Thomas Lundin Christiansen
Technical University of Denmark
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Featured researches published by Thomas Lundin Christiansen.
Surface Engineering | 2010
Thomas Lundin Christiansen; Thomas Strabo Hummelshøj; Marcel A. J. Somers
Abstract The identity of expanded austenite as developing during low temperature nitriding and/or carburising of austenitic stainless steel has been under debate since the very first observation of this phase. In the present article, recent results obtained with (a) homogeneous samples of various uniform compositions and (b) unravelling of the contributions of stress–depth and composition–depth profiles in expanded austenite layers are summarised and discussed. It is shown through simulation of line profiles that the combined effects of composition gradients, stress gradients and stacking fault gradients can explain the observations in typical X-ray diffractograms.
International Journal of Materials Research | 2008
Thomas Lundin Christiansen; Marcel A. J. Somers
Abstract The concentration dependent diffusion coefficient of nitrogen in expanded austenite was determined from the rate of retracting nitrogen from thin initially N-saturated coupons. Nitrogen saturated homogeneous foils of expanded austenite were obtained by nitriding AISI 304 and AISI 316 in pure ammonia at 693 K and 718 K. Denitriding experiments were performed by equilibrating the foils with a successively lower nitrogen activity, as imposed by a gas mixture of ammonia and hydrogen. The concentration depen-dent diffusion coefficient of nitrogen in expanded austenite was approximated in the composition range where nitrogen can be extracted by hydrogen gas at the diffusion temperature. Numerical simulation of the denitriding experiments shows that the thus determined concentration dependent diffusion coefficients are an accurate approximation of the actual diffusivity of nitrogen in expanded austenite.
Journal of Applied Crystallography | 2008
Jette Oddershede; Thomas Lundin Christiansen; Kenny Ståhl
Stress-free and homogeneous samples of nitrogen-expanded austenite, a defect-rich f.c.c. structure with a high interstitial nitrogen occupancy (between 0.36 and 0.61), have been studied using X-ray powder diffraction and Debye simulations. The simulations confirm the presence of deformation stacking faults in the structure, while twin or growth faulting can be ruled out. Screw dislocations are abundant and the dislocation density increases with the interstitial nitrogen occupancy. Whether the N atoms are clustered or distributed randomly among the octahedral interstices was found to be indistinguishable to X-ray powder diffraction.
Metallurgical and Materials Transactions A-physical Metallurgy and Materials Science | 2015
Federico Bottoli; Grethe Winther; Thomas Lundin Christiansen; Marcel A. J. Somers
This article addresses an investigation of the influence of plastic deformation on low-temperature surface hardening by gaseous nitriding of two commercial stainless steels: EN 1.4369 and AISI 304. The materials were plastically deformed to several levels of equivalent strain by conventional tensile straining, plane strain compression, and shear. Gaseous nitriding of the strained material was performed in ammonia gas at atmospheric pressure at various temperatures. Microstructural characterization of the as-deformed state and the nitrided case produced included X-ray diffraction analysis, reflected-light microscopy, and microhardness testing. The results demonstrate that a case of expanded austenite develops and that the presence of plastic deformation has a significant influence on the morphology of the nitrided case. The presence of strain-induced martensite favors the formation of CrN, while a high dislocation density in a fully austenitic structure does not lead to such premature nucleation of CrN.
Journal of Applied Crystallography | 2014
Bastian Brink; Kenny Ståhl; Thomas Lundin Christiansen; Marcel A. J. Somers
Nitrogen-expanded austenite, γN, with high and low nitrogen contents was produced from AISI 316 grade stainless steel powder by gaseous nitriding in ammonia/hydrogen gas mixtures. In situ synchrotron X-ray diffraction was applied to investigate the thermal expansion and thermal stability of expanded austenite in the temperature range 385–920 K. Evaluation of the diffractograms of the sample with a high nitrogen content, corresponding to an occupancy of the interstitial lattice of 56%, with Rietveld refinement yielded a best convergence after including the stacking fault probability as a fitting parameter. The stacking fault density is constant for temperatures up to 680 K, whereafter it decreases to nil. Surprisingly, a transition phase with composition M4N (M = Fe, Cr, Ni, Mo) appears for temperatures above 770 K. The linear coefficient of thermal expansion depends on the nitrogen content and is lowest for the sample with a high level of nitrogen.
Surface Engineering | 2011
Thomas Lundin Christiansen; Thomas Strabo Hummelshøj; Marcel A. J. Somers
Abstract Gaseous carburising of self-passivating Fe–Cr–Ni alloys in acetylene–hydrogen was investigated for temperatures up to 823 K. Acetylene–hydrogen gas mixtures allow both the activation of the surface and the subsequent carburising at a high and adjustable carburising potential. For relatively low temperatures, carbon stabilised expanded austenite develops, which has high hardness, while retaining the corrosion performance of the untreated alloy; for relatively high temperatures, Cr based carbides develop, and eventually, the material deteriorates by metal dusting corrosion.
Materials Science Forum | 2004
Thomas Lundin Christiansen; Marcel A. J. Somers
On evaluating lattice strain-depth or stress-depth profiles with X-ray diffraction, the variation of the information depth while combining various tilt angles, in combination with lattice spacing gradients leads to artefacts, so-called ghost or fictitious stresses. X-ray diffraction lattice-strain analysis was simulated for a model stress-depth profile combined with a composition-depth profile. Two principally different methods were investigated for the reconstruction of the actual stress and composition profiles from the simulated data: - considering the stress/strain determined at a specific depth as a weighted average over the actual stress/strain depth profile - considering the lattice spacing determined at a specific depth, for a specific value for as a weighted average over the actual lattice spacing profile for this direction. On the basis of the results it is possible to propose a preferred method for the evaluation of stress/strain and composition profiles, while minimising the risk for ghost stresses.
Thermochemical Surface Engineering of Steels#R##N#Improving Materials Performance | 2015
Marcel A. J. Somers; Thomas Lundin Christiansen
Abstract In this chapter low temperature surface hardening by nitriding and carburising of austenitic stainless steel is described. A historical evolution of surface hardening of austenitic stainless steel from a carburising corrosion phenomenon in liquid sodium and from plasma-based nitrogen incorporation is presented. The development of gaseous processes enabled a systematic investigation of the crystallography, thermodynamics and diffusion kinetics in nitrogen and carbon stabilised expanded austenite brought about by dissolving large amounts of nitrogen and carbon in stainless steel. Finally, the thermal stability of expanded austenite is discussed. The chapter addresses the fundamentals which will be elaborated upon in the following chapters.
Defect and Diffusion Forum | 2006
Thomas Lundin Christiansen; Kristian Vinter Dahl; Marcel A. J. Somers
Abstract. A numerical model is presented, which simulates nitrogen concentration-depth profiles as obtained with low temperature gaseous nitriding of stainless steel. The evolution of the calculated nitrogen concentration-depth profiles is compared with experimental nitriding kinetics. It is shown that the evolution of the surface concentration is likely to play a dominant role under experimental conditions.
Defect and Diffusion Forum | 2010
Thomas Lundin Christiansen; Marcel A. J. Somers
The present paper addresses the influence of chemical induced stresses on diffusion in interstitial systems. This is exemplified by simulations of carbon diffusion in austenite at high temperatures and it is shown that old well established literature data is flawed by the occurrence of composition induced stress. For the technological relevant system of expanded austenite the diffusion can be dramatically affected by composition induced stress.