Thomas Nosker

Toxicity of construction materials in the marine environment: a comparison of chromated-copper-arsenate-treated wood and recycled plastic.

Previous studies have demonstrated leaching from chromated-copper-arsenate (CCA)-treated wood, which is used in pilings and bulkheads, and resulting toxicity to various estuarine organisms. The current study compared effects of leachates from CCA-treated wood with those of recycled plastic “lumber,” a possible alternative construction material. Limb regeneration in fiddler crabs, while depressed in leachates from CCA wood, was accelerated in three formulations of recycled plastics. The acceleration was reduced in subsequent trials with the same pieces of plastic. Using a sea urchin fertilization test, no effects were seen in 1- and 3-day leachates from the plastics. However, CCA wood reduced fertilization by 90%, and totally inhibited larval development of those that did fertilize. A smaller piece of wood, one-tenth the size (0.4 cm2), did not have a significant effect on fertilization or development. With 1–3 weeks of leaching, significant reductions in fertilization were seen in sea urchin gametes exposed to one plastic formulation and no fertilization was seen in leachates from the small piece of CCA wood. Two formulations enriched to 30% polystyrene (PS) had no significant effect on fertilization, but did reduce larval growth. When the same pieces of plastic and wood were used for a second set of experiments, all three formulations of plastic, as well as the small piece of wood, inhibited fertilization significantly, and one of the 30% PS formulations and the wood caused reduced larval growth.In another assay, snails and an alga were exposed to plastics for two months with no observed effect; the CCA leachates caused 100% snail mortality within one week and chlorosis of the alga. Chemical analysis by GC/MS revealed a large number of chemicals leached in various quantities from the plastic.

The Utilization of Recycled Thermoplastic Composites for Civil and Military Load Bearing Applications

Long-term performance and extended service life are issues of vital importance to the Department of Defense (DoD). The DoD seeks alternative construction materials to replace more traditional materials, such as wood and steel, for heavily loaded infrastructure to combat this expensive corrosion and bio-degradation problem. Recently, two military bridge installations were completed, composed entirely of a reinforced thermoplastic composite lumber (RTCL) material that is capable of supporting the load of an M1 Abrams tank at approximately 64,410 kg (71 tons). The RTCL material selected for these applications is polypropylene (PP) coated fiberglass blended with high-density polyethylene (HDPE). Advantages of using RTCL include the following qualities: corrosion, insect, and rot resistance; no toxic chemical treatments required to increase service life; environmentally friendly; diversion of waste plastics from landfills; reduction of deforestation, green house gases, and global warming. RTCL has many advantages but does behave differently than traditional materials and certain properties must be addressed during the design stage. Both bridges are continually monitored, have performed well over the first year and a half, and are more cost-effective than any other construction material. Details of the material, design considerations, and construction are reviewed.

Mechanical grafting and morphology characterization in immiscible polymer blends

Blends of PS/HDPE and PS/PP were investigated for synergism in flexural modulus with varying composition. The evolution of blend morphology was studied and related to the improvement in flexural modulus around the co-continuous composition. DSC studies were conducted to study crystallinity variations in the semi-crystalline component of the blend. We found that co-continuous morphologies help in developing strong mechanical bonds between the components. Crystallization is inhibited in the co-continuous region and is related to the spatial constraints during the solidification process.