Tengfei Wang

Hydrothermal carbonization of sewage sludge: The effect of feed-water pH on fate and risk of heavy metals in hydrochars

In this study, the effect of feed-water pH (pH=2-12) on fate and risk of heavy metals (HMs) in hydrochars (HCs) was investigated. Hydrothermal carbonization (HTC) of sewage sludge (SS) was carried out with different feed-water pH at 270°C. The research results showed that changing feed-water pH had a positive effect on accumulating Pb, Ni, Cd and Zn in HCs. Chemical forms of Cu and Cr converted from an unstable state to stable in the alkaline environment while in the acidic condition was opposite. The effect of feed-water pH on the chemical forms of HMs was variable but not significant. Risk assessments of Igeo, Er(i), RAC and RI were applied to evaluate the accumulation levels of individual metal, the potential ecological risks, the bio-availabilities and the comprehensive toxicity and sensitivity of HMs, respectively. The lowest pollution level of HMs was obtained at 270°C with pH=11.

Influence of temperature on nitrogen fate during hydrothermal carbonization of food waste

The influence of temperature (180-260°C) on the fate of nitrogen during hydrothermal carbonization (HTC) of food waste (FW) was assessed. The distribution and evolution of nitrogen in aqueous products and bio-oil, as well as hydrochar, were conducted. Results suggested that elevated temperature enhanced the deamination and the highest ammonium concentration (929.75mg/L) was acquired at 260°C. At temperatures above 220°C, the total N in the hydrochar became stable, whereas the mass percentage of N increased. Amines and heterocyclic-N compounds from protein cracking and Maillard reactions were identified as the main nitrogen-containing compounds in the bio-oil. As to the hydrochar, increasing temperature resulted in condensed nitrogen-containing aromatic heterocycles (e.g. pyridine-N and quaternary-N). In particular, remarkable Maillard reactions at 180°C and the highest temperature at 260°C enhanced nitrogen incorporation (i.e. quaternary-N) into hydrochar.

Nitrogen-doped porous carbon from Camellia oleifera shells with enhanced electrochemical performance

Nitrogen doped porous activated carbon was prepared by annealing treatment of Camellia oleifera shell activated carbon under NH3. We found that nitrogen content of activated carbon up to 10.43 at.% when annealed in NH3 at 800 °C. At 600 °C or above, the N-doped carbon further reacts with NH3, leads to a low surface area down to 458 m(2)/g and low graphitization degree. X-ray photoelectron spectroscope (XPS) analysis indicated that the nitrogen functional groups on the nitrogen-doped activated carbons (NACs) were mostly in the form of pyridinic nitrogen. We discovered that the oxygen groups and carbon atoms at the defect and edge sites of graphene play an important role in the reaction, leading to nitrogen atoms incorporated into the lattice of carbon. When temperatures were lower than 600 °C the nitrogen atoms displaced oxygen groups and formed nitrogen function groups, and when temperatures were higher than 600 °C and ~4 at.% carbon atoms and part of oxygen function groups reacted with NH3. When compared to pure activated carbon, the nitrogen doped activated carbon shows nearly four times the capacitance (191 vs 51 F/g).

A review on airborne microorganisms in particulate matters: Composition, characteristics and influence factors

Airborne microorganisms (AM), vital components of particulate matters (PM), are widespread in the atmosphere. Since some AM have pathogenicity, they can lead to a wide range of diseases in human and other organisms, meanwhile, some AM act as cloud condensation nuclei and ice nuclei which let them can affect the climate. The inherent characteristics of AM play critical roles in many aspects which, in turn, can decide microbial traits. The uncertain factors bring various influences on AM, which make it difficult to elaborate effect trends as whole. Because of the potential roles of AM in environment and potent effects of factors on AM, detailed knowledge of them is of primary significance. This review highlights the issues of composition and characteristics of AM with size-distribution, species diversity, variation and so on, and summarizes the main factors which affect airborne microbial features. This general information is a knowledge base for further thorough researches of AM and relevant aspects. Besides, current knowledge gaps and new perspectives are offered to roundly understand the impacts and application of AM in nature and human health.

Feedwater pH affects phosphorus transformation during hydrothermal carbonization of sewage sludge

In this study, the effect of feedwater pH (3-11) on phosphorus (P) transformation during the hydrothermal carbonization (HTC) of sewage sludge (SS) was investigated at a temperature range of 200-260°C. The HTC significantly accumulated P in the hydrochar. Different feedwater pH stimulated the transformation of various forms of P. An acidic feedwater pH promoted the transformation of apatite phosphorus (AP) to non-apatite inorganic phosphorus (NAIP), and of organic P (OP) to inorganic P (IP). The NAIP tended to transformation to AP and a small part of the IP was transformed to OP when the SS was treated in a basic environment. The combination of three P analysis methods (chemical extractive fractionation, X-ray powder diffraction (XRD) and energy dispersive spectroscopy (EDS)) showed that metal cations (e.g. Al and Ca) and the pH played important roles in the transformation of different forms of P during the HTC of the SS.

