Stefano Riva-Sanseverino

Integrated Optic Surface Plasmon Resonance Measurements in a Borosilicate Glass Substrate

The surface plasmon resonance (SPR) technique is a well-known optical method that can be used to measure the refractive index of organic nano-layers adsorbed on a thin metal film. Although there are many configurations for measuring biomolecular interactions, SPR-based techniques play a central role in many current biosensing experiments, since they are the most suited for sensitive and quantitative kinetic measurements. Here we give some results from the analysis and numerical elaboration of SPR data from integrated optics experiments in a particular borosilicate glass, chosen for its composition offering the rather low refractive index of 1.4701 at 633 nm wavelength. These data regard the flow over the sensing region (metal window) of different solutions with refractive indexes in the range of interest (1.3÷1.5) for the detection of contaminants in aqueous solutions. After a discussion of the principles of SPR, of the metal window design optimization by means of optical interaction numerical modeling, and of waveguide fabrication techniques, we give a description of system setup and experimental results. Optimum gold film window thickness and width in this guided-wave configuration has been for the first time derived and implemented on an integrated optic prototype device. Its characterization is given by means of the real time waveguide output intensity measurements, which correspond to the interaction between the sensing gold thin film window and the flowing analyte. The SPR curve was subsequently inferred. Finally, a modified version of the device is reported, with channel waveguides arranged in a Y-junction optical circuit, so that laser source stability requirements are lowered by a factor of 85 dB, making possible the use of low cost sources in practical applications.

Continuous-wave backward frequency doubling in periodically poled lithium niobate

We report on backward second-harmonic-generation in bulk periodically poled congruent lithium niobate with a 3.2 μm period. A tunable continuous-wave Ti:sapphire laser allowed us exciting two resonant quasi-phase-matching orders in the backward configuration. The resonances were also resolved by temperature tuning and interpolated with standard theory to extract relevant information on the sample.

Guided-wave frequency doubling in surface periodically poled lithium niobate: competing effects

We carried out second-harmonic generation in quasi-phase-matched α-phase lithium niobate channel waveguides realized by proton exchange and surface periodic poling. Owing to a limited ferroelectric domain depth, we could observe the interplay between second-harmonic generation and self-phase modulation due to cascading and cubic effects, resulting in a nonlinear resonance shift. Data reduction allowed us to evaluate both the quadratic nonlinearity in the near infrared as well as the depth of the uninverted domains.

Nonstoichiometric silica mask for fabricating reverse proton-exchanged waveguides in lithium niobate crystals

Producing channel waveguides requires a photolithographic mask, but the standard technique of using thermally evaporated metal films for proton exchange has proved to be unsuitable for withstanding the rather aggressive process of reverse proton exchange. We report the fabrication of a nonstoichiometric silica mask by ion-plating plasma-assisted deposition. This mask is strong enough to resist both direct and reverse proton exchange and is also compatible with anisotropic dry etching for patterning the mask and with electric field poling. Our technique is a practical alternative to the use of SiO2 sputtered masks.

Frequency doubling in surface periodically poled lithium niobate waveguides: competing effects

We fabricated alpha-phase proton-exchanged (PE) lithium niobate (LN) channel waveguides quasi phase-matched (QPM) via surface periodic poling (SPP) and carried out the first experimental demonstration of second harmonic generation (SHG) in such devices. In order to quantitatively interpret the experimental data, we took into account not only the periodically-poled transverse region providing 1st-order QPM, but also the homogeneously-inverted portion of the waveguides extending below the shallow domains. By a numerical fit of the data we found that, because of the shallow non-inverted domains with depth of the order of 430nm (to be compared with a waveguide depth of 2.6mm), a cascaded process in phase-mismatch gives rise to an effective self-defocusing response which combines with the cubic nonlinearity of the material to provide the measured SHG resonance shift with power.

Ultraviolet quasi-phase-matched second harmonic generation in surface periodically poled lithium niobate optical waveguides

The compatibility of low concentration (α-phase) proton exchange channel waveguides with electric field surface periodic poling of congruent lithium niobate (SPPLN) crystals has been experimentally demonstrated. With such waveguides, we obtained ultraviolet second harmonic generation (SHG) by first order quasi-phase-matching (QPM), a result made possible by the fabrication, on Z-cut LN crystals, of periodic structures with a pitch down to 750 nm. Nonlinear copropagating QPM-SHG measurements have been carried out on such structures. The pump source was a Ti:sapphire laser with a tunability range of 700–980 nm and a 40 GHz linewidth. We have measured UV continuous wave light at 390 nm by means of a lock-in amplifier and a photodiode with an enhanced response in the UV. The measured conversion efficiency was about 1% W−1 cm−2.

NANOTECHNOLOGY IN LITHIUM NIOBATE FOR INTEGRATED OPTIC FREQUENCY CONVERSION IN THE UV

In the domain of Earth Explorer satellites nanoengineered nonlinear crystals can optimize UV tunable solid-state laser converters. Lightweight sources can be based on Lithium Niobate (LN) domain engineering by electric field poling and guided wave interactions. In this Communication we report the preliminary experimental results and the very first demonstration of UltraViolet second-harmonic generation by first-order quasi-phase-matching in a surface-periodically-poled proton-exchanged LN waveguide. The pump source was a Ti-Sapphire laser with a tunability range of 700- 980 nm and a 40 GHz linewidth. We have measured UV continuous-wave light at 390 nm by means of a lock-in amplifier and of a photodiode with enhanced response in the UV. Measured conversion efficiency was about 1%W-1cm-2. QPM experiments show good agreement with theory and pave the way for a future implementation of the technique in materials less prone to photorefractive damage and wider transparency in the UV, such as Lithium Tantalate.

Nanopatterned Ferroelectric Crystals for Parametric Generation

We report on recent results by surface periodic poling on lithium niobate and lithium tantalate. Such approach allows periodic inversion of the second order susceptibility with nanoscale features using insulating masks. We achieved a world-best 200 nm feature size, as well as good compatibility with alpha-phase proton exchanged channel waveguides in lithium niobate. Preliminary results of surface periodic poling in lithium tantalate also show similar characteristics. Surface poling is best suited for integrated optics devices in technologically-demanding configurations such as backward second harmonic generation and counter propagating optical parametric amplification