Tanya Furman

Erosion of lithospheric mantle beneath the East African Rift system: geochemical evidence from the Kivu volcanic province

Abstract This study presents new major and trace element and Sr–Nd isotopic results for a suite of Miocene–Recent mafic lavas from the Kivu volcanic province in the western branch of the East African Rift. These lavas exhibit a very wide range in chemical and isotopic characteristics, due to a lithospheric mantle source region that is heterogeneous on a small scale, probably 87 Sr / 86 Sr , (La/Sm)n, Ba/Nb, and Zr/Hf than the majority of Kivu (Bukavu) samples. The range of 87 Sr / 86 Sr at Tshibinda (0.70511–0.70514) overlaps some compositions found in the neighboring Virunga province, while Bukavu group lavas include the lowest 87 Sr / 86 Sr (0.70314) and highest eNd (+7.6) yet measured in western rift lavas. The Tshibinda compositions trend towards a convergence for Sr–Nd–Pb isotopic values among western rift lavas. Among Kivu lavas, variations in 143 Nd / 144 Nd correlate with those for certain incompatible trace element ratios (e.g., Th/Nb, Zr/Hf, La/Nb, Ba/Rb), with Tshibinda samples defining one compositional extreme. There are covariations of isotopic and trace element ratios in mafic lavas of the East African Rift system that vary systematically with geographic location. The lavas represent a magmatic sampling of variations in the underlying continental lithospheric mantle, and it appears that a common lithospheric mantle (CLM) source is present beneath much of the East African Rift system. This source contains minor amphibole and phlogopite, probably due to widespread metasomatic events between 500 and 1000 Ma. Lava suites which do not show a strong component of the CLM source, and for which the chemical constraints also suggest the shallowest magma formation depths, are the Bukavu group lavas from Kivu and basanites from Huri Hills, Kenya. The inferred extent of lithospheric erosion therefore appears to be significant only beneath these two areas, which is generally consistent with lithospheric thickness variations estimated from gravity and seismic studies.

Heads and tails: 30 million years of the Afar plume

Abstract Primitive recent mafic lavas from the Main Ethiopian Rift provide insight into the structure, composition and long-term history of the Afar plume. Modern rift basalts are mildly alkalic in composition, and were derived by moderate degrees of melting of fertile peridotite at depths corresponding to the base of the modern lithosphere (c.100 km). They are typically more silica-undersaturated than Oligocene lavas from the Ethiopia-Yemen continental flood basalt province, indicating derivation by generally smaller degrees of melting than were prevalent during the onset of plume head activity in this region. Major and trace element differences between the Oligocene and modern suites can be interpreted in terms of melting processes, including melt-induced binary mixing of melts from the Afar plume and those from three mantle end-member compositions (the convecting upper mantle and two enriched mantle sources). The Afar plume composition itself has remained essentially constant over the past 30 million years, indicating that the plume is a long-lived feature of the mantle. The geochemical and isotopic compositions of mafic lavas derived from the Afar plume support a modified single plume model in which multiple plume stems rise from a common large plume originating at great depth in the mantle (i.e. the South African superplume).

Geophysical project in Ethiopia studies continental breakup

As continental rift zones evolve to sea floor spreading, they do so through progressive episodes of lithospheric stretching, heating, and magmatism, yet the actual process of continental breakup is poorly understood. The East African Rift system in northeastern Ethiopia is central to our understanding of this process, as it lies at the transition between continental and oceanic rifting [Ebinger and Casey, 2001]. We are exploring the kinematics and dynamics of continental breakup through the Ethiopia Afar Geoscientific Lithospheric Experiment (EAGLE), which aims to probe the crust and upper mantle structure between the Main Ethiopian (continental) and Afar (ocean spreading) rifts, a region providing an ideal laboratory to examine the process of breakup as it is occurring. EAGLE is a multidisciplinary study centered around the most advanced seismic project yet undertaken in Africa (Figure l). Our study follows the Kenya Rift International Seismic Project [e.g., KRISP Working Group, 1995],and capitalizes on the IRIS/PASSCAL broadband seismic array [Nyblade and Langston, 2002], providing a telescoping view of the East African Rift within this suspected plume province.

