even the equilibrium force on a thermalized atom (molecule) may be overestimated when using the ground-state polarizability instead of its thermal counterpart.

Directional spontaneous emission and lateral Casimir-Polder force on an atom close to a nanofiber

We study the spontaneous emission of an excited atom close to an optical nanofiber and the resulting scattering forces. For a suitably chosen orientation of the atomic dipole, the spontaneous emission pattern becomes asymmetric and a resonant Casimir-Polder force parallel to the fiber axis arises. For a simple model case, we show that such a lateral force is due to the interaction of the circularly oscillating atomic dipole moment with its image inside the material. With the Casimir\char21{}Polder energy being constant in the lateral direction, the predicted lateral force does not derive from a potential in the usual way. Our results have implications for optical force measurements on a substrate as well as for laser cooling of atoms in nanophotonic traps.

Thermal Casimir-Polder shifts in Rydberg atoms near metallic surfaces

The Casimir-Polder (CP) potential and transition rates of a Rydberg atom above a plane metal surface at finite temperature are discussed. As an example, the CP potential and transition rates of a rubidium atom above a copper surface at 300 K are computed. Close to the surface we show that the quadrupole correction to the force is significant and increases with increasing principal quantum number n. For both the CP potential and decay rates one finds that the dominant contribution comes from the longest wavelength transition and the potential is independent of temperature. We provide explicit scaling laws for potential and decay rates as functions of atom-surface distance and principal quantum number of the initial Rydberg state.

Body-assisted van der Waals interaction between two atoms

Using fourth-order perturbation theory, a general formula for the van der Waals potential of two neutral, unpolarized, ground-state atoms in the presence of an arbitrary arrangement of dispersing and absorbing magnetodielectric bodies is derived. The theory is applied to two atoms in bulk material and in front of a planar multilayer system, with special emphasis on the cases of a perfectly reflecting plate and a semi-infinite half space. It is demonstrated that the enhancement and reduction of the two-atom interaction due to the presence of a perfectly reflecting plate can be understood, at least in the nonretarded limit, by using the method of image charges. For the semi-infinite half space, both analytical and numerical results are presented.

Ground-state van der Waals forces in planar multilayer magnetodielectrics

Within the frame of lowest-order perturbation theory, the van der Waals potential of a ground-state atom placed within an arbitrary dispersing and absorbing magnetodielectric multilayer system is given. Examples of an atom situated in front of a magnetodielectric plate or between two such plates are studied in detail. Special emphasis is placed on the competing attractive and repulsive force components associated with the electric and magnetic matter properties, respectively, and conditions for the formation of repulsive potential walls are given. Both numerical and analytical results are presented.

Macroscopic quantum electrodynamics in nonlocal and nonreciprocal media

We formulate macroscopic quantum electrodynamics in the most general linear, absorbing media. In particular, Onsager reciprocity is not assumed to hold. The field quantization is based on the source-quantity representation of the electromagnetic field in terms of the dyadic Greens tensor. For media with a nonlocal response, a description in terms of a complex conductivity tensor is employed. As an alternative description, we introduce the permittivity, permeability and magnetoelectric susceptibilities to obtain an explicitly duality-invariant scheme. We find that duality invariance only holds as a continuous symmetry when nonreciprocal responses are allowed for.

Probing Atom-Surface Interactions by Diffraction of Bose-Einstein Condensates

In this article we analyze the Casimir-Polder interaction of atoms with a solid grating and an additional repulsive interaction between the atoms and the grating in the presence of an external laser source. The combined potential landscape above the solid body is probed locally by diffraction of Bose-Einstein condensates. Measured diffraction efficiencies reveal information about the shape of the Casimir-Polder interaction and allow us to discern between models based on a pairwise-summation (Hamaker) approach and Lifshitz theory.