Svetlana Savić-Šević

Femtosecond laser induced periodic surface structures on multi-layer graphene

In this work, we present an observation of laser induced periodic surface structures (LIPSS) on graphene. LIPSS on other materials have been observed for nearly 50 years, but until now, not on graphene. Our findings for LIPSS on multi-layer graphene were consistent with previous reports of LIPSS on other materials, thus classifying them as high spatial frequency LIPSS. LIPSS on multi-layer graphene were generated in an air environment by a linearly polarized femtosecond laser with excitation wavelength λ of 840 nm, pulse duration τ of ∼150 fs, and a fluence F of ∼4.3–4.4 mJ/cm2. The observed LIPSS were perpendicular to the laser polarization and had dimensions of width w of ∼30–40 nm and length l of ∼0.5–1.5 μm, and spatial periods Λ of ∼70–100 nm (∼λ/8–λ/12), amongst the smallest of spatial periods reported for LIPSS on other materials. The spatial period and width of the LIPSS were shown to decrease for an increased number of laser shots. The experimental results support the leading theory behind high s...

High angular and spectral selectivity of purple emperor (Lepidoptera: Apatura iris and A. ilia) butterfly wings

The iridescent features of the butterfly species Apatura iris (Linnaeus, 1758) and A. ilia (Denis & Schiffermüller, 1775) were studied. We recognized the structural color of scales only on the dorsal side of both the fore and hind wings of males of both of the aforementioned butterfly species. The scale dimensions and microstructure were analyzed by a scanning electron microscope (SEM) and transmission electron microscope (TEM). The optical properties were measured and it was found that the peak reflectivity is around 380 nm, with a spectral width (full width at half maximum) of approximately 50 nm in both species. The angular selectivity is high and a purple iridescent color is observed within the angular range of only 18 degrees in both species.

Real-time measurement of internal stress of dental tissue using holography.

We describe a real-time holographic technique used to observe dental contraction due to photo-polymerization of dental filling during LED lamp illumination. An off-axis setup was used, with wet in-situ processing of the holographic plate, and consequent recording of interference fringes using CCD camera. Finite elements method was used to calculate internal stress of dental tissue, corresponding to experimentally measured deformation. A technique enables selection of preferred illumination method with reduced polymerization contraction. As a consequence, durability of dental filling might be significantly improved.

Holographic detection of a tooth structure deformation after dental filling polymerization

An experimental technique to reveal the effects of dental polymer contraction is established to choose the most appropriate polymerization technique. Tooth deformation following a dental filling polymerization is analyzed using double-exposure holographic interferometry. A caries-free, extracted human molar is mounted in dental gypsum and different cavity preparations and fillings are made on the same tooth. Dental composite fillings are polymerized by an LED light source especially designed for this purpose. Holographic interferograms are made for occlusal (class I), occlusomesial (class II), and mesioocclusodistal (class II MOD) cavities and fillings. Maximum intercuspal deformation ranges from 2 microm for the class I cavity to 14 mum for the MOD class cavity. A finite element method (FEM) is used to calculate von Mises stress on a simplified tooth model, based on experimental results. The stress varies between 50 and 100 MPa, depending on the cavity type.

Micro- and nanostructures of iridescent wing scales in purple emperor butterflies (Lepidoptera: Apatura ilia and A. iris).

Apatura ilia (Denis and Schiffermüller, 1775) and A. iris (Linnaeus, 1758) are fascinating butterflies found in the Palaearctic ecozone (excepting the north of Africa). The wings of these insects are covered with a great number of two types of scales positioned like roof tiles. Type I scales are on the surface, while type II scales are situated below them. The structural color of the type I scales is recognized only on the dorsal side of both the fore and hind wings of the males of the aforementioned species. Both types of scales are responsible for pigment color of the wings, but iridescence is observed only in the type I scales. The brilliant structural color is due to a multilayer structure. The features of the scales, their dimensions and fine structure were obtained using scanning electron microscopy. Cross sections of the scales were then analyzed by transmission electron microscopy. The scales of the “normal” and clytie forms of A. ilia have a different nanostructure, but are of the same type. A similar type of structure, but with a different morphology, was also noticed in A. iris. The scales of the analyzed species resemble the scales of tropical Morpho butterflies. Microsc. Res. Tech., 2012.

