Thomas C. Zietlow | Researchain

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Journal of Solid State Chemistry | 1985

Electronic spectroscopy and photophysics of d4 clusters

Thomas C. Zietlow; Michael D. Hopkins; Harry B. Gray

The electronic structural analogies between ( d 4 ) 2 M 2 X 8 4− and ( d 4 ) 6 ( M 6 X 8 ) X 6 2− ( M =Mo, W; X =Cl, Br, I) clusters are outlined. Metal-localized δ-type orbitals play an important role in the ground state and the lowest excited states of each complex. All evidence suggests that the splitting between the emissive δδ * -singlet and the δδ * -triplet excited states of M 2 X 8 4− and related species is greater than 1 eV, whereas the ∼2-eV emissive excited state of ( M 6 X 8 ) X 6 2− is a spin triplet.

Inorganic Chemistry | 1986

Hexanuclear tungsten cluster structures: tetradecachlorohexatungstate(2-), tetradecabromohexatungstate(2-), and tetradecaiodohexatungstate(2-) relevance to unusual emissive behavior

Thomas C. Zietlow; William P. Schaefer; Behzad Sadeghi; Nhi Hua; Harry B. Gray

Inorganic Chemistry | 1986

Photophysics and electrochemistry of hexanuclear tungsten halide clusters

Thomas C. Zietlow; Daniel G. Nocera; Harry B. Gray

Journal of the American Chemical Society | 1985

Magnetic and spectroscopic properties of the .delta..delta.* states of tetrachlorotetrakis(trimethylphosphine)dimolybdenum and .beta.-[tetrachlorobis[1,2-bis(dimethylphosphino)ethane]dimolybdenum]: experimental determination of the energy of a triplet .delta..delta.* state

Michael D. Hopkins; Thomas C. Zietlow; Vincent M. Miskowski; Harry B. Gray

Inorganic Chemistry | 1981

Complex halides of the transition metals. 28. One-electron oxidations of quadruply bonded molybdenum dimers

Thomas C. Zietlow; Douglas D. Klendworth; Tayseer. Nimry; Dennis J. Salmon; Richard A. Walton

Inorganic Chemistry | 1996

Resonance Raman Spectra of [M(6)X(8)Y(6)](2)(-) Cluster Complexes (M = Mo, W; X, Y = Cl, Br, I).

Jon R. Schoonover; Thomas C. Zietlow; David L. Clark; Joseph A. Heppert; Malcolm H. Chisholm; Harry B. Gray; and Alfred P. Sattelberger; William H. Woodruff

Inorganic Chemistry | 1986