Stéphane Troesch

Steel slag filters to upgrade phosphorus removal in constructed wetlands: two years of field experiments.

Electric arc furnace steel slag (EAF-slag) and basic oxygen furnace steel slag (BOF-slag) were used as filter substrates in two horizontal subsurface flow filters (6 m(3) each) designed to remove phosphorus (P) from the effluent of a constructed wetland. The influences of slag composition, void hydraulic retention time (HRTv), temperature, and wastewater quality on treatment performances were studied. Over a period of almost two years of operation, the filter filled with EAF-slag removed 37% of the inlet total P, whereas the filter filled with BOF-slag removed 62% of the inlet total P. P removal occurred predominantly via CaO-slag dissolution followed by Ca phosphate precipitation. P removal efficiencies improved with increasing temperature and HRTv, most probably because this affected the rates of CaO-slag dissolution and Ca phosphate precipitation. It was observed that long HRTv (>3 days) can cause high pH in the effluents (>9) as a result of excessive CaO-slag dissolution. However, at shorter HRTv (1-2 days), pH values were elevated only during the first five weeks and then stabilized below a pH of 9. The kinetics of P removal were investigated employing a first-order equation, and a model for filter design was proposed.

Treatment of septage in sludge drying reed beds: a case study on pilot-scale beds

French legislation requires the control of private on-site sanitation systems by local authorities. This will result in a large increase of the quantity of sludge from septic tanks to be treated. Nevertheless, large wastewater treatment plants are not systematically able to treat this sludge because they may have reached their nominal load or they are not so numerous in rural zone to avoid too long transportation. The study concerns both the feasibility of sludge reed beds devoted to the treatment of septage and the assessment of a simultaneous treatment with aerated sludge. The experiments have been carried out on eight pilot-scale drying reed beds (2 m(2)) planted with Phragmites australis. Two filtration layers of either vegetal compost or sand were tested. The study is focused on the commissioning period (first vegetative year) with a loading rate of 30 kg SS m(-2) yr(-1). According to these operational conditions, dewatering efficiencies reached approx. 30% DM during summer but less than 20% DM in winter for each filtration layer and sludge. High removal efficiencies, with an average of 96%, 92% and 89% for SS, COD and TKN respectively, were achieved with septage whereas they were lower for the mixture of aerated sludge and septage. The dewaterability of septage and its filtration behaviour were assessed by several parameters (Capillary Suction Time, bound water) which may be some interesting tools for an optimised loading strategy.

Sludge drying reed beds : full and pilot scale study for activated sludge treatment

Sludge drying reed beds have been used for dewatering and mineralization of sludge since the beginning of the 90s, but their insufficient performances in terms of Dry Matter [DM] content and mineralization of the sludge have made necessary new studies. Therefore, 8 pilots of 2 m2 each and a full-scale plant (13,000 p.e, 8 beds of 470 m2 in operation for 4 years) have been monitored to examine the influence of the sludge loading rate, the sludge quality and the loading frequency on the dewatering and mineralization efficiencies. Two filtration layers and two loading rhythms were tested on pilots which were fed at a loading rate of 25-30 kg DM m(-2) yr(-1) during the first year of operation (commissioning period). Hydraulic behaviour (infiltration rate, outflow), O2 and CO2 relative concentrations in the filtration media, redox potential, pollutants removal and dry matter content were assessed during all the study. The rheological quality of the extracted sludge from full scale beds was assessed and showed that its mechanical behaviour exceed those of sludge of comparable dry matter content, making its spreading easier. Therefore, this sludge could easily claim the status of solid and stabilized sludge according to the French regulation. Design and management recommendations (number of beds, loading rates, feeding/rest period) gained from the experiments results are suggested.

