Teamrat A. Ghezzehei

A new method for rapid determination of carbohydrate and total carbon concentrations using UV spectrophotometry

A new UV spectrophotometry based method for determining the concentration and carbon content of carbohydrate solution was developed. This method depends on the inherent UV absorption potential of hydrolysis byproducts of carbohydrates formed by reaction with concentrated sulfuric acid (furfural derivatives). The proposed method is a major improvement over the widely used Phenol-Sulfuric Acid method developed by DuBois, Gilles, Hamilton, Rebers, and Smith (1956). In the old method, furfural is allowed to develop color by reaction with phenol and its concentration is detected by visible light absorption. Here we present a method that eliminates the coloration step and avoids the health and environmental hazards associated with phenol use. In addition, avoidance of this step was shown to improve measurement accuracy while significantly reducing waiting time prior to light absorption reading. The carbohydrates for which concentrations and carbon content can be reliably estimated with this new rapid Sulfuric Acid-UV technique include: monosaccharides, disaccharides and polysaccharides with very high molecular weight.

Modeling post-tillage soil structural dynamics: a review

Abstract Tillage modifies the soil structure to create conditions favorable for plant growth. However, the resulting loose structure is susceptible to collapse by internal capillary forces and external compactive stresses with concurrent changes in soil hydraulic properties. Presently, limited understanding of these complex processes often leads to consideration of the soil plow-layer as a static porous medium. Our objective is to provide a review of recent progress in modeling soil structural dynamics at the pore-scale, based on soil mechanical and rheological properties. The basic geometrical framework of the models was a cubic arrangement of monosized spherical aggregates (other arrangements are discussed). The process of soil aggregate rejoining by capillary forces was modeled by considering the rate of energy dissipation due to viscous deformation of wet soil, and corresponding energy release due to reconfiguration of water capillary menisci. The model was complemented by independent rheological characterization of soil that provides control on the rate as well as the onset and termination of aggregate coalescence. The model was also adapted for consideration of steady stress (such as overburden) acting upon the unit cells. Unlike steady stress, transient stress (such as traffic) is applied for too short of a period to allow for total energy dissipation by viscous deformation. Hence, a portion of the deformation is elastic (with a recoverable portion of the applied energy). Rheological characterization under transient (oscillatory) stress provided coupled elastic and viscous properties under several loading frequencies. Effects of transient stresses on the geometrical model were modeled by considering a combination of (i) Hertzian-type elastic strain and (ii) viscous flow of soil at the contacts. Application of the models is demonstrated using illustrative examples and rheological measurements of Millville silt loam soil. Finally, we provide an outlook for upscaling the unit cell results to an aggregate bed scale.

Modeling the dynamics of the soil pore-size distribution

Soil tillage often results in a structurally unstable soil layer with an elevated inter-aggregate porosity that is gradually decreased by the interplay of capillary and rheological processes. We have previously proposed to describe the evolution of the pore-size distribution (PSD) with the Fokker–Planck equation (FPE). The coefficients of this equation quantify the drift, dispersion, and degradation processes acting upon the PSD. An analytical solution for the PSD is presented for the case where drift and degradation coefficients depend on time, and the dispersion coefficient is proportional to the drift coefficient. These coefficients can be estimated from independent measurements of the PSD or (surrogate) water retention data or from mechanistic models. In this paper, we illustrate the application of the pore-size evolution model for: (i) a generic drift coefficient, (ii) static water retention data for soils under different tillage regimes, and (iii) dynamic hydraulic data for a soil subject to a sequence of wetting and drying cycles. These applications show the viability of our approach to model pore-size evolution. However, the development and application of the model is hampered by a lack of definitive data on soil structural and hydraulic dynamics.

