Stephan Ker

Hydrate dissolution as a potential mechanism for pockmark formation in the Niger delta

Received 17 February 2010; accepted 9 March 2010; published 11 August 2010. [1] Based on acquired geophysical, geological and geotechnical data and modeling, we suggest hydrate dissolution to cause sediment collapse and pockmark formation in the Niger delta. Very high‐resolution bathymetry data acquired from the Niger delta reveal the morphology of pockmarks with different shapes and sizes going from a small ring depression surrounding an irregular floor to more typical pockmarks with uniform depression. Geophysical data, in situ piezocone measurements, piezometer measurements and sediment cores demonstrate the presence of a common internal architecture of the studied pockmarks: inner sediments rich in gas hydrates surrounded by overpressured sediments. The temperature, pressure and salinity conditions of the studied area have allowed us to exclude the process of gas‐hydrate dissociation (gas hydrate turns into free gas/water mixture) as a trigger of the observed pockmarks. Based on numerical modeling, we demonstrate that gas‐hydrate dissolution (gas hydrate becomes mixture of water and dissolved gas) under a local decrease of the gas concentration at the base of the gas‐hydrate occurrence zone (GHOZ) can explain the excess pore pressure and fluid flow surrounding the central hydrated area and the sediment collapse at the border of the GHOZ. The different deformation (or development) stages of the detected pockmarks confirm that a local process such as the amount of gas flow through faults rather than a regional one is at the origin of those depressions.

Evidence from three-dimensional seismic tomography for a substantial accumulation of gas hydrate in a fluid-escape chimney in the Nyegga pockmark field, offshore Norway

In recent years, it has become evident that features commonly called gas chimneys provide major routes for methane to pass through the methane-hydrate stability zone in continental margins and escape to the ocean. One of many such chimneys lying beneath pockmarks in the southeastern Voring Plateau off Norway was investigated with a high-resolution seismic experiment employing a 2-D array of sixteen 4-component ocean bottom seismic recorders at approximately 100 m separation and a dense network of shots to define the 3-D variation of the chimneys structure and seismic properties. The tomographic model derived from P wave travel times shows that P wave velocity inside the chimney is up to 300 m/s higher than in the surrounding strata within the methane-hydrate stability zone. The zone of anomalously high velocity, about 500 m wide near its base, narrowing to about 200 m near the seabed, extends to a depth of 250 m below the seafloor. The depth extent of this zone and absence of high velocity beneath the base of the methane-hydrate stability field make it more likely that it contains hydrate rather than carbonate. If a predominantly fracture-filling model is appropriate for the formation of hydrate in low-permeability sediment, the maximum hydrate concentration in the chimney is estimated to be 14%–27% by total volume, depending on how host-sediment properties are affected by hydrate formation. Doming of the strata penetrated by the chimney appears to be associated with the emplacement of hydrate, accompanying the invasion of the gas hydrate stability zone by free gas.

A joint electromagnetic and seismic study of an active pockmark within the hydrate stability field at the Vestnesa Ridge, West Svalbard margin

We acquired coincident marine controlled source electromagnetic (CSEM), high-resolution seismic reflection and ocean-bottom seismometer (OBS) data over an active pockmark in the crest of the southern part of the Vestnesa Ridge, to estimate fluid composition within an underlying fluid-migration chimney. Synthetic model studies suggest resistivity obtained from CSEM data can resolve gas or hydrate saturation greater than 5% within the chimney. Acoustic chimneys imaged by seismic reflection data beneath the pockmark and on the ridge flanks were found to be associated with high-resistivity anomalies (+2–4 ?m). High-velocity anomalies (+0.3 km/s), within the gas-hydrate stability zone (GHSZ) and low-velocity anomalies (?0.2 km/s) underlying the GHSZ, were also observed. Joint analysis of the resistivity and velocity anomaly indicates pore saturation of up to 52% hydrate with 28% free gas, or up to 73% hydrate with 4% free gas, within the chimney beneath the pockmark assuming a nonuniform and uniform fluid distribution, respectively. Similarly, we estimate up to 30% hydrate with 4% free gas or 30% hydrate with 2% free gas within the pore space of the GHSZ outside the central chimney assuming a nonuniform and uniform fluid distribution, respectively. High levels of free-gas saturation in the top part of the chimney are consistent with episodic gas venting from the pockmark.

