Surya Prakash Tiwari

Enhanced temperature sensing response of upconversion luminescence in ZnO–CaTiO3: Er3+/Yb3+ nano-composite phosphor

Upconversion emission and temperature sensing of the Er(3+)/Yb(3+) doped ZnO-CaTiO3 nano-composite phosphor is studied by varying the ZnO concentration. The XRD and EDX studies reveal the formation of composite phase when ZnO doping exceeds above 10 mw%. Five prominent upconversion emission bands at 410, 492, 524, 545 and 662 nm corresponding to (2)H9/2→(4)I15/2, (4)F3/2→(4)I15/2, (2)H11/2→(4)I15/2, (4)S3/2→(4)I15/2 and (4)F9/2→(4)I15/2 transitions, respectively are found under 980 nm excitation from a diode laser. On the basis of rise time analysis it was found that energy transfer process is responsible for the intense upconversion emission. Large reduction in decay time of (4)S3/2 level is observed on the ZnO incorporation in host matrix. Moreover, the absolute sensor sensitivity, relative sensor sensitivity and calculated color coordinates of the samples are also determined. These results indicate the potentiality of this composite phosphor for various applications.

Latent fingermarks detection for La2O3:Er3+/Yb3+ phosphor material in upconversion emission mode: A comparative study

The authors in this manuscript present the results on synthesis of Er3+/Yb3+ codoped La2O3 upconverting phosphor and its demonstration on the development of latent fingermarks on the surfaces of semi-porous and non-porous objects. The samples were synthesized via combustion using urea as a reducing agent and chemical precipitation methods. The annealed samples showed enough intense green emission in the 520–550 nm range on 980 nm excitation. Excellent emission property of the samples in the green region showed an advantage to use it in latent fingermarks detection. A dry powder dusting technique is used to develop latent fingermarks and the results are compared. The studies reflected the superiority of upconversion phosphor materials for the detection of latent fingermarks over the traditional downconversion luminescence methods.

Structural and optical properties of thermal decomposition assisted Gd2O3:Ho(3+)/Yb(3+) upconversion phosphor annealed at different temperatures.

The infrared to visible upconversion fluorescent nanoparticles of Ho(3+)/Yb(3+) codoped Gd2O3 phosphor is synthesized via thermal decomposition route. The as-synthesized sample was annealed at 800, 1000 and 1200°C for 3h and then structural and optical properties were studied. The Rietveld refinement of X-ray diffraction (XRD) data was analyzed to probe the effect of Ho(3+)/Yb(3+) dopant on the structural parameters of Gd2O3 host. The upconversion emission spectra of as-synthesized and annealed samples are compared using 980nm diode laser excitation and five emission bands noticed at 490, 539, 550, 667 and 757nm corresponding to the (5)F3→(5)I8, (5)F4→(5)I8, (5)S2→(5)I8,(5)F5→(5)I8 and (5)I4→(5)I8 manifolds, respectively. The local temperature induced by laser light is also calculated. The fluorescence intensity ratio (FIR) of two thermally coupled transitions (5)F4→(5)I8 and (5)S2→(5)I8 is plotted against the sample temperature and sensor sensitivity of sample is calculated.