The role of continental lithosphere metasomes in the production of HIMU-like magmatism on the northeast African and Arabian plates

Intraplate alkaline lavas typically exhibit isotopic characteristics that require a source with long-term isolation from the convecting asthenosphere, such as in the sub-continental lithosphere mantle or a mantle boundary layer. Melting of metasomatically enriched domains, or metasomes, within the lithospheric mantle provides a viable mechanism for generating the geochemical characteristics of intraplate alkaline basalts. The origins and distribution of these metasomes have been attributed to recent enrichment of the lithosphere by a mantle plume or ancient events that occurred during the early evolution of the sub-continental lithosphere mantle. Here, we present a geochemical study of Ethiopian Miocene intraplate alkaline lavas: melts of a lithospheric mantle that was enriched metasomatically during lithospheric stabilization and by recent plume-lithosphere interaction. We find that these lavas have geochemical characteristics consistent with melting of an amphibole-bearing lithospheric-mantle metasome. New Pb and Hf isotope data for these lavas require a HIMU-like source component, similar to other alkaline lavas erupted through the Horn of Africa, Sudan, and Egypt, and adjacent Arabian plate lithospheres. The isotopic characteristics of this component are distinct from the Afar plume mantle source and instead are consistent with the long-term evolution of a lithospheric metasome created during a Neoproterozoic subduction event associated with the Pan-African orogeny. The widespread distribution of easily fusible lithospheric metasomes within the continental lithosphere mantle may facilitate magma generation without the need for substantial lithospheric thinning or elevated mantle potential temperatures. Mantle heterogeneity of this nature has implications for the source origin of HIMU magmas associated with continental lithosphere.

Longitudinal and seasonal patterns of stream acidity in a headwater catchment on the Appalachian Plateau, West Virginia, U.S.A.

The chemical composition during baseflow was used to elucidate the fundamental processes controlling longitudinal and seasonal patterns of stream acidity in Yellow Creek, a chronically acidic headwater (pH range 3.7--4.2) on the Appalachian Plateau in northeastern West Virginia. Sulfate concentrations controlled the variability of stream acidity within the Yellow Creek catchment. Decreases in stream free H+ acidity with decreasing elevation likely resulted from SO42− retention in riparian wetland areas as well as spatial variation in dominant tree species. Seasonal variations in free H+ and inorganic monomeric aluminum (Aln+) concentrations appeared related to seasonal fluctuations in baseflow discharge which was controlled by vegetative activity. Baseflow stream discharge, as well as H+ and Aln+ acidity, gradually declined during the growing season (June through October), likely reflecting microbial SO42−> reduction in saturated anaerobic environments within riparian wetlands. A marked pulse of stream H+, Aln+, and SO42− coincided with an abrupt increase in baseflow discharge resulting from the cessation of transpiration after leaf-fall in November. This seasonal pattern suggests that autumn may be a critical period for eastern brook trout in streams draining wetlands on the Appalachian Plateau.

Magmatic activity across the East African North Tanzanian Divergence Zone

Volcanism across the North Tanzanian Divergence Zone (NTD), part of the East African Rift System, occurred episodically from the late Miocene to Recent. Here, we present a summary of previously published K–Ar and 40Ar/39Ar ages, new 40Ar/39Ar ages, and geochemical and Sr–Nd–Pb isotopic analyses on samples collected from several volcanoes distributed across the NTD: Burko, Monduli, Tarosero, Ketumbeine, Gelai, Kerimasi and Meru. The locus of volcanism over this period progressed from the southwestern portion of the NTD to the north and east, with a main pulse occurring at about 2.3 Ma, possibly marking the inception of a main rifting event. We model the source of the NTD volcanic rocks as a metasomatized subcontinental lithospheric mantle that includes minor and variable amounts of garnet and amphibole. REE data indicate variations in residual garnet content, consistent with varying depth of melt separation. Radiogenic isotopic data show systematic variations requiring the involvement of up to three components. Two alternative but not exclusive tectonic scenarios are proposed: one requiring the involvement of contributions from recent plume-related fluids, and one explaining the observed geochemical variations by melting of a lithosphere layered by multiple metasomatic events. Supplementary material: Details of analytical methods, operating system and calibration methods, a summary table of the recalculated 40Ar/39Ar and K–Ar NTD ages, a complete set of detailed release spectra analysis and dating figures, 40Ar/39Ar incremental heating data and analytical conditions, and examples of NTD calculated fractional crystallization modes are available at http://www.geolsoc.org.uk/SUP18813.