HIGH-RESOLUTION 3D SEISMIC INVESTIGATIONS OF HYDRATE- BEARING FLUID-ESCAPE CHIMNEYS IN THE NYEGGA REGION OF THE VØRING PLATEAU, NORWAY

Hundreds of pockmarks and mounds, which seismic reflection sections show to be underlain by chimney-like structures, exist in southeast part of the Voring plateau, Norwegian continental margin. These chimneys may be representative of a class of feature of global importance for the escape of methane from beneath continental margins and for the provision of a habitat for the communities of chemosynthetic biota. Thinning of the time intervals between reflectors in the flanks of chimneys, observed on several high-resolution seismic sections, could be caused by the presence of higher velocity material such as hydrate or authigenic carbonate, which is abundant at the seabed in pockmarks in this area. Evidence for the presence of hydrate was obtained from cores at five locations visited by the Professor Logachev during TTR Cruise 16, Leg 3 in 2006. Two of these pockmarks, each about 300-m wide with active seeps within them, were the sites of high-resolution seismic experiments employing arrays of 4-component OBS (Ocean-Bottom Seismic recorders) with approximately 100-m separation to investigate the 3D variation in their structure and properties. Shot lines at 50-m spacing, run with mini-GI guns fired at 8-m intervals, provided dense seismic coverage of the sub-seabed structure. These were supplemented by MAK deep-tow 5-kHz profiles to provide very high-resolution detail of features within the top 1-40 m sub-seabed. Travel-time tomography has been used to detail the variation in Vp and Vs within and around the chimneys. Locally high-amplitude reflectors of negative polarity in the flanks of chimneys and scattering and attenuation within the interiors of the chimneys may be caused by the presence of free gas within the hydrate stability field. A large zone of free gas beneath the hydrate stability field, apparently feeding several pockmarks, is indicated by attenuation and velocity pull-down of reflectors.

Identification of Shear Zones and Their Causal Mechanisms Using a Combination of Cone Penetration Tests and Seismic Data in the Eastern Niger Delta

In a site investigation of the eastern part of the offshore Niger delta, cone penetration tests (CPTU) showed significant drops in tip resistance, associated with decreases in sleeve friction and induced excess pore pressures at the interface between superficial sediments and the underlying deposits of a mass-transport complex (MTC) called NG1. Such signature characteristics of weakened zones are clearly expressed at three sites where the drop in tip resistance reaches more than 40% over 2–3 m-thick intervals. Correlations between CPTU profiles and both 3D and ultrahigh-resolution 2D seismic data suggest that the weakened zones surround syndepositional the within the frontal part of NG1. Hence, weakening appears associated with the remobilization of thrust faults, inducing localized plastic shear. Relatively recent, deep-seated structural movements affecting NG1 are suspected to have remobilized these thrusts faults. When considering the sole influence of gravity, the fact that shear strength is mobilized within scattered, limited zones along steeply dipping syndepositional faults is not favorable for the further development of a continuous slope-parallel failure surface above NG1.

A geophysical study of a pockmark in the Nyegga region, Norwegian Sea

Over the last decade pockmarks have proven to be important seabed features that provide information about fluid flow on continental margins. Their formation and dynamics are still poorly constrained due to the lack of proper three dimensional imaging of their internal structure. Numerous fluid escape features provide evidence for an active fluid-flow system on the Norwegian margin, specifically in the Nyegga region. In June-July 2006 a high-resolution seismic experiment using Ocean Bottom Seismometers (OBS) was carried out to investigate the detailed 3D structure of a pockmark named G11 in the region. An array of 14 OBS was deployed across the pockmark with 1 m location accuracy. Shots fired from surface towed mini GI guns were also recorded on a near surface hydrophone streamer. Several reflectors of high amplitude and reverse polarity are observed on the profiles indicating the presence of gas. Gas hydrates were recovered with gravity cores from less than a meter below the seafloor during the cruise. Indications of gas at shallow depths in the hydrate stability field show that methane is able to escape through the water-saturated sediments in the chimney without being entirely converted into gas hydrate. An initial 2D raytraced forward model of some of the P wave data along a line running NE-SW across the G11 pockmark shows, a gradual increase in velocity between the seafloor and a gas charged zone lying at ~300 m depth below the seabed. The traveltime fit is improved if the pockmark is underlain by velocities higher than in the surrounding layer corresponding to a pipe which ascends from the gas zone, to where it terminates in the pockmark as seen in the reflection profiles. This could be due to the presence of hydrates or carbonates within the sediments.

Multiscale seismic reflectivity of shallow thermoclines

Seismic Oceanography is coming of age as an established technique of observation of the thermohaline structure of the ocean. The present paper deals with the seismic reflectivity of the Armorican Shelf seasonal thermocline, west of France, based on two seismic experiments performed with a sparker source. The peak frequency was 500 Hz for the ASPEX experiment, where the thermocline was located at 27 m water depth, and reduced to 400 Hz associated to a higher source level for the IFOSISMO experiment, where the thermocline was 12 m deeper. Despite this settings, only the first experiment could clearly highlight the thermocline reflector, providing the first seismic observation of a shallow oceanic structure. To better understand the limitation of high-resolution seismic devices in detecting weak oceanic features, we develop a wavelet-based seismic analysis and consider, as a first approximation, a simple thermocline modelled by a Gauss Error function, allowing an analytical expression for the associated seismic reflectivity. We show that the acoustic impedance profile of the thermocline is mainly controlled by a sound velocity proportional to the temperature. We show that the seismic reflectivity is controlled by the reflection coefficient of the large-scale structure of the thermocline and by an attenuation factor which depends on the ratio between the seismic wavelength and the characteristic size of the thermocline. Depending on this ratio, the strength of the thermocline-related reflection may be too weak to be detected by seismic measurement.

