Tim B. van Erp

Dynamics of fibrillar precursors of shishes as a function of stress

. Shishes are fibrillar crystallites that can be created by deforming a polymer melt. The formation of shishes takes place when flow is strong enough to stretch molecules. In the early stages, bundles of stretched molecules with pre-crystalline order form metastable precursors whose stability depends on their size and, hence, on the stress level. We find that for a specific isotactic polypropylene, close to the nominal melting point, a stress larger than 0.10 MPa leads to stable fibrillar precursors that are partially crystalline immediately after flow. On the other hand, below 0.10 MPa, the aspect ratio of precursors tends to unity and the lack of crystallinity makes these structures prone to dissolution.

Nonlinear creep response of oriented polypropylene tapes

The creep response of a highly oriented polypropylene tape used for the manufacture of self-reinforced polypropylene or all-polypropylene composites was studied over a range of stresses and temperatures. Similar to oriented polyethylene, the creep compliance is linear viscoelastic at short loading times, whereas pronounced stress dependence is observed at longer loading times. A mathematical model is proposed, where the total deformation of the fibre is regarded as being composed of a stress-linear delayed elastic component and a nonlinear plastic flow contribution. Model predictions are in good agreement with the experimental data.