T. Tomila

Closed cycle of recycling of waste activated sludge

The recycling of waste activated sludge (WAS) formed in the process of biological purification of sewage is an urgent ecological problem. In the present work, two ways of recycling of WAS containing from 8 to 30% free water, namely, the synthesis of a carbon-containing component and synthesis of porous building ceramics (bricks) with the use of WAS and waste carbonizate, have been considered. For the preparation of a carbon adsorbent, the carbonization of WAS has been carried out in an argon atmosphere. For the synthesis of ceramics, clay-cullet-tezontle-WAS mixtures with different contents of the components have been used. Sintering has been performed in air. It has been established that, in treatment of WAS at 600 °C for 30 min, better adsorption properties are obtained due to the presence of free carbon bonds. The efficiency of water purification from dyes (methylene blue) depends on the standard conditions: the methylene blue concentration, cabonizate-to-solution ratio, and exposure time of the carbonizate in solution. The use of wet WAS makes it possible to exclude the addition of water from the traditional scheme of preparation of a plastic semiproduct, i.e., realize a water-saving technology. The introduction of low-melting cullet, basalt, and WAS powders into red clay makes enables us to reduce substantially the sintering time of porous bricks (down to 8 h) and vary their strength properties.