Taciana Toledo de Almeida Albuquerque

Potential health impact of ultrafine particles under clean and polluted urban atmospheric conditions: a model-based study

The main goal of this study was to improve the knowledge of ultrafine particle number distributions in large urban areas and also to call the attention to the importance of these particles on assessing health risks. Measurements of aerosol size distributions were performed during 2xa0weeks, with distinct pollutant concentrations (polluted and clean periods), on the rooftop of a building located in downtown of the megacity of São Paulo, Brazil. CO, NO2, PM10, SO2, and O3 concentrations and meteorological variables were also used. Aerosol size distribution measurements showed that geometric mean diameters of the size spectra in the polluted period are on average considerably larger than those in the clean one. Besides the fact that total number of ultrafine particles did not show significant differences, during the polluted period, geometric mean diameter was larger than during the clean one. The results of a mathematical model of particle deposition on human respiratory tract indicated a more significant effect of smaller particles fraction of the spectra, which predominate under clean atmospheric conditions. The results also indicated that urban environmental conditions usually considered good for air quality, under the criteria of low mass concentration, do not properly serve as air quality standard to very small particles. In the size range of ultrafine particles, this traditional clean atmospheric condition can offer a strong risk to pulmonary hazards, since the cleansing of the atmosphere creates good conditions to increase the concentration of nucleation mode particles.

Characterization of atmospheric aerosols in the city of São Paulo, Brazil: comparisons between polluted and unpolluted periods

The objective of this study was to determine the size and composition of atmospheric aerosols in the downtown area of the city of São Paulo, Brazil, for a polluted and an unpolluted period. Aerosols were sampled with a portable air sampler (PAS), Micro-Orifice Uniform Deposit Impactor (MOUDI), and Scanning Mobility Particle Sizer. At the study site, air quality is poor, especially during the winter, high concentrations of pollutants being emitted primarily by the light- and heavy-duty vehicle fleet. We analyzed mass, black carbon (BC), Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br, Rb, Sn, Zr, and Pb. During the polluted period, diurnal PM10 was higher than nocturnal PM10, whereas the inverse was true during the unpolluted period. The FPM was rich in BC, S, and Pb, whereas CPM was rich in Al, Si, Ca, Ti, and Fe. Mass balance was performed by category: ammonium sulfate, sodium chloride, crustal material, BC, and other. The PAS-determined FPM was mainly BC. The MOUDI-determined FPM crustal material explained more mass than did ammonium sulfate and BC during the polluted period, whereas ammonium sulfate had the largest mass during the unpolluted period. Crustal material was the major CPM component, followed by ammonium sulfate and BC. During the unpolluted period, FPM concentrations were lower, whereas those of ammonium sulfate were relatively higher, especially at night, and particle number was inversely proportional to particle size. Aerosol growth was more intense during the polluted period.

Evaluation of weather research and forecasting model parameterizations under sea-breeze conditions in a North Sea coastal environment

Three atmospheric boundary layer (ABL) schemes and two land surface models that are used in the Weather Research and Forecasting (WRF) model, version 3.4.1, were evaluated with numerical simulations by using data from the north coast of France (Dunkerque). The ABL schemes YSU (Yonsei University), ACM2 (Asymmetric Convective Model version 2), and MYJ (Mellor–Yamada–Janjic) were combined with two land surface models, Noah and RUC (Rapid Update Cycle), in order to determine the performances under sea-breeze conditions. Particular attention is given in the determination of the thermal internal boundary layer (TIBL), which is very important in air pollution scenarios. The other physics parameterizations used in the model were consistent for all simulations. The predictions of the sea-breeze dynamics output from the WRF model were compared with observations taken from sonic detection and ranging, light detection and ranging systems and a meteorological surface station to verify that the model had reasonable accuracy in predicting the behavior of local circulations. The temporal comparisons of the vertical and horizontal wind speeds and wind directions predicted by the WRF model showed that all runs detected the passage of the sea-breeze front. However, except for the combination of MYJ and Noah, all runs had a time delay compared with the frontal passage measured by the instruments. The proposed study shows that the synoptic wind attenuated the intensity and penetration of the sea breeze. This provided changes in the vertical mixing in a short period of time and on soil temperature that could not be detected by the WRF model simulations with the computational grid used. Additionally, among the tested schemes, the combination of the localclosure MYJ scheme with the land surface Noah scheme was able to produce the most accurate ABL height compared with observations, and it was also able to capture the TIBL.

PREVISÃO DA CONCENTRAÇÃO DE OZÔNIO NA REGIÃO DA GRANDE VITÓRIA, ESPÍRITO SANTO, BRASIL, UTILIZANDO O MODELO ARMAX-GARCH

O objetivo deste trabalho foi estimar e prever a concentracao horaria de ozonio na Regiao da Grande Vitoria, Espirito Santo, Brasil, utilizando um modelo ARMAX-GARCH, para o periodo 01/01/2011 a 31/12/2011. Foram utilizados dados da rede de monitoramento do Instituto Estadual de Meio Ambiente e Recursos Hidricos (IEMA), sendo escolhidas tres estacoes: Laranjeiras, Enseada do Sua e Cariacica. Adotou-se alguns parâmetros medidos nas estacoes como variaveis explicativas da concentracao de ozonio, a saber: temperatura, umidade relativa, velocidade do vento e concentracao de dioxido de nitrogenio. Estas foram significativas e melhoraram a estimativa do modelo ajustado. As previsoes horarias para o dia 31/12/2011 revelaram-se muito proximas dos valores observados, sendo que as estimativas, em geral, seguiram a trajetoria diaria da concentracao de ozonio. No mais, em comparacao aos modelos ARMA e ARMAX, o modelo ARMAX-GARCH revelou-se mais eficaz na predicao de episodios de poluicao de ozonio (concentracao horaria superior a 80 µg/m3), reduziu o numero de falsos alarmes estimados e apresentou menor taxa de ocorrencia de episodios nao detectados.

Automatic methods to detect the top of atmospheric boundary layer

The main objective of this work is to obtain methods that automatically allow qualitative detections of Atmospheric Boundary Layer heights from LIDAR data. Case studies will be used to describe the more relevant days of a campaign carried out in July of 2012 in Vitória, Espírito Santo, Brazil. The data analysis compares three mathematical algorithms that automatically provide the ABL height: Gradient Method (GM), using the derivative of the Range Corrected Signal (RCS) logarithm, WCT (Wavelet Covariance Transform), and Bulk Richardsons Number, which was used to validate the methods mentioned above. The comparison between the methods has shown that as the presence of clouds and the aerosol sublayer increased, the more sensitive was the refinement needed to choose the “right” parameters, whereas even Richardson’s method had ambiguities in finding a good estimate of the ABL top.

Solution of the Atmospheric Diffusion Equation with Longitudinal Wind Speed Depending on Source Distance

An integral semi-analytical solution of the atmospheric diffusion equation considering wind speed as a function of both downwind distance from a pollution source and vertical height is presented. The model accounts for transformation and removal mechanisms via both chemical reaction and dry deposition processes. A hypothetical dispersion of contaminants emitted from an urban pollution source in the presence of mesoscale winds in an unstable atmospheric boundary layer is showed. The results demonstrate that the mesoscale winds generated by urban heat islands advect contaminants upward, which increases the intensity of air pollution in urban areas.

FORMAÇÃO E TRANSPORTE DAS PARTÍCULAS FINAS INORGÂNICAS EM UMA ATMOSFERA URBANA: O EXEMPLO DE SÃO PAULO

Formacao e transporte das particulas finas inorgânicas emuma atmosfera urbana: o exemplo de Sao Paulo