T J Abram

High-Temperature Reactor Fuel Technology in the RAPHAEL European Project

Within the scope of the 5th EURATOM Framework Programme (FP) for the HTR-F and HTR-F1 projects, a new 4-year integrated project on very high temperature reactors (RAPHAEL: ReActor for Process Heat And Electricity) was started in April 2006 as part of the 6th Framework Programme. The Sub-Project on Fuel Technology (SP-FT) is one of eight sub-projects constituting the RAPHAEL project. R&D conducted in this sub-project focuses on understanding fuel behaviour, determining the limits of state-of-the-art fuel, and developing potential performance improvements. Fabrication processes were worked out for alternative fuel kernel composition (UCO instead of UO2 ) and coating (ZrC instead of SiC): i) UCO microstructure reduces fission product migration and is thus considered superior to UO2 under high burn-ups and high temperature gradients. For this reason, the manufacturing feasibility of UCO kernels using modified external sol-gel routes was addressed. The calcining and sintering steps were particularly studied. ii) For its better high temperature performance, ZrC is a candidate coating material for replacing SiC in TRISO (TRistructural ISOtropic) particles. One of the objectives was therefore to deposit a stoichiometric ZrC layer without impurities. An “analytical irradiation” experiment currently performed in the HFR — named PYCASSO for PYrocarbon irradiation for Creep And Swelling/Shrinkage of Objects — was set up to measure the changes in coating material properties as a function of neutron fluence, with samples coming from the new fabrication process. This experiment was started in April 2008 and will provide data on particle component behaviour under irradiation. This data is required to upgrade material models implemented in the ATLAS fuel simulation code. The PYCASSO irradiation experiment is a true Generation IV VHTR effort, with Korean and Japanese samples included in the irradiation. Further RAPHAEL results will be made available to the GIF VHTR Fuel and Fuel Cycle project partners in the future. Post-irradiation examinations and heat-up tests performed on fuel irradiated in an earlier project are being performed to investigate the behaviour of state-of-the-art fuel in VHTR normal and accident conditions. Very interesting results from destructive examinations performed on the HFR-EU1bis pebbles were obtained, showing a clear temperature (and high burn-up) influence on both kernel changes (including fission product behaviour) and the coating layers. Based on fuel particle models established earlier, the fuel modelling capabilities could be further improved: i) Modelling of fuel elements containing thousands of particles is expected to enable a statistical approach to mechanical particle behaviour and fission product release. ii) A database on historical and new fuel properties was built to enable validation of models. This paper reports on recent progress and main results of the RAPHAEL sub-project on fuel technology.Copyright

Simulation of the Westinghouse AP1000 Response to SBLOCA Using RELAP/SCDAPSIM

Great interest is given now to advanced nuclear reactors especially those using passive safety components. The Westinghouse AP1000 Advanced Passive pressurized water reactor (PWR) is an 1117 MWe PWR designed to achieve a high safety and performance record. The AP1000 safety system uses natural driving forces, such as pressurized gas, gravity flow, natural circulation flow, and convection. In this paper, the safety performance of the AP1000 during a small break loss of coolant accident (SBLOCA) is investigated. This was done by modelling the AP1000 and the passive safety systems employed using RELAP/SCDAPSIM code. RELAP/SCDAPSIM is designed to describe the overall reactor coolant system (RCS) thermal hydraulic response and core behaviour under normal operating conditions or under design basis or severe accident conditions. Passive safety components in the AP1000 showed a clear improvement in accident mitigation. It was found that RELAP/SCDAPSIM is capable of modelling a LOCA in an AP1000 and it enables the investigation of each safety system component response separately during the accident. The model is also capable of simulating natural circulation and other relevant phenomena. The results of the model were compared to that of the NOTRUMP code and found to be in a good agreement.

The Oxidation of A3-3 Matrix Material in a CO2 Atmosphere in Support of a Nuclear Battery Type Reactor Design

A significant attraction of a small-scale self-contained nuclear reactor that requires limited human intervention is a reduction in the required infrastructure costs through on-site generation. The option of CO2 coolant rather than helium within a VHTR-type design has been considered, as the use of CO2 results in a higher potential for convective cooling, and lower costs. Within a CO2 coolant environment, graphite components are subject to oxidation, both through radiolysis and potentially thermally, and for modern nuclear graphites alongside the graphitic matrix A3-3, this behaviour must be considered as part of the design process. This research presents the results from irradiation experiments within pressurised sealed quartz ampoules, which have been conducted at The Technical University of Delft, alongside thermal oxidation experiments and material characterisation at The University of Manchester. Characterisation work has been undertaken to understand changes to the microstructure in terms of pre- and post-oxidation. The techniques applied include laser con-focal microscopy and helium pycnometry, with SEM and X-ray tomography planned for future work. The effects of oxidation on A3-3 matrix are compared to two grades of nuclear graphite: NBG-18 and Gilsocarbon with the effects of oxidation on TRISO coated particles also planned for investigation.