PRIMARY MINERAL WEATHERING IN THE CENTRAL APPALACHIANS : A MASS BALANCE APPROACH

Abstract We use a mass balance approach to calculate long-term weathering rates for three forested watersheds in the southeastern USA. One watershed (Shaver Hollow) is underlain by Precambrian granodiorite, and two (White Oak Run, Deep Run) are underlain by Cambrian metasedimentary units. Each of the study areas receives high levels of acidic precipitation, and each watershed was almost completely defoliated by gypsy moth larvae for at least two consecutive years during the study period. Our analysis uses stream and precipitation chemistry obtained weekly from 1987 to 1993 for Shaver Hollow and from 1980 to 1993 for White Oak Run and Deep Run. Mass balance calculations for the granodiorite watershed indicate that plagioclase feldspar is the dominant reactant and that basalt dikes which comprise a small fraction of the catchment make a significant contribution to the base cation budget. Corresponding calculations for the metasedimentary bedrock watersheds indicate contributions from plagioclase feldspar, muscovite, and biotite. At best, the mass balance models provide an approximation of weathering processes because the soils are immature and contain few stoichiometric clay minerals such as kaolinite. Annual cation release rates from Shaver Hollow suggest soil profile ages of ∼4 ka, consistent with the observed surficial geology and the geological history of the area. Base cation efflux patterns during the period of severe defoliation differ markedly between the three watersheds and reflect a continuum of ecosystem sensitivities. The Pedlar granodiorite system is relatively robust to the effects of disturbance: calculated weathering rates and proportions change by

Increasing Diversity in the Geosciences: Recruitment Programs and Student Self-Efficacy

Using a conceptual framework constructed around self-efficacy, this study explores specific recruitment programs that may contribute to the development of self-efficacy for students of color in the geosciences. This mixed methods study of geoscience education includes quantitative analysis of the Summer Experience in Earth and Mineral Science Program and qualitative analysis of the Summer Research Opportunity Program. Findings identify programmatic components that fostered self-efficacy, thus contributing to students’ continued interest in careers in geoscience. This study has potential implications for higher education institutions interested in cultivating programs that attract, support, and retain students of color through various stages of the geoscience education pipeline.

Geochemistry of 24 Ma basalts from NE Egypt: source components and fractionation history

Abstract Subalkaline basalts from NE Egypt represent an episode of magmatism at c. 24 Ma, coincident with widespread eruptive activity in northern Africa. New geochemical data provide insight into the mineralogical and isotopic characteristics of the underlying mantle. The basalts show little geochemical variation, with incompatible trace element abundances similar to those of ocean island basalts. They display fairly smooth primitive mantle-normalized incompatible trace element patterns. Trace element abundances and Sr–Nd–Pb–Hf isotopic signatures are consistent with contributions from two distinct source regions, one similar to the Afar plume and the other located within the metasomatized spinel-facies subcontinental lithosphere. Mixing of melts from these two domains was followed by minor crustal contamination during prolonged ascent or emplacement. Integrating the geochemical data with available tomographic information allows us to develop a framework for understanding mid-Tertiary magmatic activity throughout northern Africa. A model for this widespread volcanism involves ascent of upwelling mantle derived from the margins of the South African Superplume rooted at the core–mantle boundary and/or through small-scale convection at the 660 km discontinuity. Ascent of magmas to the surface was facilitated by pre-existing structures within the lithosphere, including those associated with incipient rifting of the Red Sea. Supplementary material: Mineral chemistry data are available at http://www.geolsoc.org.uk/SUP18483.

A real-world plan to increase diversity in the geosciences

Quinton Williams (quinton.l.williams@jsums.edu) is chair and associate professor of physics at Jackson State University in Jackson, Mississippi. Vernon Morris (vmorris@howard.edu) is an associate professor in the chemistry department at Howard University in Washington, DC. Tanya Furman (furman@geosc.psu.edu) is a professor in the department of geosciences at Pennsylvania State University, University Park, Pennsylvania.