Treatment performances of French constructed wetlands: results from a database collected over the last 30 years

Approximately 3,500 constructed wetlands (CWs) provide raw wastewater treatment in France for small communities (<5,000 people equivalent). Built during the past 30 years, most consist of two vertical flow constructed wetlands (VFCWs) in series (stages). Many configurations exist, with systems associated with horizontal flow filters or waste stabilization ponds, vertical flow with recirculation, partially saturated systems, etc. A database analyzed 10 years earlier on the classical French system summarized the global performances data. This paper provides a similar analysis of performance data from 415 full-scale two-stage VFCWs from an improved database expanded by monitoring data available from Irstea and the French technical department. Trends presented in the first study are confirmed, exhibiting high chemical oxygen demand (COD), total suspended solids (TSS) and total Kjeldahl nitrogen (TKN) removal rates (87%, 93% and 84%, respectively). Typical concentrations at the second-stage outlet are 74 mgCOD L(-1), 17 mgTSS L(-1) and 11 mgTKN L(-1). Pollutant removal performances are summarized in relation to the loads applied at the first treatment stage. While COD and TSS removal rates remain stable over the range of applied loads, the spreading of TKN removal rates increases as applied loads increase.

Wineries wastewater treatment by constructed wetlands: a review

The application of wetland systems for the treatment of wineries wastewater started in the early 1990s in the USA followed a few years later by France, Italy, Germany and Spain. Various studies demonstrated the efficiency of constructed wetlands (CWs) as a low cost, low maintenance and energy-saving technology for the treatment of wineries wastewater. Several of these experiences have also shown lessons to be learnt, such as some limits in the tolerance of the horizontal subsurface flow and vertical subsurface flow classic CWs to the strength of the wineries wastewater, especially in the first stage for the multistage systems. This paper is presenting an overview of all the reported experiences at worldwide level during the last 15 years, giving particular attention and provision of details to those systems that have proven to get reliable and constant performances in the long-term period and that have been designed and realized as optimized solutions for the application of CW technology to this particular kind of wastewater. The organic loading rates (OLRs) applied to the examined 13 CW systems ranged from about 30 up to about 5,000 gCOD/m² d (COD: chemical oxygen demand), with the 80th percentile of the reported values being below 297 gCOD/m² d and the median at 164 gCOD/m² d; the highest OLR values have in all cases been measured during the peak season (vintage) and often have been linked to lower surface removal rates (SRRs) in comparison to the other periods of the year. With such OLRs the SRRs have ranged from a minimum of 15 up to 4,700 gCOD/m² d, with the 80th percentile of the reported values being below 308 gCOD/m² d and the median at 112 gCOD/m² d.

A single-output model for the dynamic design of constructed wetlands treating combined sewer overflow

Constructed wetlands treating combined sewer overflow (CSO CWs) are vertical flow filters in France, with outflow limitation and detention basin. Treating storm-generated flows reduces pollutants and flow peaks entering natural waters. Storm-generated flows are stochastic and therefore optimized CSO CW design requires a dynamic approach, i.e., a modelling software targeting engineers. Therefore a new tool, called Orage, was developed. Orage consists of a core model, an iterative shell and a user interface. It optimizes dimensions and materials of CSO CWs site-specifically, based on inflow series and a low number of input parameters. The core model simulates hydraulics and TSS, COD and NH4-N removal. Manual fitting of the core showed good results with a single load. The same parameters gave satisfying accuracy when simulating load series with closed material balance. Sensitivity analysis confirmed model robustness and justified coupling with an automatic shell algorithm for automatic optimization, based on a single output. We developed a model for dual-sided CSO constructed wetlands.Calibration to an extreme load that our wetland failed to treat was accurate.The model showed stability with a series of loads.Simplified process descriptions led to good predictions.The model is robust and can serve automatic optimization for design-support.

Performance assessment of a vertical flow constructed wetland treating unsettled combined sewer overflow

The performance of a vertical flow constructed wetland for combined sewer overflow treatment (CSO CW) has been evaluated. The full-scale site has been monitored for 3 years for major pollutants and for two load events for a range of micropollutants (metals, metalloids and polycyclic aromatic hydrocarbons (PAHs)). Performance were predominantly high (97% for total suspended solids (TSS), 80% for chemical oxygen demand (COD), 72% for NH4-N), even if several loads were extremely voluminous, pushing the filter to its limits. Two different filter materials (a 4:1 mixture of sand and zeolite and natural pozzolana) showed similar treatment performance. Furthermore, environmental factors were correlated with COD removal efficiency. The greatest influencers of COD removal efficiency were the inlet dissolved COD concentrations and the duration and potential evapotranspiration during inter-event periods. Furthermore, sludge was analysed for quality and a sludge depth map was created. The map, and calculating the changes in sludge volume, helped to understand solid accumulation dynamics.

