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Steven F. Rice

California Institute of Technology

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Featured researches published by Steven F. Rice.

Comments on Inorganic Chemistry | 1981

On the Role of the High-Spin State in the Water Exchange Reaction of Hexaaquocobalt(III)

Jay R. Winkler; Steven F. Rice; Harry B. Gray

Abstract The potential surface for the 5T2g state of Co(OH2)3+ 6, as estimated from spectroscopic data plus some assumptions from the work of Wilson and Solomon on Co(NH3)3+ 6, has a minimum that falls about 4 kcal mol−1 above the low-spin ground state. The quintet state probably plays a role in the substitutional lability of the aquo ion, as suggested 30 years ago by Taube and coworkers.

Journal of the American Chemical Society | 1983

Electronic absorption and emission spectra of binuclear platinum(II) complexes. Characterization of the lowest singlet and triplet excited states of tetrakis(diphosphonato)diplatinate(4-) anion (Pt2(H2P2O5)44-)

Steven F. Rice; Harry B. Gray

Inorganic Chemistry | 1987

Electronic spectroscopy of d8-d8 diplatinum complexes. 1A2u (d.sigma.* .fwdarw. p.sigma.), 3Eu (dxz,dyz .fwdarw. p.sigma.), and 3,1B2u (d.sigma.* .fwdarw. dx2-y2) excited states of tetrakis(diphosphonato)diplatinate(4-), Pt2(P2O5H2)44-

A. E. Stiegman; Steven F. Rice; Harry B. Gray; Vincent M. Miskowski

Inorganic Chemistry | 1994

Spectroscopy and photophysics of Rh2(dimen)42+ (dimen = 1,8-diisocyanomenthane). Exceptional metal-metal bond shortening in the lowest electronic excited states

Vincent M. Miskowski; Steven F. Rice; Harry B. Gray; Richard F. Dallinger; Steven J. Milder; Michael G. Hill; Christopher L. Exstrom; Kent R. Mann

Journal of the American Chemical Society | 1981

Metal-metal interactions in binuclear rhodium isocyanide complexes. Polarized single-crystal spectroscopic studies of the lowest triplet.rarw.singlet system in tetrakis(1,3-diisocyanopropane)dirhodium(2+)

Steven F. Rice; Harry B. Gray

Coordination Chemistry Reviews | 1982

Photophysical properties of the lowest electronic excited states of binuclear rhodium(I) isocyanide complexes

Steven F. Rice; Steven J. Milder; Harry B. Gray; Robert A. Goldbeck; David S. Kliger

The Journal of Physical Chemistry | 1993

Excited-state decay processes of binuclear rhodium(I) isocyanide complexes

Vincent M. Miskowski; Steven F. Rice; Harry B. Gray; Steven J. Milder

Inorganic Chemistry | 1988

Electronic absorption spectra of binuclear rhodium(I) isocyanide complexes. Comparison of ground-state and d.sigma.* .fwdarw. p.sigma. excited-state bond energies

Steven F. Rice; Vincent M. Miskowski; Harry B. Gray

Inorganic Chemistry | 1988

Electronic absorption spectra of binuclear rhodium(I) isocyanide complexes: comparison of ground-state and dσ*→pσ excited-state bond energies

Steven F. Rice; Vincent M. Miskowski; Harry B. Gray

Inorganic Chemistry | 1980

Electronic absorption spectrum of chromous acetate dihydrate and related binuclear chromous carboxylates

Steven F. Rice; Randall B. Wilson; Edward I. Solomon

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Harry B. Gray

Iowa State University

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Vincent M. Miskowski

California Institute of Technology

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Steven J. Milder

Brookhaven National Laboratory

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A. E. Stiegman

Iowa State University

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Christopher L. Exstrom

University of Nebraska at Kearney

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David S. Kliger

University of California

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Edward I. Solomon

Stanford University

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Jay R. Winkler

California Institute of Technology

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Kent R. Mann

University of Minnesota

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Michael G. Hill

Occidental College

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