Steven J. Schowalter

Evidence for sympathetic vibrational cooling of translationally cold molecules

Compared with atoms, molecules have a rich internal structure that offers many opportunities for technological and scientific advancement. The study of this structure could yield critical insights into quantum chemistry, new methods for manipulating quantum information, and improved tests of discrete symmetry violation and fundamental constant variation. Harnessing this potential typically requires the preparation of cold molecules in their quantum rovibrational ground state. However, the molecular internal structure severely complicates efforts to produce such samples. Removal of energy stored in long-lived vibrational levels is particularly problematic because optical transitions between vibrational levels are not governed by strict selection rules, which makes laser cooling difficult. Additionally, traditional collisional, or sympathetic, cooling methods are inefficient at quenching molecular vibrational motion. Here we experimentally demonstrate that the vibrational motion of trapped BaCl+ molecules is quenched by collisions with ultracold calcium atoms at a rate comparable to the classical scattering, or Langevin, rate. This is over four orders of magnitude more efficient than traditional sympathetic cooling schemes. The high cooling rate, a consequence of a strong interaction potential (due to the high polarizability of calcium), along with the low collision energies involved, leads to molecular samples with a vibrational ground-state occupancy of at least 90 per cent. Our demonstration uses a novel thermometry technique that relies on relative photodissociation yields. Although the decrease in vibrational temperature is modest, with straightforward improvements it should be possible to produce molecular samples with a vibrational ground-state occupancy greater than 99 per cent in less than 100u2009milliseconds. Because sympathetic cooling of molecular rotational motion is much more efficient than vibrational cooling in traditional systems, we expect that the method also allows efficient cooling of the rotational motion of the molecules. Moreover, the technique should work for many different combinations of ultracold atoms and molecules.

An integrated ion trap and time-of-flight mass spectrometer for chemical and photo- reaction dynamics studies

We demonstrate the integration of a linear quadrupole trap with a simple time-of-flight mass spectrometer with medium-mass resolution (m/Δm ∼ 50) geared towards the demands of atomic, molecular, and chemical physics experiments. By utilizing a novel radial ion extraction scheme from the linear quadrupole trap into the mass analyzer, a device with large trap capacity and high optical access is realized without sacrificing mass resolution. This provides the ability to address trapped ions with laser light and facilitates interactions with neutral background gases prior to analyzing the trapped ions. Here, we describe the construction and implementation of the device as well as present representative ToF spectra. We conclude by demonstrating the flexibility of the device with proof-of-principle experiments that include the observation of molecular-ion photodissociation and the measurement of trapped-ion chemical reaction rates.

Low-threshold ultraviolet solid-state laser based on a Ce 3+ :LiCaAlF 6 crystal resonator

A low-threshold solid-state UV laser using a whispering gallery mode (WGM) resonator constructed from UV transparent crystalline material is demonstrated. Using a Ce3+:LiCaAlF6 resonator, we observe broad bandwidth lasing (280-330 nm) with a low threshold intensity of 7.5×10(9) W/m(2) and an effective slope efficiency of ~25%. The lasing time delay dynamics in the pulsed operation mode are also observed and analyzed. Additionally, a LiCaAlF(6) WGM resonator with Q=2×10(7) at 370 nm is realized. The combination of this high Q and the small WGM mode volume significantly lowers the pump power threshold compared to traditional cavity designs, opening the door for both tunable continuous-wave and mode-locked operation.

Laser-Cooling-Assisted Mass Spectrometry

Mass spectrometry is a key analytical tool in many disciplines, as it provides accurate identification of unknown chemical components in complex mixtures. The authors demonstrate that using laser cooling significantly increases the phase-space density of this assay, improving both mass resolution and detection limits by better than an order of magnitude.

Molecular-ion trap-depletion spectroscopy of BaCl{sup +}

We demonstrate a simple technique for molecular-ion spectroscopy. BaCl

Blue-sky bifurcation of ion energies and the limits of neutral-gas sympathetic cooling of trapped ions

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Electronics of an ion trap with integrated time-of-flight mass spectrometer

molecular ions are trapped in a linear Paul trap in the presence of a room-temperature He buffer gas and photodissociated by driving an electronic transition from the ground

Action spectroscopy of SrCl⁺ using an integrated ion trap time-of-flight mass spectrometer.

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Photodissociation spectroscopy of the dysprosium monochloride molecular ion

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A solid state ultraviolet lasers based on cerium-doped LiCaAlF6 crystal resonator

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