Traffic-related heavy metals uptake by wild plants grow along two main highways in Hunan Province, China: effects of soil factors, accumulation ability, and biological indication potential

This study was performed to investigate pollution of traffic-related heavy metals (HMs—Zn, Pb, Cu, Cr, and Cd) in roadside soils and their uptake by wild plants growing along highways in Hunan Province, China. For this, we analyzed the concentration and chemical fractionation of HMs in soils and plants. Soil samples were collected with different depths in the profile and different distances from highway edge. And leaves and barks of six high-frequency plants were collected. Results of the modified European Community Bureau of Reference (BCR) showed that the mobile fraction of these HMs was in the order of Cd > Pb > Zn > Cu > Cr. A high percentage of the mobile fraction indicates Cd, Pb, and Zn were labile and available for uptake by wild plants. The total concentration and values of risk assessment code (RAC) showed that Cd was the main risk factor, which were in the range high to very high risk. The accumulation ability of HMs in plants was evaluated by the biological accumulation factor (BAF) and the metal accumulation index (MAI), and the results showed that all those plant species have good phyto-extraction ability, while accumulation capacity for most HMs plants tissues was bark > leaf. The highest MAI value (5.99) in Cinnamomum camphora (L) Presl indicates the potential for bio-monitoring and a good choice for planting along highways where there is contamination with HMs.

Effect of sewage sludge hydrochar on soil properties and Cd immobilization in a contaminated soil

To investigate hydrochar as a soil amendment for the immobilization of Cd, the characteristics of hydrochars (HCs) under three temperatures and residence times, were studied, with a particular interest in soil properties, as well as the speciation, availability and plant uptake of Cd. HCs were obtained by a hydrothermal carbonization (HTC) reaction of sewage sludge (SS). Based on the study of HC properties, we found that HCs present weak acidity with relatively high ash content and low electrical conductivity (EC) values. The addition of HCs to soil decreased soil pH and EC values but increased the abundance of soil microorganism. HCs also promoted the transformation of Cd from unstable to stable speciation and can decrease the content of phyto-available Cd (optimum condition and efficiency: A13,2 15.38%), which restrained cabbage from assimilating Cd from soil both the aboveground (optimum condition and efficiency: A35, 52.29%) and underground (optimum condition and efficiency: C15, 57.53%) parts of it.

Evaluation of the clean characteristics and combustion behavior of hydrochar derived from food waste towards solid biofuel production

This study investigated the clean properties and combustion behavior of hydrochar from food waste (FW). The hydrochar was characterized by proximate analysis and HHVs, and the chemical forms were investigated by FTIR, XPS (Sulfur), and XANES (Chlorine). TG-FTIR was used to assess the combustion behaviors, and XRF was used to assess the fouling and slagging inclinations. Results showed that increasing temperature from 180 °C to 260 °C enhanced the removal of N, S, and Cl for hydrochar. Especially, aromatic-S and sulfate-S increased in contrast to sulfoxide-S, and more inorganic-S was produced in hydrochar; all samples had mainly inorganic-chlorine. Additionally, the release of HCl, SO2, and NO of hydrochar combustion were significantly reduced and the SI and FI index decreased to ranges of 0.18-0.16 and 0.32-0.17, respectively. However, hydrochar produced at temperature above 220 °C led increased NO emission possibly due to formation of more pyridine-N and quaternary-N.

Co-hydrothermal carbonization of food waste-woody biomass blend towards biofuel pellets production

Co-hydrothermal carbonization of food waste-woody biomass blend was conducted to enhance the pelletization and hydrochar-fuel properties. The hydrochar was characterized by proximate, elemental analysis and HHVs, whilst energy consumption of pelletization, tensile strength, and combustion characteristics of hydrochar pellets were evaluated. Results showed that food waste (FW) blended with 0-50% mainly decreased H/C of hydrochar, while blend ratio from 75% to 100% mainly decreased O/C. When FW blended from 0% to 75%, the energy consumption for hydrochar palletization decreased about 12-17 J, whereas tensile strength of pellets increased about 2.4-5.5 MPa by formation of solid bridge when woody biomass (WS) ratio was increased. The hydrochar pellets from high ratio FW had decreased ignition temperature and maximum weight loss rate with wider temperature range, indicating the increased flammability and moderate combustion. These findings demonstrate that HTC of food waste-woody biomass blend was suitable for pelletization towards solid biofuel production.

The adsorption mechanisms of ClO4− onto highly graphited and hydrophobic porous carbonaceous materials from biomass

Biomass activated carbons were activated and pyrolyzed at 300–800 °C under nitrogen circumstance (named as CAC300–CAC800). The physicochemical characteristics of CACs and mechanisms of perchlorate (ClO4−) adsorption on CACs were investigated. Compared to CAC300, CAC600–CAC800 had higher surface area, total prove volume, higher hydrophobic surface and an abundant of oxygen-containing groups (–COH and –COOH) which contributed to a higher ClO4− adsorption capacity. The pH value of solution significantly affected ClO4− adsorption and the maximum ClO4− adsorption capacity occurred at pH 2.0 (less than pHIEP), where surface charge was positive. Electrostatic attraction and hydrogen bonding to oxygen-containing groups on CACs were considered as the dominant force for ClO4− adsorption. With the pH increased, electrostatic attraction disappeared and surface oxygen-containing groups were gradually deprotonated, and the ClO4− adsorption amount was gradually decreased few until pH 12.0. The batch adsorption experiments of ClO4− showed that CAC600–CAC800 were effective adsorbents for the adsorption of ClO4−.