Thomas R. Halbach

Input characterization of perfluoroalkyl substances in wastewater treatment plants: Source discrimination by exploratory data analysis

This paper presents a methodology based on multivariate data analysis for identifying input sources of perfluoroalkyl substances (PFASs) detected in 37 wastewater treatment plants (WWTPs) across more than 40 cities in the state of Minnesota (USA). Exploratory analysis of data points has been carried out by unsupervised pattern recognition (cluster analysis), correlation analysis, ANOVA and per capita discharges in an attempt to discriminate sources of PFASs in WWTPs. Robust cluster solutions grouped the database according to the different PFAS profiles in WWTP influent. Significantly elevated levels of perfluorohexanoic acid (PFHxA), perfluorooctanoic acid (PFOA) and/or perfluorooctane sulfonate (PFOS) in influent have been found in 18 out of 37 WWTPs (49%). A substantial increase in the concentrations of PFHxA and/or PFOA from influent to effluent was observed in 59% of the WWTPs surveyed, suggestive of high concentration inputs of precursors. The fate of one precursor (8:2 fluorotelomer alcohol) in WWTP was modeled based on fugacity analysis to understand the increasing effluent concentration. Furthermore, population-related emissions cannot wholly explain the occurrence and levels of PFASs in WWTPs. Unusually high influent levels of PFASs were observed in WWTPs located in specific industrial areas or where known contamination had taken place. Despite the restriction on the production/use of PFOA and PFOS, this paper demonstrates that wastewater from industrial activities is still a principal determinant of PFAS pollution in urban watersheds.

Nitrogen and carbon mineralization in soil amended with municipal solid waste compost

Municipal solid waste (MSW) compost contains large amounts of organic matter that can be beneficial to soil. The objectives of this study were to measure N mineralization and acid hydrolyzable N in soil amended with MSW compost and correlate corn (Zea mays L.) grain yield with acid hydrolyzable N. The soil, an Orthic Black Chernozem (Entic Hapludoll) cropped to corn, was amended with composts at either 90 dry Mg ha−1 yr−1 from 1993 to 1995, or at 270 dry Mg ha−1 in one application in 1993. Soil samples were collected in the fall of 1994 and 1995 to measure C and N mineralization and acid hydrolyzable N. Potentially mineralizable N was estimated with the NCSOIL model after using C and N mineralization observed in the laboratory to calibrate the model. Net N immobilization occurred in compost-amended soils collected in 1994 with less than 0.2% of the total soil N mineralized in the compost treatments. In 1995, there was net mineralization in compost treatments but less than 5% of total soil N mineralized in...

Effect of A Waste Stream Component on the Agronomic Properties of Municipal Solid Waste Compost

Managing municipal solid waste (MSW) compost for agricultural use requires an understanding of waste stream components and how they affect the value of the finished product. We evaluated the influence of disposable diaper content in MSW compost because of the recent concern of the environmental impact of this product. To determine the potential effect of disposable diapers on MSW compost, the ‘normal’ concentration of soiled, disposable diapers in a waste stream was raised from 2 percent to 8 percent. Previous observations indicated that the diapers disassociated during in-vessel digestion and most of the components could not be distinguished from the primary compost. The objective of this study was to examine the effect of additional diapers on the agricultural value of mature MSW compost. Loamy sand and silt loam soils were amended with MSW compost at a rate of 20 percent. Comparisons between the two composts and their interactions with soil type were made on the basis of water retention characteristics...

A Method for Determining the Ultimate Fate of Synthetic Chemicals during Composting

▪ Pollution control workers have proposed composting as a bioremediation method for the cleanup of contaminated soil and for the detoxification of hazardous organic chemicals. However, decomposition (mineralization to CO2 and H2O) may not always be enhanced by composting, and transformation products of unknown risk may accumulate during composting. This paper presents a scientifically based scheme to determine the ultimate fate of synthetic materials in a composting environment, and for studying factors that may control the degradation of specific chemicals including herbicides (e.g., substrate bioavailability, enzyme concentrations, environmental conditions).