Holographic Measurement of a Tooth Model and Dental Composite Contraction

We have developed a real-time holographic technique to observe deformation induced by dental composite contraction. The standard split beam method was used, in conjunction with in situ holographic plate processing. Experiments were performed on a mechanical model of a human tooth with cavity. A silicone mold was used to manufacture a number of identical casts, using photoactivated composite. A LED lamp was used to induce photo-polymerization reaction in a composite. We have shown that the proposed method is ideal to analyze various polymerization strategies, with the purpose of recommending one which minimizes the polymerization contraction.

Scattering-enhanced absorption and interference produce a golden wing color of the burnished brass moth, Diachrysia chrysitis

Here we report how interference and scattering-enhanced absorption act together to produce the golden wing patches of the burnished brass moth. The key mechanism is scattering on rough internal surfaces of the wing scales, accompanied by a large increase of absorption in the UV-blue spectral range. Unscattered light interferes and efficiently reflects from the multilayer composed of the scales and the wing membranes. The resulting spectrum is remarkably similar to the spectrum of metallic gold. Subwavelength morphology and spectral and absorptive properties of the wings are described. Theories of subwavelength surface scattering and local intensity enhancement are used to quantitatively explain the observed reflectance spectrum.

Orange-Reddish Light Emitting Phosphor GdVO4:Sm3+ Prepared by Solution Combustion Synthesis

The gadolinium vanadate doped with samarium (GdVO4:Sm3+) nanopowder was prepared by the solution combustion synthesis (SCS) method. After synthesis, in order to achieve the full crystallinity, the material was annealed in air atmosphere at 900°C. Phase identification in the postannealed powder samples was performed by X-ray diffraction, and morphology was investigated by high-resolution scanning electron microscopy (SEM). Photoluminescence characterization of the emission spectrum and time-resolved analysis have been performed using the tunable laser optical parametric oscillator excitation and the streak camera. Several strong emission bands in the Sm3+ emission spectrum were observed, located at 567 nm (4G5/2–6H5/2), 604 nm (4G5/2–6H7/2), and 646 (654) nm (4G5/2–6H9/2), respectively. The weak emission bands at 533 nm (4F3/2–6H5/2) and 706 nm (4G5/2–6H11/2) and a weak broad luminescence emission band of VO43− were also observed by the detection system. We analyzed the possibility of using the host luminescence for two-color temperature sensing. The proposed method is improved by introducing the temporal dependence in the line intensity ratio measurements.

On the reflectivity of one-dimensional photonic crystal realized in dichromated pullulan

In this paper we apply method of calculation of the reflectivity of one dimensional photonic crystal described in [1] but with significantly higher resolution and applied for the case of volume Bragg gratings which are made in our laboratory using dichromated pullulan. We show that calculated reflectivity as a function of incident wavelength contains rapidly oscillating part, which is not observable if the resolution of calculation is low. We show good agreement between results of the model and measured reflectivity of the 1D photonic crystal fabricated in dichromated pullulan.

Optical properties of volume gratings with nanosphere-filled layers - biomimetics of moth structures

A new type of layered photonic structure, whose alternating layers are filled with randomly dispersed nano-spheres, is fabricated and its optical properties are experimentally and theoretically analysed. Structures are made on a pullulan doped with chromium ions (dichromated pullulan - DCP) using holography. We found that experimental structures are similar to those observed on wings of the Diachrysia chrysitis moth, having layers of overlapping scales. DCP photonic structure has alternating air-pullulan layers, held in place by sparsely separated nano-pillars, and air voids filled with 30 – 60 nm diameter nanospheres which act as scatterers. Theoretical analysis of such structures shows that the scattering and interference interact to enhance the local field within the layers and increase the residual absorption of the material. We compare optical properties of moth scales with properties of structures fabricated in DCP, and calculated from the functional model.