Susan J. Hathaway

Electronic control of stereoselectivity. 20. Crystal and molecular structure of the ferrocene derived from tricyclo[5.2.1.02,6]Deca-2,5,8-triene

Abstract Reaction of the isodicyclopentadienide anion and its dehydro congener with Fe(II) leads to a stereochemically homogeneous ferrocene derivative in each instance. Through chemical correlation and X-ray analysis, above-plane complexation is established for both halves within the two sandwich compounds.

Selective trapping of rearranged spirocyclic isodicyclopentadienes by tropone

Abstract The unparalleled substituent-dependent regulation of the course of cycloaddition reactions between isodicyclopentadienes and tropones is described.

Electronic Control of Stereoselectivity. Part 29. Stereochemical and Regiochemical Course of Isodicyclopentadiene-Tropone Cycloaddition Reactions.

On etudie les reactions du tetrahydro-4,5,6,7 methano-4,7 indene (isodicyclopentadiene) et de 2 de ses derives spiro-cycliques avec la cycloheptatrienone et ses derives methyl-2 et methoxy-2. Effet des substituants