Stephen U. S. Choi

Anomalously increased effective thermal conductivities of ethylene glycol-based nanofluids containing copper nanoparticles

It is shown that a “nanofluid” consisting of copper nanometer-sized particles dispersed in ethylene glycol has a much higher effective thermal conductivity than either pure ethylene glycol or ethylene glycol containing the same volume fraction of dispersed oxide nanoparticles. The effective thermal conductivity of ethylene glycol is shown to be increased by up to 40% for a nanofluid consisting of ethylene glycol containing approximately 0.3 vol % Cu nanoparticles of mean diameter <10 nm. The results are anomalous based on previous theoretical calculations that had predicted a strong effect of particle shape on effective nanofluid thermal conductivity, but no effect of either particle size or particle thermal conductivity.

Measuring Thermal Conductivity of Fluids Containing Oxide Nanoparticles

Oxide nanofluids were produced and their thermal conductivities were measured by a transient hot-wire method. The experimental results show that these nanofluids, containing a small amount of nanoparticles, have substantially higher thermal conductivities than the same liquids without nanoparticles. Comparisons between experiments and the Hamilton and Crosser model show that the model can predict the thermal conductivity of nanofluids containing large agglomerated Al{sub 2}O{sub 3} particles. However, the model appears to be inadequate for nanofluids containing CuO particles. This suggests that not only particle shape but size is considered to be dominant in enhancing the thermal conductivity of nanofluids.

Anomalous thermal conductivity enhancement in nanotube suspensions

We have produced nanotube-in-oil suspensions and measured their effective thermal conductivity. The measured thermal conductivity is anomalously greater than theoretical predictions and is nonlinear with nanotube loadings. The anomalous phenomena show the fundamental limits of conventional heat conduction models for solid/liquid suspensions. We have suggested physical concepts for understanding the anomalous thermal behavior of nanotube suspensions. In comparison with other nanostructured materials dispersed in fluids, the nanotubes provide the highest thermal conductivity enhancement, opening the door to a wide range of nanotube applications.

Thermal Conductivity of Nanoparticle -Fluid Mixture

Effective thermal conductivity of mixtures of e uids and nanometer-size particles is measured by a steady-state parallel-plate method. The tested e uids contain two types of nanoparticles, Al 2O3 and CuO, dispersed in water, vacuum pump e uid, engine oil, and ethylene glycol. Experimental results show that the thermal conductivities of nanoparticle ‐e uid mixtures are higher than those of the base e uids. Using theoretical models of effective thermal conductivity of a mixture, we have demonstrated that the predicted thermal conductivities of nanoparticle ‐e uid mixtures are much lower than our measured data, indicating the dee ciency in the existing models when used for nanoparticle ‐e uid mixtures. Possible mechanisms contributing to enhancement of the thermal conductivity of the mixtures are discussed. A more comprehensive theory is needed to fully explain the behavior of nanoparticle ‐e uid mixtures. Nomenclature cp = specie c heat k = thermal conductivity L = thickness Pe = Peclet number P q = input power to heater 1 r = radius of particle S = cross-sectional area T = temperature U = velocity of particles relative to that of base e uids ® = ratio of thermal conductivity of particle to that of base liquid ¯ = .® i 1/=.® i 2/ ° = shear rate of e ow Ω = density A = volume fraction of particles in e uids Subscripts

Mechanisms of heat flow in suspensions of nano-sized particles (nanofluids)

Recent measurements on nanofluids have demonstrated that the thermal conductivity increases with decreasing grain size. However, such increases cannot be explained by existing theories. We explore four possible explanations for this anomalous increase: Brownian motion of the particles, molecular-level layering of the liquid at the liquid/particle interface, the nature of heat transport in the nanoparticles, and the effects of nanoparticle clustering. We show that the key factors in understanding thermal properties of nanofluids are the ballistic, rather than diffusive, nature of heat transport in the nanoparticles, combined with direct or fluid-mediated clustering effects that provide paths for rapid heat transport.

