Teck-Leong Lee

Synthesis and Mesomorphic Properties of New Fluorinated Schiff Base Liquid Crystals

Two new compounds, 4-alkanoyloxybenzylidene--fluoroaniline and 4-fluorobenzylidene--n-alkanoyloxyaniline comprising a terminal fluorosubstituent were studied. The fluoro substituent contributes to the molecular polarizability, thus affecting intermolecular interactions and hence resulting in smectic mesomorphism. The mesomorphic properties were studied using differential scanning calorimetry and polarizing optical microscopy techniques. The mesomorphic properties of compounds studied are strongly dependent on the orientation of the imine (CH=N) linkage. The former Schiff base exhibited smectic A phase whereas the latter compound did not display any mesophase. Reversed imine linkage has caused depression of mesomorphic property in the compound studied (4-fluorobenzylidene--n-alkanoyloxyaniline). The mesomorphic properties of the present compounds were compared with other structurally related series to establish the chemical structure-mesomorphic property relationship.

Synthesis of 2-(4-Propyloxyphenyl)benzothiazole

A new 2-(4-propyloxyphenyl)benzothiazole was synthesized and its IR, 1H and 13C NMR and MS spectroscopic data are presented.

4-{[(4-Iodophenyl)imino]methyl}phenyl Octadecanoate

A new Schiff base ester, 4-{[(4-iodophenyl)imino]methyl}phenyl octadecanoate was synthesized and its IR, 1H NMR, 13C NMR and EI-MS spectroscopic data are presented.

4-({[4-(Methylthio)phenyl]methylene}amino)phenyl Dodecanoate

A new Schiff base ester, 4-({[4-(methylthio)phenyl]methylene}amino)phenyl dodecanoate was synthesized and its IR, 1H NMR, 13C NMR and EI-MS spectroscopic data are presented.

2-(4-Heptyloxyphenyl)benzothiazole

2-(4-Heptyloxyphenyl)benzothiazole was synthesized and its IR, 1H NMR and MS spectroscopic data are presented.