Tadahiko Miyoshi

Characteristics of hot-pressed fiber-reinforced ceramics with SiC matrix

Silicon carbide ceramics’ matrix composites with SiC or C filaments were fabricated through hot pressing, and the effects of the filament pullout on their fracture toughness were experimentally investigated. The C-rich coating layers on the SiC filaments were found to have a significant effect on the frictional stress at the filament/matrix interfaces, through assising the filamet pullout from the matrix. Although the coating layers were apt to burn out in the sintering process of SiC matrix compposites, a small addition of carbon to the raw materials was found to be effective for the retention of the layers on the fibers, thus increasing the fracture toughness of the composites. The fracture toughness of the C filament/SiC matrix composite increased with temperature due to the larger interfacial frictional stress at higher temperatures, because of the higher thermal expansion of the filament in the radial direction than that of the matrix.

Degradation of Zinc Oxide Varistors

The effect of ambient gases on degradation and rejuvenation of ZnO varistors was investigated from the viewpoint of voltage-current characteristics. Ambient oxygen gas suppressed increases in the leakage current during ac biasing, while it rejuvenated degraded samples. The time dependence of rejuvenation indicated that ion migrations, possibly the desorption and adsorption of oxygen ions at the grain boundaries, occur reversibly in degradation and rejuvenation. Moreover, a noticeable difference was observed between V–I curve shapes after ac biasing in nitrogen and in oxygen atmospheres.