Tiantian Shao

Using Partial Least Squares-Artificial Neural Network for Inversion of Inland Water Chlorophyll-a

Accurate remote estimation of chlorophyll-a (CHL) concentration for turbid inland waters is a challenging task due to their optical complexity. In situ spectra (n=666) measured with ASD and Ocean Optics spectrometers from three drinking water sources in Indiana, USA, were used to calibrate the partial least squares model (PLS), artificial neural network model (ANN), and the three-band model (TBM) for CHL estimates; model performances are validated with three independent datasets (n=360) from China. The PLS-ANN model resulted in accurate model calibration ( R2=0.94; Range=0.2-296.6 μg/l of CHL), outperforming the PLS (R2=0.87), ANN (R2=0.91), and TBM (R2=0.86). With an independent validation dataset, the PLS-ANN yielded relatively high accuracy (RMSE: 6.12 μg/l; rRMSE=42.12%; range=0.45-97.2 μg/l of CHL), while TBM yielded acceptable accuracy (RMSE: 8.85 μg/l; rRMSE=63.21%). With simulated ESA/MERIS and EO-1/Hyperion spectra, the PLS-ANN also (MERIS: R2=0.84; Hyperion: R2=0.88) outperforms the TBM (MERIS: R2=0.69; Hyperion: R2=0.76) for model calibration. For validation, the PLS-ANN achieves good performance with simulated spectra (MERIS: RMSE=7.83 μg/l, rRMSE=48.79%; Hyperion: RMSE=6.98 μg/l, rRMSE=45.57%) as compared to the TBM (MERIS: RMSE=10.39 μg/l, rRMSE=68.92%; Hyperion: RMSE=9.54 μg/l, rRMSE=65.35%). Nevertheless, considering the large and diverse datasets, the TBM is a robust semiempirical algorithm. Based on our observations, both the PLS-ANN and TBM are effective approaches for CHL estimation in turbid waters.

Characterization of CDOM of river waters in China using fluorescence excitation‐emission matrix and regional integration techniques

The spatial characteristics of fluorescent-DOM (FDOM) components in river waters in China were firstly examined by excitation-emission matrix (EEM) spectra and fluorescence regional integration (FRI) with the data collected during September to November between 2013 and 2015. One tyrosine-like (R1), one tryptophan-like (R2), one fulvic-like (R3), one microbial protein-like (R4) and one humic-like (R5) components have been identified by FRI method. Principle components analysis (PCA) was conducted to assess variations in the five FDOM components (FRί (ί = 1, 2, 3, 4, 5)) and the humification index (HIX) for all 194 river water samples. The average fluorescence intensities of the five fluorescent components and the total fluorescence intensities FSUM differed under spatial variation among the seven major river basins (Songhua, Liao, Hai, Yellow and Huai, Yangtze, Pearl and Inflow Rivers) in China. When all the river water samples were pooled together, the fulvic-like FR3 and the humic-like FR5 showed a strong positive linear relationship (R2 = 0.90, n = 194), indicating that the two allochthonous FDOM components R3 and R5 may originate from similar sources. There is a moderate strong positive correlation between the tryptophan-like FR2 and the microbial protein-like FR4 (R2 = 0.71, n = 194), suggesting parts of two autochthonous FDOM components R2 and R4 are likely from some common sources. However, the total allochthonous substance FR(3+5) and the total autochthonous substances FR(1+2+4) exhibited a weak correlation (R2 = 0.40, n = 194). Significant positive linear relationships between FR3 (R2 = 0.69, n = 194), FR5 (R2 = 0.79, n = 194) and CDOM absorption coefficient a(254) were observed, respectively, which demonstrated the CDOM absorption were dominated by the allochthonous FDOM components R3 and R5.

Characteristics and sources analysis of riverine chromophoric dissolved organic matter in Liaohe River, China

Chromophoric dissolved organic matter (CDOM) in riverine systems can be affected by environmental conditions and land-use, and thus could provide important information regarding human activities in surrounding landscapes. The optical properties of water samples collected at 42 locations across the Liaohe River (LHR, China) watershed were examined using UV-Vis and fluorescence spectroscopy to determine CDOM characteristics, composition and sources. Total nitrogen (TN) and total phosphorus (TP) concentrations at all sampling sites exceeded the GB3838-2002 (national quality standards for surface waters, China) standard for Class V waters of 2.0 mg N/L and 0.4 mg P/L respectively, while trophic state index (TSIM) indicated that all the sites investigated were mesotrophic, 64% of which were eutrophic at the same time. Redundancy analysis showed that total suspended matter (TSM), dissolved organic carbon (DOC), and turbidity had a strong correlation with CDOM, while the other parameters (Chl a, TN, TP and TSIM) exhibited weak correlations with CDOM absorption. High spectral slope values and low SUVA254 (the specific UV absorption) values indicated that CDOM in the LHR was primarily comprised of low molecular weight organic substances. Analysis of excitation-emission matrices contour plots showed that CDOM in water samples collected from upstream locations exhibited fulvic-acid-like characteristics whereas protein-like substances were most likely predominant in samples collected in estuarine areas and downstream from large cities. These patterns were interpreted as indicative of water pollution from urban and industrial activities in several downstream sections of the LHR watershed.