Stephen M. Kuebler

Laser and Electron‐Beam Induced Growth of Nanoparticles for 2D and 3D Metal Patterning

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Photoresponsive Hydrogel Microstructure Fabricated by Two-Photon Initiated Polymerization

A photoresponsive polymeric hydrogel cantilever that deflects under illumination has been fabricated by using two-photon three-dimensional lithography. The hydrogel was prepared from a comonomer solution containing acryloylacetone, acrylamide, and N,N′-methylene bisacrylamide. The photoresponse of the cantilever was activated by photoexcitation of acetylacetone groups at 244 nm. Deflection of the cantilever by ∼ 45° was effected upon UV irradiation for 20 min.

Fabrication of three-dimensional micro-photonic structures on the tip of optical fibers using SU-8.

A method is reported for fabricating truly three-dimensional micro-photonic structures directly onto the end face of an optical fiber using the cross-linkable resist SU-8. This epoxide-based material is well suited for micro-device fabrication because it is photo-processed as a solid and the cross-linked material is mechanically robust, chemically resistant, and optically transparent. Yet, procedures commonly used to process SU-8, particularly spin-coating, are impractical when the intended fabrication substrate is the end-face of an optical fiber. A melt-reflow process was developed to prepare optical fibers having SU-8 resin deposited at controlled thickness on the fiber end-face. Multi-photon direct laser writing was then used to fabricate various refractive lenses, a compound lens system, and a woodpile photonic crystal within the resin on the end-face of the optical fiber. Data are presented that show how the refractive lenses can be used to alter the output of the optical fiber. This work opens a new path to low-profile integrated photonic devices.

Vector diffraction analysis of high numerical aperture focused beams modified by two- and three-zone annular multi-phase plates

Vector diffraction theory was applied to study the effect of two- and three-zone annular multi-phase plates (AMPs) on the three-dimensional point-spread-function (PSF) that results when linearly polarized light is focused using a high numerical aperture refractory lens. Conditions are identified for which a three-zone AMP generates a PSF that is axially superresolved by 19% with minimal change in the transverse profile and sufficiently small side lobes that the intensity pattern could be used for advanced photolithographic techniques, such as multi-photon 3D microfabrication, as well as multi-photon imaging. Conditions are also found in which a three-zone AMP generates a PSF that is axially elongated by 510% with only 1% change along the transverse direction. This intensity distribution could be used for sub-micron-scale laser drilling and machining.

Information storage and retrieval using macromolecules as storage media

No abstract available.

Fabrication and characterization of three-dimensional copper metallodielectric photonic crystals

Three-dimensional metallodielectric photonic crystals were created by fabricating a micron-scale polymeric template using multiphoton direct laser writing (DLW) in SU-8 and conformally and selectively coating the template with copper (Cu) via nanoparticle-nucleated electroless metallization. This process deposits a uniform metal coating, even deep within a lattice, because it is not directional like sputter-coating or evaporative deposition. Infrared reflectance spectra show that upon metallization the optical behavior transitions fully from a dielectric photonic crystal to that of a metal photonic crystal (MPC). After depositing 50 nm of Cu, the MPCs exhibit a strong plasmonic stop band having reflectance greater than 80% across the measured part of the band and reaching as high as 95% at some wavelengths. Numerical simulations match remarkably well with the experimental data and predict all dominant features observed in the reflectance measurements, showing that the MPCs are structurally well formed. These data show that the Cu-based process can be used to create high performance MPCs and devices that are difficult or impossible to fabricate by other means.

Vectorial beam shaping

An algorithm is reported for the design of a phase-only diffractive optical element (DOE) that reshapes a beam focused using a high numerical aperture (NA) lens. The vector diffraction integrals are used to relate the field distributions in the DOE plane and focal plane. The integrals are evaluated using the chirp-z transform and computed iteratively within the Method of Generalized Projections (MGP) to identify a solution that simultaneously satisfies the beam shaping and DOE constraints. The algorithm is applied to design a DOE that transforms a circularly apodized flat-top beam of wavelength lambda to a square irradiance pattern when focused using a 1.4-NA objective. A DOE profile is identified that generates a 50 lambda x 50 lambda square irradiance pattern having 7% uniformity error and 74.5% diffraction efficiency (fraction of focused power). The diffraction efficiency and uniformity decrease as the size of the focused profile is reduced toward the diffraction limited spot size. These observations can be understood as a manifestation of the uncertainty principle.

Three-dimensional microfabrication using two-photon-activated chemistry

Photochemical reactions which can be activated by the simultaneous absorption of two photons provide a means for single-step fabrication of complex 3D microstructures. These types of structures are needed for a wide range of applications, including microfluidics, electrooptics, and micro-electromechanical systems. We have shown that chromophores can be engineered to have both large two-photon absorptivities as well as an efficient means for activating chemical processes, such as radical polymerization, subsequent to the photoexcitation. Chromophores designed following this strategy two-photon-activate the radical polymerization of acrylates at lower incident laser powers than conventional UV initiators. Efficient two-photon photopolymer resins based on these chromophores were used in the fabrication of complex microarchitectures, such as photonic bandgap structures and tapered waveguides. We have devised a strategy which allows this approach to be extended to other chemical systems.

Tight control of light beams in photonic crystals with spatially-variant lattice orientation

Spatially-variant photonic crystals (SVPCs), in which the orientation of the unit cell changes as a function of position, are shown to be capable of abruptly controlling light beams using just low index materials and can be made to have high polarization selectivity. Multi-photon direct laser writing in the photo-polymer SU-8 was used to fabricate three-dimensional SVPCs that direct the flow of light around a 90 degree bend. The lattice spacing and fill factor were maintained nearly constant throughout the structure. The SVPCs were characterized at a wavelength of 2.94 μm by scanning the faces with optical fibers and the results were compared to electromagnetic simulations. The lattices were shown to direct infrared light of one polarization through sharp bends while the other polarization propagated straight through the SVPC. This work introduces a new scheme for controlling light that should be useful for integrated photonics.

Effect of refractive index mismatch on multi-photon direct laser writing

This work reports how the process of three-dimensional multi-photon direct laser writing (mpDLW) is affected when there is a small mismatch in refractive index between the material being patterned and the medium in which the focusing objective is immersed. Suspended-line microstructures were fabricated by mpDLW in the cross-linkable epoxide SU-8 as a function of focus depth and average incident power. It is found that even a small refractive index contrast of Δn = + 0.08 causes significant variation in feature width and height throughout the depth of the material. In particular, both the width and height of features can either increase or decrease with depth, depending upon how much the average incident laser power exceeds the threshold for writing. Vectorial diffraction theory is used to obtain insight into the origin of the effect and how to compensate for it. We demonstrate that varying the average focused power is a practical means for controlling the variation in feature size with focal depth.