Teemu Sarikka

High performance carbon-based printed perovskite solar cells with humidity assisted thermal treatment

We report humidity assisted thermal exposure (HTE) as a post-treatment method for carbon based printed perovskite solar cells (CPSCs). The method does not only improve the interfaces of different layers of the printed stack, but also provides a pathway to fabricate high performance CPSCs with low hysteresis along with high stability. The HTE treatment directly influences over the associated components in the stack and remarkably improves each photovoltaic parameter of the CPSCs as seen by several characterization schemes presented in this study. The average initial efficiency (9.0% ± 0.2%) of the CPSCs of a batch was significantly improved to 13.1% ± 0.2% i.e. as high as 45% when subjected to HTE treatment for a period of 200 hours. Furthermore, the highest average efficiency obtained from the same batch from reverse scanning was 13.8% ± 0.4% with a CPSC attaining as high as 14.3% when exposed to the same thermo-humid environment for a period of 115 hours. Above all, the stability of the HTE treated CPSCs was also not compromised for over 350 hours under full-sun illumination stress testing at 40 °C. The results presented in this work provide an opportunity to adopt HTE treatment as a complementary step for the fabrication of high-performance carbon-based perovskite solar cells with low hysteresis accompanied by high durability and performance reproducibility.

Characterisation of local grain size variation of welded structural steel

Previously, it has been shown that the grain size distribution plays an important role in the mechanical properties of welded steel. In the previous investigation, the volume-weighted average grain size has been shown to capture the influence of grain size distribution, resulting in a better fitting Hall–Petch relationship between grain size and hardness. However, the previous studies exclude the effects arising from local variation in grain size. In this paper, the grain size measurement methods are extended for the characterisation of the local grain size variation, which is significant for welded joints and can have an adverse effect on mechanical properties. The local gradient of grain size variation and its dependency on measurement direction are considered. In addition, examples of grain size and hardness variation are shown for S355 base metal and two weld metals, and characteristic differences are highlighted and discussed. The coarse-grained areas of a heterogeneous microstructure are found to have lower hardness than fine-grained areas. However, the surrounding microstructure, i.e. local grain size gradient, has an influence on the measured hardness values.

Microstructural Characterization of Alloy 52 Narrow-Gap Dissimilar Metal Weld After Aging

The safe-end dissimilar metal weld (DMW) joining the reactor pressure vessel to the main coolant piping is one of the most critical DMWs in a nuclear power plant (NPP). DMWs have varying microstructures at a short distance across the ferritic-austenitic fusion boundary (FB) region. This microstructural variation affects the mechanical properties and fracture behavior and may evolve as a result of thermal aging during long-term operation of an NPP. This paper presents microstructural characterization performed for as-manufactured and 5000 h and 10,000 h thermally aged narrow-gap DMW representing a safe-end DMW of a modern pressurized water reactor (PWR) NPP. The most significant result of the study is that the thermal aging leads to a significant decrease in a hardness gradient observed across the ferritic-austenitic FB of the as-manufactured DMW.

The Paths of Small Fatigue Cracks in High-Strength Steels Initiated from Inclusions and Small Defects

In fatigue, the early growth mechanisms, paths, and rates of the microstructurally small cracks are not well known. Growth of subsurface—undetected—cracks cannot be monitored in real time, and postfracture fractography is complicated because of the statistical nature of local microstructure. Furthermore, hammering or sliding often damages the fracture surface before the test is stopped. We addressed this challenge with two approaches. This paper deals with fractographic details connected to local microstructure obtained by milling and imaging with a focused ion beam in a scanning electron microscope (SEM). The results provided input such as crack growth on adjacent planes and their coalescence, as well as formation of the “optically dark areas” that play a key role in the early growth and initiation of small cracks in fatigue. A subset of data consisting of eleven 100Cr6 bearing steel specimens loaded at the same stress amplitude, with fatigue lives (Nf) in the range of 10·106 < Nf < 650·106 loading cycles are studied and discussed. The second test series revealed that very early initiation and crack arrest are typical for small notches in the 34CrNiMo6 QT steel. The relation of crack path and microstructure, along with their connection to the optically dark area, is discussed.