Role of Brownian motion in the enhanced thermal conductivity of nanofluids

We have found that the Brownian motion of nanoparticles at the molecular and nanoscale level is a key mechanism governing the thermal behavior of nanoparticle–fluid suspensions (“nanofluids”). We have devised a theoretical model that accounts for the fundamental role of dynamic nanoparticles in nanofluids. The model not only captures the concentration and temperature-dependent conductivity, but also predicts strongly size-dependent conductivity. Furthermore, we have discovered a fundamental difference between solid/solid composites and solid/liquid suspensions in size-dependent conductivity. This understanding could lead to design of nanoengineered next-generation coolants with industrial and biomedical applications in high-heat-flux cooling.

Empirical correlation finding the role of temperature and particle size for nanofluid (Al2O3) thermal conductivity enhancement

In this letter, we report an experimental correlation [Eqs. (1a) and (1b) or (1c)] for the thermal conductivity of Al2O3 nanofluids as a function of nanoparticle size (ranging from 11nmto150nm nominal diameters) over a wide range of temperature (from 21to71°C). Following the previously proposed conjecture from the theoretical point-of-view (Jang and Choi, 2004), it is experimentally validated that the Brownian motion of nanoparticles constitutes a key mechanism of the thermal conductivity enhancement with increasing temperature and decreasing nanoparticle sizes.

Review and Comparison of Nanofluid Thermal Conductivity and Heat Transfer Enhancements

This study provides a detailed literature review and an assessment of results of the research and development work forming the current status of nanofluid technology for heat transfer applications. Nanofluid technology is a relatively new field, and as such, the supporting studies are not extensive. Specifically, experimental results were reviewed in this study regarding the enhancement of the thermal conductivity and convective heat transfer of nanofluids relative to conventional heat transfer fluids, and assessments were made as to the state-of-the-art of verified parametric trends and magnitudes. Pertinent parameters of particle volume concentration, particle material, particle size, particle shape, base fluid material, temperature, additive, and acidity were considered individually, and experimental results from multiple research groups were used together when assessing results. To this end, published research results from many studies were recast using a common parameter to facilitate comparisons of data among research groups and to identify thermal property and heat transfer trends. The current state of knowledge is presented as well as areas where the data are presently inconclusive or conflicting. Heat transfer enhancement for available nanofluids is shown to be in the 15–40% range, with a few situations resulting in orders of magnitude enhancement.

Heat Transfer in Nanofluids—A Review

Suspended nanoparticles in conventional fluids, called nanofluids, have been the subject of intensive study worldwide since pioneering researchers recently discovered the anomalous thermal behavior of these fluids. The enhanced thermal conductivity of these fluids with small-particle concentration was surprising and could not be explained by existing theories. Micrometer-sized particle-fluid suspensions exhibit no such dramatic enhancement. This difference has led to studies of other modes of heat transfer and efforts to develop a comprehensive theory. This article presents an exhaustive review of these studies and suggests a direction for future developments. The review and suggestions could be useful because the literature in this area is spread over a wide range of disciplines, including heat transfer, material science, physics, chemical engineering and synthetic chemistry.

Nanofluids: From Vision to Reality Through Research

Nanofluids are a new class of nanotechnology-based heat transfer fluids engineered by dispersing and stably suspending nanoparticles with typical length on the order of 1-50 nm in traditional heat transfer fluids. For the past decade, pioneering scientists and engineers have made phenomenal discoveries that a very small amount (<1 vol %) of guest nanoparticles can provide dramatic improvements in the thermal properties of the host fluids. For example, some nanofluids exhibit superior thermal properties such as anomalously high thermal conductivity at low nanoparticle concentrations, strong temperature- and size-dependent thermal conductivity, a nonlinear relationship between thermal conductivity and concentration, and a threefold increase in the critical heat flux at a small particle concentration of the order of 10 ppm. Nanofluids are of great scientific interest because these unprecedented thermal transport phenomena surpass the fundamental limits of conventional macroscopic theories of suspensions. Therefore, numerous mechanisms and models have been proposed to account for these unexpected, intriguing thermal properties of nanofluids. These discoveries also show that nanofluids technology can provide exciting new opportunities to develop nanotechnology-based coolants for a variety of innovative engineering and medical applications. As a result, the study of nanofluids has emerged as a new field of scientific research and innovative applications. Hence, the subject of nanofluids is of great interest worldwide for basic and applied research. This paper highlights recent advances in this new field of research and shows future directions in nanofluids research through which the vision of nanofluids can be turned into reality.