T. S. Ivanochko

A review of nitrogen isotopic alteration in marine sediments

Key Points: Use of sedimentary nitrogen isotopes is examined; On average, sediment 15N/14N increases approx. 2 per mil during early burial; Isotopic alteration scales with water depth Abstract: Nitrogen isotopes are an important tool for evaluating past biogeochemical cycling from the paleoceanographic record. However, bulk sedimentary nitrogen isotope ratios, which can be determined routinely and at minimal cost, may be altered during burial and early sedimentary diagenesis, particularly outside of continental margin settings. The causes and detailed mechanisms of isotopic alteration are still under investigation. Case studies of the Mediterranean and South China Seas underscore the complexities of investigating isotopic alteration. In an effort to evaluate the evidence for alteration of the sedimentary N isotopic signal and try to quantify the net effect, we have compiled and compared data demonstrating alteration from the published literature. A >100 point comparison of sediment trap and surface sedimentary nitrogen isotope values demonstrates that, at sites located off of the continental margins, an increase in sediment 15N/14N occurs during early burial, likely at the seafloor. The extent of isotopic alteration appears to be a function of water depth. Depth-related differences in oxygen exposure time at the seafloor are likely the dominant control on the extent of N isotopic alteration. Moreover, the compiled data suggest that the degree of alteration is likely to be uniform through time at most sites so that bulk sedimentary isotope records likely provide a good means for evaluating relative changes in the global N cycle.

Mechanisms for millennial-scale global synchronization during the last glacial period

Global climate during the last glacial period was punctuated by abrupt warmings and occasional pulses of freshwater into the North Atlantic that disrupted deepwater production. These massive freshwater pulses known as Heinrich events arose, in part, from instabilities within the Laurentide ice sheet. Paleoevidence from the North Atlantic suggests that these events altered the production of deep water and changed downstream climate throughout the Northern Hemisphere. In the tropical western Pacific sea, surface temperatures and salinity varied together with ocean and climate changes at high latitudes. Here we present results from coupled modeling experiments that shed light on a possible dynamical link between the North Atlantic Ocean and the western tropical Pacific. This link involves a global oceanic standing wave pattern brought about by millennial-scale glacial density variations in the North Atlantic, atmospheric teleconnections triggered by meridional sea surface temperature gradients, and local air-sea interactions. Furthermore, our modeling results are compared with hydrological records from the Cariaco basin, the Indian Ocean, the Sulu Sea, and northern Australia.