Using one filter stage of unsaturated/saturated vertical flow filters for nitrogen removal and footprint reduction of constructed wetlands

French vertical flow constructed wetlands (VFCW) treating raw wastewater have been developed successfully over the last 30 years. Nevertheless, the two-stage VFCWs require a total filtration area of 2-2.5 m2/P.E. Therefore, implementing a one-stage system in which treatment performances reach standard requirements is of interest. Biho-Filter® is one of the solutions developed in France by Epur Nature. Biho-Filter® is a vertical flow system with an unsaturated layer at the top and a saturated layer at the bottom. The aim of this study was to assess this new configuration and to optimize its design and operating conditions. The hydraulic functioning and pollutant removal efficiency of three different Biho-Filter® plants commissioned between 2011 and 2012 were studied. Outlet concentrations of the most efficient Biho-Filter® configuration are 70 mg/L, 15 mg/L, 15 mg/L and 25 mg/L for chemical oxygen demand (COD), 5-day biological oxygen demand (BOD5), total suspended solids (TSS) and total Kjeldahl nitrogen (TKN), respectively. Up to 60% of total nitrogen is removed. Nitrification efficiency is mainly influenced by the height of the unsaturated zone and the recirculation rate. The optimum recirculation rate was found to be 100%. Denitrification in the saturated zone works at best with an influent COD/NO3-N ratio at the inflet of this zone larger than 2 and a hydraulic retention time longer than 0.75 days.

Modelling hydrodynamics of horizontal flow steel slag filters designed to upgrade phosphorus removal in small wastewater treatment plants

Steel slag filters, if well designed and operated, may upgrade phosphorus removal in small wastewater treatment plants such as stabilization ponds and constructed wetlands. The main objective of this study was to develop a systemic modelling approach to describe changes in the hydraulic performances and internal hydrodynamics of steel slag filters under real dynamic operating conditions. The experimental retention time distribution curves (RTD curves) determined from tracer experiments performed at different times during the first year of operation of two field-scale steel slag filters were analyzed through a three stage process. First, a statistical analysis of the RTD curves was performed to determine statistical parameters of the retention time distribution. Second, classical tanks in series (TIS) and plug flow with dispersion (PFD) models were used to obtain a first evaluation of the dispersion and mixing regime. Finally, a multi-flow path TIS model, based on the assumption of several flow paths with different hydraulic properties, is proposed to accurately describe the internal hydrodynamics. Overall, the results of this study indicate that higher CaO content, round shape, and larger grain size distribution of steel slag may promote plug-like flow rather than dispersion. The results of the multi-flow path TIS model suggest that the internal hydrodynamics of steel slag filters can be primarily described by two main flow paths: (i) a faster main flow path showing higher plug flow, followed by (ii) a slower secondary flow path showing higher dispersion. The results also showed that internal hydrodynamics may change over time as a consequence of physical-chemical phenomena occurring in the filter, including accumulation of precipitates, slag hydration and carbonation, and particle segregation.

Septage unit treatment by sludge treatment reed beds for easy management and reuse: performance and design considerations

Sustainable treatment and management of fecal sludge in rural areas require adapted solutions. Rustic and simple operating processes such as sludge treatment reed beds (STRB) have been increasingly considered for this purpose. The biggest full scale (2,600 m2 of STRB) septage treatment unit in France had been built in Nègrepelisse with the final objectives of reusing treated sludge and leachates for agriculture spreading and tree irrigation, respectively. The aim of this investigation was to validate the treatment chain of this installation. The obtained field data showed firstly that the overall removal efficiencies of STRB were satisfactory and stable. Removal rates higher than 98% for chemical oxygen demand and suspended solids and a 95% for Kjeldahl nitrogen represented so far a beneficial septage treatment by STRB. The highlighted necessity of a suitable complementary leachate treatment (before tree irrigation) justified the presence of the second stage of vertical flow constructed wetland. The sludge deposit drying and mineralization efficiencies were on the right track. According to hydrotextural diagram analysis, surface deposit was however found to have high deformability probably due to the youth of the installation. An in-depth understanding of STRB system needs continuous long-term studies.