Dynamics of soil aggregate coalescence governed by capillary and rheological processes

The desired soil structure following tillage of agricultural soils is often unstable and susceptible to coalescence of aggregates and reduction of interaggregate porosity due to wetting and drying cycles. This process of aggregate rejoining was modeled by equating the rate of work done by liquid-vapor menisci, to the rate of energy dissipation due to viscous deformation of a pair of spherical aggregates. The nonlinearity of wet soil viscous flow behavior was accounted for by introducing a Bingham rheological model. A natural outcome of the analysis was the formulation of a mathematical condition for the onset and termination of coalescence based on soil strength at specified water content. The condition states that sufficient energy in excess of soil strength (yield stress) must be available for coalescence to proceed. The rate of aggregate coalescence is proportional to available energy and is inversely related to the coefficient of plastic viscosity. Transport of wet soil to the periphery of the interaggregate contact by viscous flow leads to smoothing of the neck, resulting in pore closure, on the one hand, and restricting the minimum matric potential that can be achieved, on the other. The interplay between rheology and geometry prevent coalescence from proceeding indefinitely. Independently determined soil rheological properties were used to illustrate the use of the model. Coalescence under constant water content and during wetting-drying cycles was calculated. Comparison of data from experiments on one-dimensional, aggregate bed settlement has shown reasonable agreement with the model predictions.

Stochastic model for posttillage soil pore space evolution

Tillage operations disrupt surface layers of agricultural soils, creating a loosened structure with a substantial proportion of interaggregate porosity that enhances liquid and gaseous exchange properties favorable for plant growth. Unfortunately, such desirable soil tilth is structurally unstable and is susceptible to change by subsequent wetting and drying processes and other mechanical stresses that reduce total porosity and modify pore size distribution (PSD). Ability to model posttillage dynamics of soil pore space and concurrent changes in hydraulic properties is important for realistic predictions of transport processes through this surface layer. We propose a stochastic modeling framework that couples the probabilistic nature of pore space distributions with physically based soil deformation models using the Fokker-Planck equation (FPE) formalism. Three important features of soil pore space evolution are addressed: (1) reduction of the total porosity, (2) reduction of mean pore radius, and (3) changes in the variance of the PSD. The proposed framework may be used to provide input to hydrological models concerning temporal variations in near-surface soil hydraulic properties. In a preliminary investigation of this approach we link a previously proposed mechanistic model of soil aggregate coalescence to the stochastic FPE framework to determine the FPE coefficients. An illustrative example is presented which describes changes in interaggregate pore size due to wetting-drying cycles and the resulting effects on dynamics of the soil water characteristic curve and hydraulic conductivity functions.

Effectiveness of biochar for sorption of ammonium and phosphate from dairy effluent.

The use of biochar for recovery of excess nutrients in dairy manure effluent and the use of nutrient-enriched biochar as soil amendment can offer a robust solution for multiple environmental issues. In this study we determined the capacity of biochar, produced by pyrolyzing mixed hardwood feedstock at 300°C, to adsorb and retain or release two major nutrient ions: ammonium (NH) and phosphate (PO). We conducted the experiment using a range of nutrient concentrations that represent those commonly observed in dairy manure effluent (0-50 mg L for PO and 0-1000 mg L for NH). Up to 5.3 mg g NH and 0.24 mg g PO was adsorbed from manure by biochar (18 and 50% of total amount in the manure slurry, respectively). During the desorption phase of the experiment, biochar retained 78 to 91% of the sorbed NH and 60% of the sorbed PO at reaction times <24 h. Our findings confirm that biochar can be used for recovering excess nitrogen and phosphorus from agricultural water, such as dairy manure effluent.

Impact of biochar enriched with dairy manure effluent on carbon and nitrogen dynamics.

