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Dive into the research topics where Takumi Kagawa is active.

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Featured researches published by Takumi Kagawa.


Tetrahedron Letters | 2003

Highly enantioselective homogeneous catalysis of chiral rare earth phosphates in the hetero-Diels–Alder reaction

Hiroshi Furuno; Takeshi Kambara; Yumiko Tanaka; Takeshi Hanamoto; Takumi Kagawa; Junji Inanaga

Abstract Two types of novel rare earth (RE) complexes were synthesized and used as a chiral Lewis acid catalyst for the hetero-Diels–Alder reaction of carbonyl compounds with the Danishefskys diene under homogeneous conditions. The Y[( R )-H 8 -BNP] 3 ( 3 -Y )-catalyzed reaction of aromatic aldehydes and the Yb[( R )-BNP] 3 ( 1 -Yb )-catalyzed reaction of phenylglyoxylates afforded the corresponding cycloadducts with excellent optical purities (up to 99% ee) in high yields at room temperature. The successful recycling uses of the scandium catalyst ( 3 -Sc ) are also described.


Tetrahedron | 2003

Chiral rare earth organophosphates as homogeneous Lewis acid catalysts for the highly enantioselective hetero-Diels-Alder reactions

Hiroshi Furuno; Tetsuji Hayano; Takeshi Kambara; Yuichi Sugimoto; Takeshi Hanamoto; Yumiko Tanaka; Yong Zhi Jin; Takumi Kagawa; Junji Inanaga


Chirality | 2003

Asymmetric catalysis with self-organized chiral lanthanum complexes: Practical and highly enantioselective epoxidation of α,β-unsaturated ketones

Kazuhiro Daikai; Tetsuji Hayano; Rie Kino; Hiroshi Furuno; Takumi Kagawa; Junji Inanaga


Archive | 1997

Flame retardant and flame retardant resin composition formulated with the same

Kimitaka Kuma; Kenji Koyama; Nobuhiro Fujita; Takumi Kagawa; Fumio Okisaki; Keiji Itabashi


Archive | 1997

Brominated p-cumylphenol flame-retardants for resin composition

Takumi Kagawa; Norihisa Kondo; Noriyuki Kasai; Hideo Sakka


Archive | 1997

Brominated styrene oligomer, its production and flame-retardant resin composition compounded with the same

Takumi Kagawa; Hideo Sakka; 秀雄 属; 巧 香川


Archive | 2002

Optically active maleimide derivatives, optically active polymaleimide derivatives,production method thereof, separating agent using the same derivative, and method for separating optically active compounds using the same agent

Takumi Kagawa; Hideo Sakka


Archive | 1988

4,4'-Bis(phthalimid)diphenyl sulfone compounds, processes for their production and flame retardant polymer compositions containing them

Takao Matsuba; Masashige Kubo; Takumi Kagawa; Kiyotaka Oyama; Koji Kawabata


Archive | 2004

Optically active fluorine-containing compounds and processes for their production

Takuya Miyata; Toshio Naka; Takumi Kagawa


Archive | 2003

Optically active epoxy compounds and processes for their production

Takumi Kagawa; Takeshi Kambara; Hideo Sakka; Manabu Yanase

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