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Thomas Lobreyer

Heidelberg University

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Publication

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Journal of Molecular Structure | 1994

The GeSi bond in silylgermane. Discrepancy between experiment and theory

Heinz Oberhammer; Thomas Lobreyer; Wolfgang Sundermeyer

Abstract The gas-phase structure of H 3 GeSiH 3 was determined by joint analysis of electron diffraction intensities and the rotational constant. The following geometric parameters ( r a distances and ∠ α angles with 2σ uncertainties) were obtained: GeSi = 2.364(1), GeH = 1.538(3), SiH = 1.494(6) A, HGeH = HSiH = 108.8(3)°. The experimental GeSi bond length is 0.04–0.07 A shorter than various ab initio results reported in the literature.

Angewandte Chemie | 1994

Inversely Coordinating Silanide Ions in an Oligomeric Sodium Alcoholate

Hans Pritzkow; Thomas Lobreyer; Wolfgang Sundermeyer; Nicolaas J. R. van Eikema Hommes; Paul von Ragué Schleyer

Chemische Berichte | 1993

Über die-Synthese und Molekülstruktur von CH3M(SiH3)3 (MSi, Ge)

Thomas Lobreyer; Johannes Oeler; Wolfgang Sundermeyer; Heinz Oberhammer

Angewandte Chemie | 1993

Synthesis and Structure of Tetrasilylgermane, Ge(SiH3)4, and Other Sillgermanes

Thomas Lobreyer; Heinz Oberhammer; Wolfgang Sundermeyer

Chemische Berichte | 1991

Über die verbesserte Darstellung von Silyl- und Germylkalium sowie die Synthese von Silylgermanen

Thomas Lobreyer; Johannes Oeler; Wolfgang Sundermeyer

Chemische Berichte | 1994

Über dehydrierende Aufbaureaktionen zu silylsubstituierten Alkalimetallgermaniden, -stanniden und -phosphiden; Molekülstruktur von Neopentasilan

Thomas Lobreyer; Wolfgang Sundermeyer; Heinz Oberhammer

Archive | 1993

Method for preparing silylgermanes

Thomas Lobreyer; Wolfgang Sundermeyer

Angewandte Chemie | 1993

SYNTHESE UND STRUKTUR VON TETRASILYLGERMAN GE(SIH3)4, UND WEITEREN SILYLGERMANEN

Thomas Lobreyer; Heinz Oberhammer; Wolfgang Sundermeyer

Angewandte Chemie | 1994

INVERS KOORDINIERENDE SILANID-IONEN AN EINEM OLIGOMEREN NATRIUMALKOHOLAT

Hans Pritzkow; Thomas Lobreyer; Wolfgang Sundermeyer; Nicolaas J. R. van Eikema Hommes; Paul von Ragué Schleyer

European Journal of Inorganic Chemistry | 1993

ber die-Synthese und Moleklstruktur von CH3M(SiH3)3 (M?Si, Ge)

Thomas Lobreyer; Johannes Oeler; Wolfgang Sundermeyer; Heinz Oberhammer

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Wolfgang Sundermeyer

Heidelberg University

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Heinz Oberhammer

University of Tübingen

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Johannes Oeler

Heidelberg University

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Hans Pritzkow

Heidelberg University

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Nicolaas J. R. van Eikema Hommes

University of Erlangen-Nuremberg

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Paul von Ragué Schleyer

University of Erlangen-Nuremberg

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H. Oberhammer

Heidelberg University

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