Freshwater lake to salt-water sea causing widespread hydrate dissociation in the Black Sea

Gas hydrates, a solid established by water and gas molecules, are widespread along the continental margins of the world. Their dynamics have mainly been regarded through the lens of temperature-pressure conditions. A fluctuation in one of these parameters may cause destabilization of gas hydrate-bearing sediments below the seafloor with implications in ocean acidification and eventually in global warming. Here we show throughout an example of the Black Sea, the world’s most isolated sea, evidence that extensive gas hydrate dissociation may occur in the future due to recent salinity changes of the sea water. Recent and forthcoming salt diffusion within the sediment will destabilize gas hydrates by reducing the extension and thickness of their thermodynamic stability zone in a region covering at least 2800 square kilometers which focus seepages at the observed sites. We suspect this process to occur in other world regions (e.g., Caspian Sea, Sea of Marmara).Gas hydrates are maintained via a balance of temperature and pressure, if this changes then destabilization may occur. Here, the authors show instead that due to recent changes in the salinity of the sea water of the Black Sea, gas hydrates may become destabilized with widespread methane seepage.

Variations in pockmark composition at the Vestnesa Ridge: Insights from marine controlled source electromagnetic and seismic data

The Vestnesa Ridge marks the northern boundary of a known submarine gas hydrate province in the west Svalbard margin. Several seafloor pockmarks at the eastern segment of the ridge are sites of active methane venting. Until recently, seismic reflection data were the main tool for imaging beneath the ridge. Coincident controlled source electromagnetic (CSEM), high-resolution two-dimensional (2-D) airgun, sweep frequency SYSIF, and three-dimensional (3-D) p-cable seismic reflection data were acquired at the south-eastern part of the ridge between 2011 and 2013. The CSEM and seismic data contain profiles across and along the ridge, passing several active and inactive pockmarks. Joint interpretation of resistivity models obtained from CSEM and seismic reflection data provides new information regarding the fluid composition beneath the pockmarks. There is considerable variation in transverse resistance and seismic reflection characteristics of the gas hydrate stability zone (GHSZ) between the ridge flanks and chimneys beneath pockmarks. Layered seismic reflectors on the flanks are associated with around 300 Ωm2 transverse resistance, whereas the seismic reflectors within the chimneys exhibit amplitude blanking and chaotic patterns. The transverse resistance of the GHSZ within the chimneys vary between 400 and 1200 Ωm2. Variance attributes obtained from the 3-D p-cable data also highlight faults and chimneys, which coincide with the resistivity anomalies. Based on the joint data interpretation, widespread gas hydrate presence is likely at the ridge, with both hydrates and free gas contained within the faults and chimneys. However, at the active chimneys the effect of gas likely dominates the resistive anomalies.

Multifrequency seismic detectability of seasonal thermoclines assessed from ARGO data

Seismic oceanography is a developing research topic where new acoustic methods allow high-resolution teledetection of the thermohaline structure of the ocean. First implementations to study the Ocean Surface Boundary Layer have recently been achieved but remain very challenging due to the weakness and shallowness of such seismic reflectors. In this article, we develop a multifrequency seismic analysis of hydrographic data sets collected in a seasonally stratified midlatitude shelf by ARGO network floats to assess the detectability issue of shallow thermoclines. This analysis, for which sensitivity to the data reduction scheme used by ARGO floats for the transmission of the profiles is discussed, allows characterizing both the depth location and the frequency dependency of the dominant reflective feature of such complex structures. This approach provides the first statistical distribution of the range of variability of the frequency-dependent seismic reflection amplitude of the midlatitude seasonal thermoclines. We introduce a new parameter to quantify the overall capability of a multichannel seismic setup, including the source strength, the fold, and the ambient noise level, to detect shallow thermoclines. Seismic source signals are approximated by Ricker wavelets, providing quantitative guidelines to help in the design of seismic experiments targeting such oceanic reflectors. For shallow midlatitude seasonal thermoclines, we show that the detectability is optimal for seismic peak frequencies between 200 and 400 Hz: this means that airgun and Sparker sources are not well suited and that significant improvements of source devices will be necessary before seismic imaging of OSBL structures can be reliably attempted.