Amending soils with biochar can have multiple environmental benefits, including improvement in soil physicochemical properties, carbon sequestration, reduction in leaching losses of essential nutrients, and reduction in greenhouse gas (GHG) emissions. This study was conducted to determine the effect of enriched biochar amendments on leaching losses of essential nutrients and GHG emissions from soil. The enriched biochar was prepared by shaking biochar with dairy manure effluent for 24 h, which increased the C and N concentration of biochar by 9.3 and 8.3%, respectively. Incubation and leaching experiments were conducted for 8 wk with three treatments: soil, soil + 1% biochar, and soil + 1% enriched biochar. Amendment with biochar and enriched biochar relative to unamended soil resulted in 68 and 75% reduction in net nitrification, 221 and 229% reduction in net ammonification, 67 and 68% reduction in cumulative CO flux, respectively, and 26% reduction in cumulative NO flux for both biochar treatments. There were no significant differences among treatments in total leaching losses of C, N, and base cations. Our findings suggest that enrichment of biochar with dairy manure effluent can promote C and N storage in soil and provide additional environmental benefits.

Effects of root-induced compaction on rhizosphere hydraulic properties--X-ray microtomography imaging and numerical simulations.

Soil compaction represents one of the most ubiquitous environmental impacts of human development, decreasing bulk-scale soil porosity and hydraulic conductivity, thereby reducing soil productivity and fertility. At the aggregate-scale however, this study shows that natural root-induced compaction increases contact areas between aggregates, leading to an increase in unsaturated hydraulic conductivity of the soils adjacent to the roots. Contrary to intuition, water flow may therefore be locally enhanced due to root-induced compaction. This study investigates these processes by using recent advances in X-ray microtomography (XMT) imaging and numerical water flow modeling to show evolution in interaggregate contact and its implications for water flow between aggregates under partially saturated conditions. Numerical modeling showed that the effective hydraulic conductivity of a pair of aggregates undergoing uniaxial deformation increased following a nonlinear relationship as the interaggregate contact area increased due to increasing aggregate deformation. Numerical modeling using actual XMT images of aggregated soil around a root surrogate demonstrated how root-induced deformation increases unsaturated water flow toward the root, providing insight into the growth, function, and water uptake patterns of roots in natural soils.

Modeling Coupled Evaporation and Seepage in Ventilated Cavities

Cavities excavated in unsaturated geological formations are important to activities such as nuclear waste disposal and mining. Such cavities provide a unique setting for simultaneous occurrence of seepage and evaporation. Previously, inverse numerical modeling of field liquid-release tests and associated seepage into cavities were used to provide seepage-related large-scale formation properties, ignoring the impact of evaporation. The applicability of such models was limited to the narrow range of ventilation conditions under which the models were calibrated. The objective of this study was to alleviate this limitation by incorporating evaporation into the seepage models. We modeled evaporation as an isothermal vapor diffusion process. The semiphysical model accounts for the relative humidity (RH), temperature, and ventilation conditions of the cavities. The evaporation boundary layer thickness (BLT) over which diffusion occurs was estimated by calibration against free-water evaporation data collected inside the experimental cavities. The estimated values of BLT were 5 to 7 mm for the open underground drifts and 20 mm for niches closed off by bulkheads. Compared with previous models that neglected the effect of evaporation, this new approach showed significant improvement in capturing seepage fluctuations into open cavities of low RH. At high relative-humidity values (>85%), the effect of evaporation on seepage was very small.

Correspondence of the Gardner and van Genuchten–Mualem relative permeability function parameters

The Gardner and van Genuchten models of relativepermeability are widely used in analytical and numerical solutions toflow problems. However, the applicab ility of the Gardner model to realproblems is usually limited, because empirical relative permeability datato calibrate the model are not routinely available. In contrast, vanGenuchten parameters can be estimated using more routinely availablematric potential and saturation data. However, the van Genuchten model isnot amenable to analytical solutions. In this paper, we introducegeneralized conversion formulae that reconcile these two models. Ingeneral, we find that the Gardner parameter alpha G is related to the vanGenuchten parameters alpha vG and n by alpha G=alpha vG ~; 1:3 n. Thisconversion rule will allow direct recasting of Gardner-based analyticalsolutions in the van Genuchten parameter space. The validity of theproposed formulae was tested by comparing the predicted relativepermeability of various porous media with measured values.