Hydrogen-induced delayed cracking in TRIP-aided lean-alloyed ferritic-austenitic stainless steels

Susceptibility of three lean-alloyed ferritic-austenitic stainless steels to hydrogen-induced delayed cracking was examined, concentrating on internal hydrogen contained in the materials after production operations. The aim was to study the role of strain-induced austenite to martensite transformation in the delayed cracking susceptibility. According to the conducted deep drawing tests and constant load tensile testing, the studied materials seem not to be particularly susceptible to delayed cracking. Delayed cracks were only occasionally initiated in two of the materials at high local stress levels. However, if a delayed crack initiated in a highly stressed location, strain-induced martensite transformation decreased the crack arrest tendency of the austenite phase in a duplex microstructure. According to electron microscopy examination and electron backscattering diffraction analysis, the fracture mode was predominantly cleavage, and cracks propagated along the body-centered cubic (BCC) phases ferrite and α’-martensite. The BCC crystal structure enables fast diffusion of hydrogen to the crack tip area. No delayed cracking was observed in the stainless steel that had high austenite stability. Thus, it can be concluded that the presence of α’-martensite increases the hydrogen-induced cracking susceptibility.

Development of Short-Range Order and Intergranular Carbide Precipitation in Alloy 690 TT upon Thermal Ageing

Thermal ageing promotes intergranular carbide precipitation and atomic ordering reaction in most commercial nickel-base alloys, and it affects the long-term primary water stress corrosion cracking (PWSCC) resistance of pressurized water reactor components. Alloy 690 with 9.8 wt% Fe was solution annealed and heat-treated at low temperature, then aged between 350 and 550 °C for 10,000 h. No direct observation of ordering was possible, but variations in hardness and lattice parameter suggested the formation of short-range ordering (SRO) with a peak level upon ageing at 420 °C, while a disordering reaction occurred at higher temperatures. Heat treatment induced ordering before thermal ageing was compared to the solution-annealed state. Thermal ageing resulted in the precipitation of Cr-rich M23C6 carbides at grain boundaries and twin boundaries. Although no link between SRO and an increase in strain localization was observed, the combination of intergranular carbide formation and SRO over longer ageing times was deemed detrimental to the PWSCC resistance of Alloy 690 TT.

Effect of thermal aging on fracture mechanical properties and crack propagation behavior of alloy 52 narrow-gap dissimilar metal weld

Determination of the fracture toughness properties and thermal aging behavior of dissimilar metal weld (DMW) joints is of utmost importance for successful structural integrity and lifetime analyses. This paper presents results from fracture resistance (J-R), fracture toughness (T0) and Charpy-V impact toughness tests as well as fractography performed for an industrially manufactured narrow-gap DMW mock-up (SA508-Alloy 52-AISI 316L). Tests were performed on post-weld heat treated, 5000 h aged and 10,000 h aged material. The results show that this DMW is tough at the SA 508-Alloy 52 interface, which typically is the weakest zone of a DMW. The DMW joint maintains its high fracture resistance also after thermal aging. Crack propagates for a large part in the carbon-depleted zone (CDZ) of SA 508 but deflects occasionally to the Alloy 52 side due to small weld defects in µm scale. Ductile-to-brittle transition temperature determined from Charpy-V impact toughness tests increases due to thermal aging, but only to a minor extent. No significant change is observed for the T0 transition temperature due to aging.

Metallurgical response of weld metal to different filler metal and joint design combinations of laser-arc hybrid welded lean duplex and novel ferritic stainless steels

Laser and laser-arc hybrid welding of duplex and ferritic stainless steels is demanding, because microstructure of the welds tends to be highly ferritic. Therefore, filler metal must be used for maintaining corrosion and mechanical properties of the welds. In this study, different filler metals including duplex, basic, and overalloyed austenitic grades were used with laser-arc hybrid method to weld lean duplex 1.4162 and novel ferritic stainless steels grades 1.4622 and 1.4509. Several sets of joint design and welding parameter combinations were used to adjust the amount of filler metal in the weld. The purpose of the trials was to evaluate whether weld metal microstructures (grain morphology, austenite/ferrite balance, etc.) can be modified by using an applicable joint preparation and an “overmatched” filler metal addition. Weld characterization included several research methods such as: Macro- and microscopic examination using light microscope¸ cross-sectional dilution ratio determination from the metallographic cross sections, electron backscatter diffraction method in order to assess austenite, and ferrite phase proportions in the test welds. The effects of used groove geometry, filler metal composition, and content on resulting metallurgical features of the welds are discussed in detail.